Effects of Different Extraction Methods on the Gelatinization and Retrogradation Properties of Highland Barley Starch

The purpose of this study was to compare the gelatinization and retrogradation properties of highland barley starch (HBS) using different extraction methods. We obtained HBS by three methods, including alkali extraction (A-HBS), ultrasound extraction (U-HBS) and enzyme extraction (E-HBS). An investigation was carried out using a rapid viscosity analyzer (RVA), texture profile analysis (TPA), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier-transform infrared spectrometry (FTIR). It is shown that the different extraction methods did not change the crystalline type of HBS. E-HBS had the lowest damaged starch content and highest relative crystallinity value (p < 0.05). Meanwhile, A-HBS had the highest peak viscosity, indicating the best water absorption (p < 0.05). Moreover, E-HBS had not only higher G′ and G″ values, but also the highest gel hardness value, reflecting its strong gel structure (p < 0.05). These results confirmed that E-HBS provided better pasting stability and rheological properties, while U-HBS provides benefits of reducing starch retrogradation.     

最小二乘法直线拟合基本假定的几点讨论

本文讨论物理实验中因不满足基本假定不宜用最小二乘法进行直线拟合的几种情况。     

Understanding the Palatability,Flavor, Starch Functional Properties and Storability of Indica-Japonica Hybrid Rice

The rice quality and starch functional properties, as well as the storability of three YY-IJHR cultivars, which included YY12 (biased japonica type YY-IJHR), YY1540 (intermedius type YY-IJHR) and YY15 (biased indica type YY-IJHR), were studied and compared to N84 (conventional japonica rice). The study results suggested that the three YY-IJHR varieties all had greater cooking and eating quality than N84, as they had lower amylose and protein content. The starch of YY-IJHR has a higher pasting viscosity and digestibility, and there was a significant difference among the three YY-IJHR cultivars. Rice aroma components were revealed by GC-IMS, which indicated that the content of alcohols vola-tile components of YY-IJHR were generally lower, whereas the content of some aldehydes and esters were higher than N84. In addition, YY-IJHR cultivars’ FFA and MDA contents were lower, which demonstrated that YY-IJHR had a higher palatability and storability than those of N84 in fresh rice and rice stored for 12 months. In conclusion, this study suggested that YY-IJHR had better rice quality and storability than N84. PCA indicated that the grain quality and storability of YY12 and YY15 were similar and performed better than YY1540, while the aroma components and starch functional properties of YY-IJHR cultivars all had significant differences.     

Stereocomplex Crystallization in Asymmetric Diblock Copolymers Studied by Dynamic Monte Carlo Simulations

Stereocomplex crystallization in asymmetric diblock copolymers was studied using dynamic Monte Carlo simulations, and the key factor dominating the formation of stereocomplex crystallites(SCs) was uncovered. The asymmetric diblock copolymers with higher degree of asymmetry exhibit larger difference between volume fractions of beads of different blocks, and local miscibility between different kinds of beads is lower, leading to lower SC content. To minimize the interference from volume fraction of beads, the SC formation in blends of asymmetric diblock copolymers was also studied. For the cases where the volume fractions of beads of different blocks are the same, similar local miscibility between beads of different blocks and similar SC content was observed. These findings indicate that the volume fraction of beads of different blocks is a key factor controlling the SC formation in the asymmetric diblock copolymers. The SC content can be regulated by adjusting the difference between the contents of beads of different blocks in asymmetric diblock copolymers.     

New Organoselenium (NSAIDs-Selenourea and Isoselenocyanate) Derivatives as Potential Antiproliferative Agents: Synthesis,Biological Evaluation and in Silico Calculations

In this study, we report on the synthesis of new organoselenium derivatives, including nonsteroidal anti-inflammatory drugs (NSAIDs) scaffolds and Se functionalities (isoselenocyanate and selenourea), which were evaluated against four types of cancer cell line: SW480 (human colon adenocarcinoma cells), HeLa (human cervical cancer cells), A549 (human lung carcinoma cells), MCF-7 (human breast adenocarcinoma cells). Among these compounds, most of the investigated compounds reduced the viability of different cancer cell lines. The most promising compound 6b showed IC₅₀ values under 10 μM against the four cancer cell lines, particularly to HeLa and MCF-7, with IC₅₀ values of 2.3 and 2.5 μM, respectively. Furthermore, two compounds, 6b and 6f, were selected to investigate their ability to induce apoptosis in MCF-7 cells via modulation of the expression of anti-apoptotic Bcl-2 protein, pro-inflammatory cytokines (IL-2) and proapoptotic caspase-3 protein. The redox properties of the NSAIDs-Se derivatives were conducted by 2, 2-didiphenyl-1-picrylhydrazyl (DPPH), bleomycin-dependent DNA damage and glutathione peroxidase (GPx)-like assays. Finally, a molecular docking study revealed that an interaction with the active site of thioredoxin reductase 1 (TrxR1) predicted the antiproliferative activity of the synthesized candidates. Overall, these results could serve as a promising launch point for further designs of NSAIDs-Se derivatives as potential antiproliferative agents.     

CdZnTe像素阵列探测器成像评价模型及实验

考虑载流子陷获效应建立了碲锌镉(CdZnTe)像素阵列探测器感应电荷分布模型,并从非平衡载流子连续方程出发,推导了晶体内部陷获载流子数密度分布,得到了CdZnTe探测器成像调制传递函数评价模型。数值计算结果表明：随入射光子能量的增加,探测器成像质量明显下降;当电子载流子与空穴载流子迁移寿命积范围分别为0.510-3 to 5.010-3 cm2/V,2.010-5 to 7.510-5 cm2/V时,电子载流子感应信号是探测器响应信号的主要来源,而空穴迁移寿命积变化对探测器成像性能的影响有限,所建立模型的载流子收集特性与实际探测器载流子收集特性相符。搭建了40 mm40 mm的CdZnTe成像探测系统,探测并获得了系统预采样调制传递函数。实验结果表明:模型理论值与实验数据相符合,实际CdZnTe晶体中存在的固有深能级缺陷、实验所采用的非单色性X射线源及较大的实际像素间隙是造成理论值与实验结果存在一定偏差的主要原因。     

《国民百科》机械条目在中、日的翻译与传播

钱伯斯的《国民百科》（Chambers's Information for the People）是传入中国的第一部西方百科全书,但只传入少数条目,其中机械条目于1857年传入中国,译为《重学浅说》.《国民百科》1871年传入日本,机械条目译为《重学》.本文通过机械条目中译本《重学浅说》,日译本《重学》与底本Chambers's Information for the People的对比研究,认为中译本《重学浅说》没有完整翻译且遗漏信息较多,日译本《重学》较为完整地反映了底本;日译本的术语及一些表达方式借鉴了中译本,也有自己的特点.另外,还有新的发现,对以往的部分研究成果予以补充及更正.     

剥离膜安装与空气动力学分析

在散裂中子源注入系统工作过程中,剥离膜是实现负氢离子转换为质子注入加速的关键部件。百nm到μm级厚度的剥离膜超薄易碎,安装及系统真空获得难度较高,一直是散裂中子源研究的重点。对比了国外膜片固定方式现状,通过设计剥离膜辅助安装装置,实现剥离膜样品批量安装;通过Fluent仿真分析,模拟得出膜片在不同进出口压差下真空获得过程中的压力分布、膜片附件空气扰动及系统空气流动,制定在不破坏剥离膜的前提下真空获得方案,并获得剥离膜系统超高真空环境。     

有耗介质空间完全匹配层吸收边界条件及其应用

针对Gedney提出的完全匹配层(PML)无法用于有耗各向同性计算域的截断及其对倏逝波的衰减不理想等问题,提出了一种扩展方法。扩展的PML的主要思想是在各向异性的PML中引入与有耗介质空间相一致的复介电常数和复磁导率,使之可以与有耗介质计算域相匹配。通过给PML的张量介电常数、张量磁导率增加衰减因子以加速倏逝波的衰减。构造了PML吸收效果验证模型,数值结果证明了扩展的PML在处理有耗介质计算域截断问题中的有效性。利用该吸收边界条件,采用时域有限差分法计算了电磁脉冲作用下地面铺设电缆的电磁脉冲响应,计算结果和试验结果取得了较好的一致。     

偏压电场作用下磁电弹板中Lamb波传播研究

基于磁电弹性材料的本构关系和运动微分方程,研究了磁电弹板中Lamb波的传播特性.在电磁开路和短路两种边界条件下,导出了偏压电场作用下磁电弹板中Lamb波的对称模态和反对称模态的相速度方程,求解了相应的应力场.通过数值算例分析了偏压电场对相速度和应力场的影响.结果表明,偏压电场对相速度有较大影响,对应力场几乎没有影响.研究成果可为设计磁电换能器提供一定的理论参考.