全文获取类型
收费全文 | 1266篇 |
免费 | 35篇 |
国内免费 | 7篇 |
专业分类
化学 | 904篇 |
晶体学 | 9篇 |
力学 | 16篇 |
数学 | 98篇 |
物理学 | 281篇 |
出版年
2021年 | 13篇 |
2020年 | 10篇 |
2019年 | 17篇 |
2018年 | 18篇 |
2017年 | 14篇 |
2016年 | 17篇 |
2015年 | 20篇 |
2014年 | 17篇 |
2013年 | 76篇 |
2012年 | 64篇 |
2011年 | 66篇 |
2010年 | 42篇 |
2009年 | 32篇 |
2008年 | 90篇 |
2007年 | 87篇 |
2006年 | 80篇 |
2005年 | 76篇 |
2004年 | 49篇 |
2003年 | 55篇 |
2002年 | 46篇 |
2001年 | 25篇 |
2000年 | 16篇 |
1999年 | 15篇 |
1998年 | 11篇 |
1997年 | 17篇 |
1996年 | 18篇 |
1995年 | 16篇 |
1994年 | 15篇 |
1993年 | 13篇 |
1992年 | 11篇 |
1991年 | 12篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 6篇 |
1985年 | 16篇 |
1984年 | 24篇 |
1982年 | 12篇 |
1981年 | 17篇 |
1980年 | 15篇 |
1979年 | 24篇 |
1978年 | 10篇 |
1977年 | 11篇 |
1976年 | 9篇 |
1975年 | 14篇 |
1974年 | 12篇 |
1973年 | 10篇 |
1971年 | 5篇 |
1967年 | 5篇 |
排序方式: 共有1308条查询结果,搜索用时 15 毫秒
71.
Akio Urushima Dr. Daisuke Taura Makoto Tanaka Naomichi Horimoto Dr. Junki Tanabe Dr. Naoki Ousaka Prof. Tadashi Mori Prof. Eiji Yashima 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(19):7548-7556
A novel 2,6-anthrylene-linked bis(m-terphenylcarboxylic acid) strand ( 1 ) self-associates into a racemic double-helix. In the presence of chiral mono- and diamines, either a right- or left-handed double-helix was predominantly induced by chiral amines sandwiched between the carboxylic acid strands with accompanying stacking of the two prochiral anthracene linker units in an enantiotopic face-selective way, as revealed by circular dichroism and NMR spectral analyses. The photoirradiation of the optically active double helices complexed with chiral amines proceeded in a diastereo- (anti or syn) and enantiodifferentiating way to afford the chiral anti-photodimer with up to 98 % enantiomeric excess when (R)-phenylethylamine was used as a chiral double-helix inducer. The resulting optically active anti-photodimer can recognize the chirality of amines and diastereoselectively complex with chiral amines. 相似文献
72.
Akio Urushima Daisuke Taura Makoto Tanaka Naomichi Horimoto Junki Tanabe Naoki Ousaka Tadashi Mori Eiji Yashima 《Angewandte Chemie (International ed. in English)》2020,59(19):7478-7486
A novel 2,6‐anthrylene‐linked bis(m‐terphenylcarboxylic acid) strand ( 1 ) self‐associates into a racemic double‐helix. In the presence of chiral mono‐ and diamines, either a right‐ or left‐handed double‐helix was predominantly induced by chiral amines sandwiched between the carboxylic acid strands with accompanying stacking of the two prochiral anthracene linker units in an enantiotopic face‐selective way, as revealed by circular dichroism and NMR spectral analyses. The photoirradiation of the optically active double helices complexed with chiral amines proceeded in a diastereo‐ (anti or syn) and enantiodifferentiating way to afford the chiral anti‐photodimer with up to 98 % enantiomeric excess when (R)‐phenylethylamine was used as a chiral double‐helix inducer. The resulting optically active anti‐photodimer can recognize the chirality of amines and diastereoselectively complex with chiral amines. 相似文献
73.
74.
The potential barriers for the internal rotation of silole dimers are studied theoretically using the ab initio molecular orbital method at the RHF/6-31G** level of calculations. In 2,2′-bisilole, it is found that the anti-conformation is the most stable structure in the ground state and that the potential barrier height for rotation over the perpendicular conformation is 3.3 kcal/mol. © 1996 John Wiley & Sons, Inc. 相似文献
75.
Yoshinori SaitoYuriko Takashima Aya KamadaYurika Suzuki Midori SuenagaYasuko Okamoto Yoichi MatsunagaRyo Hanai Takayuki KawaharaXun Gong Motoo Tori Chiaki Kuroda 《Tetrahedron》2012,68(48):10011-10029
Root chemicals and DNA sequences were analyzed for Ligularia virgaurea collected in the northern Sichuan Province and adjacent areas of China. Thirty-eight samples were found to contain five chemotypes, two known and three new ones. From samples of the new chemotypes, 13 new compounds were isolated, including 3 sesquiterpene dimers and some rearranged eremophilanes. The DNA sequences suggested that the chemotype differentiation had a genetic origin. 相似文献
76.
Naoki Kise Yosei Takenaga Yohei Ishikawa Yoichi Morikami Toshihiko Sakurai 《Tetrahedron letters》2012,53(15):1940-1945
The reductive coupling of N-methoxycarbonyl lactams with benzophenone by Zn-TiCl4 in THF gave cross-coupled products as cyclic α-diphenylidene-N-methoxycarbonylamines and ring-opening α,α-diphenyl-α-hydroxy-ω-(N-methoxycarbonyl)amino ketones selectively depending on the reduction conditions. The reductive coupling of N-methoxycarbonyl lactams with 9-fluorenone by Zn-TiCl4 gave cyclic α-(9H-fluoren-9-ylidene)-N-methoxycarbonylamines preferentially irrespective to the conditions. 相似文献
77.
78.
79.
An insoluble and assembled catalyst of palladium and a non-cross-linked amphiphilic polymer were developed. In the presence of 50-500 ppm mol equiv of catalyst, the Suzuki-Miyaura reaction proceeded efficiently under organic solvent-free conditions. The catalyst was reused 10 times without any decrease in activity and was recycled without any special treatment.[structure: see text] 相似文献
80.