首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   488篇
  免费   42篇
  国内免费   3篇
化学   376篇
晶体学   2篇
力学   7篇
数学   32篇
物理学   116篇
  2024年   1篇
  2023年   2篇
  2022年   8篇
  2021年   18篇
  2020年   19篇
  2019年   23篇
  2018年   12篇
  2017年   6篇
  2016年   27篇
  2015年   16篇
  2014年   26篇
  2013年   18篇
  2012年   39篇
  2011年   44篇
  2010年   24篇
  2009年   36篇
  2008年   29篇
  2007年   31篇
  2006年   30篇
  2005年   23篇
  2004年   16篇
  2003年   22篇
  2002年   13篇
  2001年   6篇
  2000年   7篇
  1999年   2篇
  1998年   4篇
  1997年   6篇
  1995年   3篇
  1993年   1篇
  1990年   2篇
  1989年   2篇
  1987年   1篇
  1985年   2篇
  1984年   1篇
  1979年   1篇
  1978年   3篇
  1977年   2篇
  1976年   2篇
  1975年   1篇
  1973年   1篇
  1972年   3篇
排序方式: 共有533条查询结果,搜索用时 250 毫秒
91.
As a model of polymer-sustained-alignment liquid crystal display (PSA-LCD), the liquid crystal (LC) cells having the polymer layers produced from monomers of phenanthrene (Phen)-carrying monomers, 2,7-, 3,8-, 1,8- and 3,6-dimethacryloyl-oxy-phenanthrene (DMAPhen), were prepared and investigated image sticking phenomenon with evaluations of residual direct current voltage (VrDC) and difference in pretilt angle before and after application of alternate current voltage (Δtilt). The VrDC values were small for the LC cells with the polymer layers produced from the Phen-carrying monomers used in this study. On the other hand, Δtilt depends on the molecular structure of the Phen-carrying monomer. The Δtilt values became small with increasing the linearity of the monomer structure for the Phen-carrying monomers. The findings would be useful for obtaining the small level of image sticking in the PSA-LCDs produced from the Phen-carrying monomers.  相似文献   
92.
Recent discoveries of new classes of self‐cleaving ribozymes in diverse organisms have triggered renewed interest in the chemistry and biology of ribozymes. Functional analysis and engineering of ribozymes often involve performing biochemical assays on multiple ribozyme mutants. However, because each ribozyme mutant must be individually prepared and assayed, the number and variety of mutants that can be studied are severely limited. All of the single and double mutants of a twister ribozyme (a total of 10 296 mutants) were generated and assayed for their self‐cleaving activity by exploiting deep sequencing to count the numbers of cleaved and uncleaved sequences for every mutant. Interestingly, we found that the ribozyme is highly robust against mutations such that 71 % and 30 % of all single and double mutants, respectively, retain detectable activity under the assay conditions. It was also observed that the structural elements that comprise the ribozyme exhibit distinct sensitivity to mutations.  相似文献   
93.
Alkyl‐substituted pyrrole‐based anion‐responsive π‐electronic systems formed supramolecular gels and liquid crystals through effective π–π stacking and van der Waals interactions. The addition of chloride as a planar cation salt afforded ion‐pairing assemblies as soft materials comprising planar receptor‐Cl? complexes and the cation.  相似文献   
94.
95.
Six new sesquiterpenoid quinones with an amino acid residue, metachromins L-Q (1-6), have been isolated from an Okinawan marine sponge Spongia sp. The structures and stereochemistry of 1-6 were elucidated on the basis of the spectroscopic data and chemical correlations. Metachromins L (1) and M (2) showed modest cytotoxicity.  相似文献   
96.
97.
98.
We prove the transcendence results for the infinite product , where Ek(x), Fk(x) are polynomials, α is an algebraic number, and r?2 is an integer. As applications, we give necessary and sufficient conditions for transcendence of and , where Fn and Ln are Fibonacci numbers and Lucas numbers respectively, and {ak}k?0 is a sequence of algebraic numbers with log‖ak‖=o(rk).  相似文献   
99.
Three new sesquiterpenoids, metachromins R--T (1--3), have been isolated from an Okinawan marine sponge Spongia sp. The structures and stereochemistry of 1--3 were elucidated on the basis of the spectroscopic data. Metachromins S (2) and T (3) showed modest cytotoxicity.  相似文献   
100.
Liquid–liquid equillibria (LLE) of the tertiary system of hydroxypropylated polyrotaxane (HPPR)–poly(vinyl alcohol) (PVA)–solvent have been investigated by focusing on the internal structures of HPPR–PVA blend gels. The phase diagrams of the HPPR–PVA aqueous systems displayed two liquid phases at a high concentration and molecular weight of PVA. This result was consistent with the prediction of the Flory–Huggins lattice model. On the contrary, the HPPR–PVA–DMSO system exhibited only a single phase. The HPPR–PVA blend gels crosslinked in dimethylsulfoxide (DMSO) were highly transparent over a wide concentration range, while the gels prepared in water were opaque at high polymer concentrations. Spherical domains were observed in the opaque gels by laser scanning confocal microscopy, and the sizes of the domains were significantly dependent on the amount of cross-linking reagent utilized. These results indicated that the transparency of the HPPR–PVA blend gels was strongly affected by the competition between the liquid–liquid two-phase separation and the crosslinking HPPR and PVA polymers during the preparation of the blend gels.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号