Multi-channel plasmonic waveguide filters with disk-shaped nanocavities

A kind of multi-channel plasmonic filters based on metal–insulator–metal waveguides with disk-shaped nanocavities is proposed and numerically investigated. By calculating the resonant mode of disk-shaped nanocavity, it is found that the radius and refractive index of the nanocavity effectively control the resonance wavelength, which is consistent with the results obtained by finite-difference time-domain method. The characteristics of resonance spectra are influenced by the gap width between the cavity and waveguide, as can be exactly analyzed by temporal coupled mode theory. In addition, multi-channel plasmonic filters are achieved by increasing the number of nanocavity.     

Induced transparency in nanoscale plasmonic resonator systems

An optical effect analogous to electromagnetically induced transparency (EIT) is observed in nanoscale plasmonic resonator systems. The system consists of a slot cavity as well as plasmonic bus and resonant waveguides, where the phase-matching condition of the resonant waveguide is tunable for the generation of an obvious EIT-like coupled resonator-induced transparency effect. A dynamic theory is utilized to exactly analyze the influence of physical parameters on transmission characteristics. The transparency effect induced by coupled resonance may have potential applications for nanoscale optical switching, nanolaser, and slow-light devices in highly integrated optical circuits.     

在预吸附氧原子的Ag(100)面上氯乙烯环氧化反应的密度泛函理论研究

采用密度泛函理论和周期性平板模型对氯乙烯在预吸附氧原子的Ag(100)面上选择性环氧化反应进行了模拟计算.结果表明,该反应首先由反应物生成中间体,再由中间体生成产物.由于氯乙烯是一种不对称的分子,所以该反应存在两种可能的途径.比较反应活化能可以发现,在一个反应通道中环氧氯乙烷要比氯乙醛的生成更容易;而在另一反应通道中,...     

Characteristics of backing impacts on the performance of the thickness mode piezoelectric transducer

The impacts of the thickness, the specific acoustic impedance and the mechanical loss factor of the backing on the performance of the thickness mode piezoelectric transducer are systemically studied, which are focused on the effective electromechanical coupling coefficient and the mechanical quality factor near the center frequency. The results show that with contin?uous increasing of the backing thickness, the effective electromechanical coupling coefficient and the mechanical quality factor are found rapidly declined by oscillation way. With the increase of the difference value of the acoustic impedance between the backing material and the piezoelec?tric material, the effective electromechanical coupling coefficient deceases and the mechanical quality factor increases. Under condition that the thickness of the piezoelectric material is fixed, the effective electromechanical coupling coefficient is found declined with the increase of the mechanical loss factor by monotonous way. The mechanical quality factor has minimum value and the electric characteristic curve tends to be smooth in a given frequency range. The equivalent circuit theory result is in good agreement with the ones by finite element method and the experimental results. The work mentioned above provides a theoretical guidance for the design and experimental fabrication of the thickness mode piezoelectric transducer.     

液晶实时掩膜技术制作连续微光学元件

提出制作连续微光学元件的一种新技术———液晶实时掩膜技术 ,阐述了其基本原理和制作方法。基于部分相干光成像理论 ,采用计算机模拟了用实时掩膜制作微透镜和微轴锥镜阵列的过程。同时建立了实验装置进行实验 ,用全色银盐干板 (Kodak 131)通过酶刻蚀得到口径为 118.7μm ,深为 1.32 2 μm的 5 6× 48的轴锥镜的列阵。     

二元光学分束器输出稳定性的优化设计

 提出将微分-积分法用于二元光学分束器的设计, 以改善其输出对输入变化的敏感性。模拟计算表明, 使用这种方法设计的分束器, 当输入光束形状和强度变化时, 目标光强分布保持一定程度的稳定性, 衍射效率达到92.67% , 光强不均匀性小于0.002%。当输入由基模高斯波变为超高斯波或带有微小随机起伏的矩形光斑和平面波时, 衍射效率最低仍能达到89.60% 以上, 光强不均匀性最高为11.49%。综合衍射效率与光强不均匀性两方面考虑, 本文设计结果优于现有文献报导。     

二步合成平板周视彩虹全息术

提出一种将物光波前先分解记录，再合成的二步平板周视彩虹全息术。波前的分解记录与合成彩虹全息图是分别通过转动物体和干板来实现的。记录这种周视全息图，不需要大孔径和其它特殊光学元件，即可获得周视半径大的无象差立体再现象。该方法可直接用于模压全息图母板的制作。     

误差扩散法设计用于惯性约束聚变驱动器的色分离光栅-光束采样光栅集成元件

针对多次曝光法制作集成衍射光学元件时存在的加工制作复杂,会引入较大的对位误差等问题,基于计算全息中的误差扩散编码原理及部分相干光成像理论,提出采用误差扩散编码方法来设计用于制作浮雕结构集成元件的编码掩模的新方法。给出了利用误差扩散法设计的色分离光栅-光束采样光栅(CSG-BSG)集成元件编码掩模,模拟计算了经部分相干成像系统后的空间像光强分布,并与理想的集成元件面形进行了比较。结果表明,校正后均方差为7.5%,体积偏差为10.2%。     

改性纳米ZSM－5催化剂脱除汽油中烯烃的性能

 在考察ZSM－5沸石晶粒大小对脱除汽油中烯烃的影响的基础上，用纳米ZSM－5沸石作为活性组分负载Co－Mo氧化物制备了改性纳米ZSM－5沸石催化剂，并用XRF，NH3－TPD和TEM等方法对催化剂进行了表征．以脱除DCC汽油中的烯烃为探针反应，临氢条件下，在固定床反应器上对催化剂脱除烯烃的性能进行了评价，考察了反应温度、压力、质量空速和氢／油比对催化剂脱除烯烃性能的影响．结果表明，由于纳米ZSM－5沸石具有晶粒小、微孔短、扩散路程短以及表面酸中心数量多等特点，因而表现出较高的催化活性和较强的抗积碳性能．在V（H2）／V（oil）＝300，WHSV＝3h－1，p（H2）＝3．0MPa和θ＝350℃的适宜条件下，DCC汽油中烯烃的含量由60．7％下降到40％左右，芳烃和烷烃的含量增加；在脱除烯烃的同时可维持汽油的辛烷值不降低．催化剂连续运行1000h以上，其脱除烯烃的性能稳定．     

Sodium caseinate as a particulate emulsifier for making indefinitely recycled pH-responsive emulsions

pH-responsive emulsions are one of the simplest and most readily implementable stimuli-responsive systems. However, their practical uses have been greatly hindered by cyclability. Here, we report a robust pH-responsive emulsion prepared by utilizing pure sodium caseinate (NaCas) as the sole emulsifier. We demonstrate that the emulsification/demulsification of the obtained NaCas-stabilized emulsion can be triggered by simply changing the pH value over 100 cycles, which has never been observed in any protein-stabilized emulsion system. The NaCas-stabilized emulsion maintains its pH-responsive properties even in a saturated salt solution (NaCl ∼ 6.1 M) or seawater. We illustrate how NaCas functions in pH-responsive emulsions and show that when conventional nanoparticles such as zein protein or bare SiO₂ particles were coated with a layer of NaCas, the resulting formulated emulsions could be switched on and off over 10 cycles. The unique properties of NaCas thus enable the engineering of conventional Pickering emulsions to pH-responsive Pickering emulsions. Finally, we have integrated catalytically active gold (Au) nanoclusters (NCs) into the NaCas protein and then utilized them to produce emulsions. Remarkably, these NaCas–Au NCs assembled at the oil–water interface exhibited excellent catalytic activity and cyclability, not only in aqueous solution, but also in complicated seawater environments.

An unprecedented pH-responsive emulsion is shaped by utilizing pure sodium caseinate (NaCas) as the sole emulsifier for recyclable interfacial catalysis. This emulsion could be reversibly switched on and off over 100 cycles.