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71.
Kazuo Furihata Sakurako Shimotakahara Yoichi Shibusawa Mitsuru Tashiro 《Magnetic resonance in chemistry : MRC》2009,47(11):971-976
An efficient pulse sequence for observing the ligand signals resonating close to the water signal has been developed by incorporating the WET technique into the saturation transfer difference pulse sequence. Although several pulse sequences have been developed for observing a ligand binding with a protein receptor, the ligand signals resonating close to the water were undetectable owing to the interference of the huge water signal in the samples containing 95% 1H2O. On the point of sample preparation, it is preferable to avoid the solvent exchange in the protein samples. In the proposed pulse sequence, a WET sequence is incorporated for the selective suppression of the water resonance. The efficient water suppression and the clear observation of the bound ligand signals close to the water have been demonstrated using the lysozyme‐glucose complex. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
72.
This paper mainly focuses on refrigerant mixtures with relatively simple critical behavior, and presents a practical and useful method for the critical point calculation for the mixtures using mixture models based on Helmholtz energy equations of state. The expression for critical point criterion suitable for this objective is derived first. Numerical manipulations to obtain a physically correct solution are described in detail. For four binary refrigerant mixtures of difluoromethane (R-32) + pentafluoroethane (R-125), R-125 + 1,1,1,2-tetrafluoroethane (R-134a), R-125 + 1,1,1-trifluoroethane (R-143a), and R-32 + propane (R-290), the critical temperatures and critical molar volumes are calculated applying the presented method. The calculation results are compared with experimental values, and the capabilities of the mixture models for the mixtures in the critical region are discussed. 相似文献
73.
74.
Michael Andreas Tandiary Masashi Asano Taiki Hattori Satoshi Takehira Yoichi Masui Makoto Onaka 《Tetrahedron letters》2017,58(20):1925-1928
The solid acid, tin hydroxide-embedded montmorillonite, catalyzes the unprecedented alkylation of various silicon enolates with primary, secondary and tertiary benzylic alcohols as well as secondary allylic alcohols. The acid catalysis of Sn-Mont was not only higher than that of the other ion-exchanged montmorillonites (M-Mont; M = H, Ti, Fe and Al), but also higher than that of the typical homogeneous acid catalysts such as BF3·OEt2, TMSOTf and TfOH. 相似文献
75.
Yoichi Shibusawa Atsushi Shoji Chihiro Suzuka Akio Yanagida Yoichiro Ito 《Journal of chromatography. A》2010,1217(20):3457-3460
Nucleic acid constituents such as nucleobases, nucleosides and nucleotides were separated by counter-current chromatography using type J coil planet centrifuge. The separation was performed with a hydrophilic solvent system composed of 1-propanol/800 mM potassium phosphate buffer (pH 7.4) (1:1, v/v) by eluting the lower aqueous phase at a flow-rate of 0.5 ml/min. Eight selected nucleic acid constituents (4.0 mg, 0.5 mg of each), uridine monophosphate (UMP), adenosine monophosphate (AMP), deoxyadenosine monophosphate (dAMP), uridine, urasile, deoxy uridine, adenosine and adenine were well resolved within 160 min. 相似文献
76.
Sasaki S Kriener M Segawa K Yada K Tanaka Y Sato M Ando Y 《Physical review letters》2011,107(21):217001
A topological superconductor (TSC) is characterized by the topologically protected gapless surface state that is essentially an Andreev bound state consisting of Majorana fermions. While a TSC has not yet been discovered, the doped topological insulator Cu(x)Bi(2)Se(3), which superconducts below ~3 K, has been predicted to possess a topological superconducting state. We report that the point-contact spectra on the cleaved surface of superconducting Cu(x)Bi(2)Se(3) present a zero-bias conductance peak (ZBCP) which signifies unconventional superconductivity. Theoretical considerations of all possible superconducting states help us conclude that this ZBCP is due to Majorana fermions and gives evidence for a topological superconductivity in Cu(x)Bi(2)Se(3). In addition, we found an unusual pseudogap that develops below ~20 K and coexists with the topological superconducting state. 相似文献
77.
Laser action of the photo-thermo-refractive (PTR) glass, which is the photosensitive material for holographic recording of volume Bragg gratings (VBGs), was demonstrated for the first time by introducing Nd3?. Nd:PTR glass has a bandwidth of 27.8 nm and 16.0 nm for luminescence and absorption, respectively. An uncoated 2 mm thick Nd:PTR element generated cw laser output of 124 mW, with a slope efficiency of 25%, by laser diode pumping. This Nd:PTR glass also performed wide bandwidth laser action at 1053.9-1063.3 nm, where the decrease of the pump-absorption efficiency was held off below 30%, even under a 3.5 nm shift of pump wavelength from its absorption center. 相似文献
78.
Yoichi Hiraga 《Accreditation and quality assurance》1999,4(4):162-162
Japan Chemical Laboratory Accreditation (JCLA), a new accreditation body in chemical fields was established and the activities
and organization of JCLA are outlined. 相似文献
79.
Periodica Mathematica Hungarica - 相似文献
80.
Paul K. B. ALANIS Yusuke YAMAYA Akihiro TAKEUCHI Yoichi SASAI Yoshihiro OKADA Toshiyasu NAGAO 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2013,89(8):383-389
Taal Volcano is one of the most active volcanoes in the Philippines. The magnetotelluric 3D forward analyses indicate the existence of a large high resistivity anomaly (∼100 Ω·m) with a volume of at least 3 km × 3 km × 3 km, which is capped by a conductive layer (∼10 Ω·m), beneath the Main Crater. This high resistivity anomaly is hypothesized to be a large hydrothermal reservoir, consisting of the aggregate of interconnected cracks in rigid and dense host rocks, which are filled with hydrothermal fluids coming from a magma batch below the reservoir. The hydrothermal fluids are considered partly in gas phase and liquid phase. The presence of such a large hydrothermal reservoir and the stagnant magma below may have influences on the volcano’s activity. Two possibilities are presented. First, the 30 January 1911 explosion event was a magmatic hydrothermal eruption rather than a base-surge associated with a phreato-magmatic eruption. Second, the earlier proposed four eruption series may be better interpreted by two cycles, each consisting of series of summit and flank eruptions. 相似文献