基于喹喔啉和吡啶并吡嗪及咔唑和二苯胺衍生物电子给体-受体结构荧光材料的合成和光电性能

通过α-二酮与邻苯二胺、吡啶二胺缩合反应,构建了喹喔啉和吡啶并吡嗪衍生物作为电子受体,分别以二苯胺、咔唑衍生物为电子给体,合成了 4个具有电子给体-电子受体结构的氮杂环荧光材料 F1~F4。通过低温荧光/磷光光谱、荧光寿命测试,结合密度泛函理论计算可知,F1~F4均为荧光小分子。室温荧光光谱结果表明,利用电子给体和受体的电子效应不同可以调控材料的发光颜色,其中三苯胺相对于苯基咔唑的供电子能力更强,表现为F1比F2、F3比F4红移现象更加明显;而吡啶并吡嗪具有多氮的缺电子结构,与喹喔啉相比共轭程度增加,导致 F3 比 F1、F4 比 F2 发生的斯托克斯位移数值增大。总之,F1~F4的甲苯溶液最大荧光光谱发射峰位于 529、464、568和 507 nm,荧光寿命分别为 12.21、2.61、9.76和 6.03 ns,荧光量子效率最高可达98.2%,具有良好的发光性能。将F1~F4发光材料掺杂在主体材料中制备了有机电致发光二极管DF1~DF4。所得器件DF1和DF3性能更好,最大电流效率分别为13.38和11.98 cd·A^-1,且最大外量子效率分别达到4.8%和4.5%。     

New cyclopiane diterpenes with anti-inflammatory activity from the sea sediment-derived fungus Penicillium sp. TJ403-2

Three new rare cyclopiane diterpenes(1-3),together with thirteen known compounds(4-16),were isolated and identified from a sea sediment-derived fungus Penicillium sp.TJ403-2.The planar and relative structures of compounds 1-3 were elucidated by HRESIMS,one-and two-dimensional NMR analyses,and their absolute configurations were further established by X-ray crystallography experiment.Compounds 1-3 were evaluated for the anti-inflammatory activity against LPS-induced NO production,and compound 1 showed notable inhibitory potency with an IC50 value of2.19±0.25μmol/L,which was three fold lower than the positive control indomethacin(IC50=8.76±0.92μmol/L).Further Western blot and immunofluorescence experiments demonstrated its mechanism of action to be that 1 inhibited the NF-κB-activated pathway,highlighting it as a promising starting point for the development of new anti-inflammatory agents.     

Pd掺杂的Ni催化剂表面CH4解离吸附的理论研究

使用密度泛函理论研究了Pd掺杂的Ni(111),Ni(100)和Ni(211)表面最稳定的结构,同时考察了干净的和Pd掺杂的Ni表面催化CH₄解离反应的活性.结果表明,由Pd原子取代最外层Ni原子而形成的表面Pd掺杂的Ni表面在热力学上最为稳定,亚表面Pd掺杂的Ni表面在热力学上都不稳定; 而对于表面Pd吸附的Ni表面,只有Pd/Ni(211)表面是稳定的.表面掺杂的Pd/Ni表面上CH₄解离中间体(CH₄,CH₃,CH,C,H)吸附能的计算结果表明,Pd的掺杂在不同程度上减弱了除CH₄之外各解离中间体的吸附能.另外,CH₄和CH均优先在Ni(211)和Pd/Ni(211)台阶面上解离,其次是在比较开阔的Ni(100)和Pd/Ni(100)表面上.Pd的掺杂不同程度上提高了CH₄和CH解离的能垒,对于活性最高的Ni(211)面,Pd的掺杂使得CH脱氢的能垒较CH₄脱氢的高,改变了其速率控制步骤,从而抑制了积碳的生成.     

EXISTENCE OF POSITIVE PERIODIC SOLUTION OF A DISCRETE TIME MUTUALISM SYSTEM WITH DELAYS

Discrete-time analogue of mutualism model is introduced. The discrete-time analogues is considered to be numerical discretization of the continuous-time models and we study their dynamical characteristics. It is shown that the discrete-time analogues preserve the periodicity of the continuous-time models.     

The existence of almost periodic solutions of certain perturbation systems

Certain almost periodic perturbation systems are considered in this paper. By using the roughness theory of exponential dichotomies and the contraction mapping principle, some sufficient conditions are obtained for the existence and uniqueness of almost periodic solution of the above systems. Our results generalize those in [J.K. Hale, Ordinary Differential Equations, Krieger, Huntington, 1980; C. He, Existence of almost periodic solutions of perturbation systems, Ann. Differential Equations 9 (1992) 173-181; M. Lin, The existence of almost periodic solution and bounded solution of perturbation systems, Acta Math. Sinica 22A (2002) 61-70 (in Chinese); W.A. Coppel, Almost periodic properties of ordinary differential equations, Ann. Math. Pura Appl. 76 (1967) 27-50; A.M. Fink, Almost Periodic Differential Equations, Lecture Notes in Math., vol. 377, Springer-Verlag, New York, 1974; Y. Xia, F. Chen, A. Chen, J. Cao, Existence and global attractivity of an almost periodic ecological model, Appl. Math. Comput. 157 (2004) 449-475].     

双束旁射虚阴极振荡器的粒子模拟

提出了虚阴极振荡器（Ｖｉｒｃａｔｏｒ）一种新的物理模型，用自己编写的两维半、全电磁、相对论性的粒子模拟程序ＷＧＣＦ模拟了两个对称虚阴极互相耦合振荡产生高功率微波（ＨＰＭ）的物理过程，激发的柱面波横向３６０°引出。通过大量的计算（包括单束情况）表明：（１）极距ｄ不变时，无论双束还是单束，比值Ｊ＿０／Ｊ＿ｃ在１２～２之间效率较高；（２）Ｊ＿０／Ｊ＿ｃ不变时，极距ｄ有一最佳值，大于或小于此值时效率略降低；（３）双束情况输出波型较纯净，无“直流”分量，单束情况却不然；（４）双束时频率增宽；（５）与一维情况不同，Ｊ＿０≈Ｊ＿ｃ时也会发生振荡，但直流成分较大。此外，我们对横向外边界的透射边界条件和辐射功率按模式、频率分布的表达式进行了推导。     

Existence of an exponential periodic attractor of a class of impulsive differential equations with time-varying delays

By using the continuation theorem due to Mawhin and Gaines, some analysis techniques and the Lyapunov functional method, the sufficient conditions ensuring the existence of an exponential periodic attractor of a class of impulsive differential equations with time-varying delays are established. The results are interesting and very different from previously known results [Xia and Wong, 2009 [7]; Tan and Tan, 2009 [19]; Huang et al., 2005 [20]; Liu and Huang, 2006 [22]]. Finally, applications and an example are given to illustrate the effectiveness of the results.     

Demonstration of a directed optical decoder using two cascaded microring resonators

We propose and demonstrate a directed optical decoder that can perform the decoding function from a two-bit electrical signal to a four-bit optical signal based on two cascaded microring resonators. We use two electrical signals regarded as a two-bit electrical signal to modulate the two microring resonators through the thermo-optic effect and four optical signals regarded as a four-bit optical signal appear at the output ports, respectively. The device operating at 10?kbps is demonstrated.