发光多孔硅表面微结构及其晶格畸变的实验研究

用电化学方法制备了不发光多孔硅和发光多孔硅,用X射线双晶衍射对两类多孔硅表面进行了微结构分析和晶体质量表征,实验表明两类多孔硅的微结构间存在着很大差别。不发光多孔硅表面对X射线的双晶衍射摇摆曲线可解叠成两个峰,它们分别来自样品多孔层和单晶硅衬底,而发光多孔硅对X射线的双晶衍射摇摆曲线呈高斯对称分布,不可解叠。发光多孔硅比不发光多孔硅表面晶体质量差,且电化学腐蚀越严重,表面晶体质量下降也越严重。     

运动目标空间位置坐标激光跟踪测量的数学模型

运动目标空间位置激光跟踪测量是国际计量测试领域的前沿课题，该测量系统集激光干涉测距、精密机械、计算机及控制系统和现代数值计算于一体，对空间运动目标进行跟踪并实时测量其坐标和姿态。它的测量范围为１～５ｍ，测量精度为５０μｍ／ｍ。它的测量原理主要是干涉法和三角法。在干涉法中，根据跟踪测量机构数量的多少又可分为一站法和多站法。一站法采用球坐标测量法，多站法通过解最小二乘方程组计算出被测点的坐标。文中对各种测量方法的数学理论模型进行了较为详细地论述。     

外控弱周期电位约束近似下电极BZ体系中极限环振荡的蜕变

在纯粹BZ反应体系的三变量Oregonator模型及电极过程动力学的基础上,建立了电极BZ反应体系的动力学模型.并在外控弱周期约束近似下,对这类电极BZ反应体系的慢流型上准定态进行了线性化稳定性分析;同时进一步对该类体系中有利于出现极限环振荡的范围进行了计算,绘制出了出现极限环振荡的参数区域.计算机模拟发现,由于外控电极电位的周期性变化,Pt电极反应相中出现极限环振荡的参数区域发生蜕变在极限环振荡区域内呈现的动力学行为是BZ反应的本征自组织行为,但其周期振幅已发生变异;而在振荡区域外体系则可出现对外控约束的纯粹响应性振荡,周期与外控约束电位振荡相同.     

高重复率电光调Q的高光束质量Nd∶YVO_4板条激光器

部分端面抽运混合腔板条激光器可以在紧凑的空间内实现大功率高光束质量的激光输出。利用这一技术并结合具有增益高、荧光寿命短等特点的Nd∶YVO4晶体 ,配合新型高重复率的电光Q开关 ,易于实现高频窄脉冲高光束质量的激光输出。在德国EdgeWaveGmbH进行了混合腔电光调Q激光器的合作研究中 ,实现了高重复率近衍射极限的输出 ;在以 5kHz的高重复率运转时 ,获得了单脉冲能量 7 2mJ ,脉宽 5 7ns,平均功率约 36W的脉冲 ;当重复率高达 5 0kHz时 ,输出的激光脉冲的参量是单脉冲能量 1.6mJ,脉宽 9 5ns,平均功率超过 80W。实验所测的光束质量因子M2 小于 2。     

Fe/CexZr0.9-xLa0.1O1.95-Al2O3 整体式催化剂上的甲烷催化燃烧反应

 采用共沉淀法制备了一系列 CexZr0.9-xLa0.1O1.95-Al2O3 储氧材料 (其中 CexZr0.9-xLa0.1O1.95 与 Al2O3 的质量比为 1; x = 0, 0.3, 0.5, 0.7 和 0.9), 以其为载体, 制备了一系列负载铁基整体式催化剂. 考察了该系列催化剂催化甲烷燃烧反应性能, 并用低温 N2 吸附-脱附、储氧能力测试、X 射线衍射和 H2 程序升温还原等手段对载体和催化剂进行了表征. 活性测试结果表明, 当 x = 0.7 时, 催化剂活性最高, 可在 V(CH4) = 1% 和 50 000 h1 条件下使甲烷 465 oC 起燃, 615 oC 完全转化. CexZr0.9-xLa0.1O1.95-Al2O3 样品同时具有较高的储氧能力、较高的比表面积和抗热老化能力. 当 x = 0.5 和 0.7 时, 催化剂载体以 CeZrLaAlO 固溶体存在, 抗老化能力最好, 且 x = 0.7 时, 催化剂最易被还原.     

LC-ESI-MS-MS Determination of Rat Plasma Protein Binding of Major Flavonoids of Flos Lonicerae Japonicae by Centrifugal Ultrafiltration

A simple, precise, accurate, selective, and sensitive reversed-phase LC–UV method has been developed for simultaneous analysis of diltiazem and non-steroidal anti-inflammatory drugs (NSAIDs) in the bulk drug, tablet dosage forms, and human serum. Chromatographic separation of the drugs was performed at ambient temperature on a C₁₈ stationary phase with 80:20 (v/v) methanol–water, pH 3.1 ± 0.02, as isocratic mobile phase. The mobile phase flow rate was initially 0.5 mL min^?1 then increased to 1 mL min^?1. All the NSAIDs were well separated from each other and from diltiazem. Total run time was 10 min. The assay was successfully applied to pharmaceutical formulations and serum and there was no chromatographic interference from tablet excipients. The method was linear in the range 1.25–50 μg mL^?1 both for diltiazem and the NSAIDs. The suitability of this HPLC method for quantitative analysis of the drugs was proved by validation in accordance with International Conference on Harmonization (ICH) guidelines. The validation results, and results from statistical analysis of the data, demonstrated the method was reliable.     

Thermodynamics of the gas-phase reactions in chemical vapor deposition of silicon carbide with methyltrichlorosilane precursor

The gas-phase reaction thermodynamics in the chemical vapor deposition system of preparing silicon carbide via methyltrichlorosilane pyrolysis is investigated with a relatively complete set of 226 species, in which the thermodynamic data of 163 species are evaluated in this work with accurate model chemistry G3(MP2) and G3//B3LYP calculations combined with standard statistical thermodynamics. The data include heat capacity (C _p,m ^θ ), entropy (S _m ^θ ), enthalpy of formation (Δ_f H _m ^θ ) and Gibbs free energy of formation (Δ_f G _m ^θ ). All the results are consistent with the available reliable experiments. Based on these thermodynamic data, the equilibrium concentration distribution of the 226 possible species in 300–2,000 K is evaluated with the chemical equilibrium principle under a typical experimental condition. It is shown that the theoretical results are in very good agreement with the experiments. We conclude that the present work is instructive for experiments with different conditions.     

解初值问题y"=g(x,y)的含参数块方法

1引言对于二阶常微分方程的初值问题y″=g(x,y),y(x_0)=y_0,y′(x_0)=y_0′,x_0(?)x(?)T(1)的数值解法的研究引起人们的广泛兴趣．对于直接积分(1),自从1976年J．D．Lambert和I．A．Waston提出二阶P-稳定方法和1978年G．Dahlquist证明P-稳定常系数线性多步方法的最高相容阶不超过2的重要结论以来,截止目前,已积累了许多高于2阶的P-稳定方法．例如,修正的Numerov方法,混合法(特殊形式RK的方法),多导法,Obrechkoff方法,显式RKN方法,单隐方法和对角隐式RKN方法等(顺便指出,文献[5,16]中所说的高阶方法的相容阶均不超过4)．所有这些方法,有些相     

Shape-controlled synthesis of ZnO nano- and micro-structures

A simple efficient thermal evaporation technique, oxidizing zinc foils and in situ evaporating at 700 °C in air without the presence of catalyst and carrier gas, was developed to control the growth of the different morphologies of ZnO nano- and micro-structures. Porous membrane, nanowires (or nanorods), nanobelts, nanoneedles, and tetrapods have been achieved through tuning the heating rates in a tube furnace. The morphologies and microstructures of samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. Our deterministic growth of different shapes of ZnO crystals offers ideal model system to study the physical properties.