全文获取类型
收费全文 | 12063篇 |
免费 | 2309篇 |
国内免费 | 2341篇 |
专业分类
化学 | 9628篇 |
晶体学 | 244篇 |
力学 | 640篇 |
综合类 | 204篇 |
数学 | 1310篇 |
物理学 | 4687篇 |
出版年
2024年 | 29篇 |
2023年 | 236篇 |
2022年 | 377篇 |
2021年 | 527篇 |
2020年 | 555篇 |
2019年 | 571篇 |
2018年 | 466篇 |
2017年 | 520篇 |
2016年 | 650篇 |
2015年 | 673篇 |
2014年 | 840篇 |
2013年 | 1042篇 |
2012年 | 1176篇 |
2011年 | 1168篇 |
2010年 | 933篇 |
2009年 | 901篇 |
2008年 | 979篇 |
2007年 | 846篇 |
2006年 | 792篇 |
2005年 | 634篇 |
2004年 | 478篇 |
2003年 | 375篇 |
2002年 | 351篇 |
2001年 | 306篇 |
2000年 | 225篇 |
1999年 | 190篇 |
1998年 | 173篇 |
1997年 | 124篇 |
1996年 | 99篇 |
1995年 | 89篇 |
1994年 | 74篇 |
1993年 | 59篇 |
1992年 | 49篇 |
1991年 | 45篇 |
1990年 | 42篇 |
1989年 | 34篇 |
1988年 | 18篇 |
1987年 | 11篇 |
1986年 | 17篇 |
1985年 | 12篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1979年 | 3篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1959年 | 2篇 |
1957年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
921.
HL-2A装置激光吹气系统采用了全新自动控制的设计方法,实现了杂质注入量、靶片位移以及激光器被触发的时刻的精确自动控制.运行结果表明,该系统能把杂质的注入量控制在适当的水平,既不对等离子体约束产生影响,又便于光谱测量和杂质粒子输运研究.给出了激光吹气系统的设计,以及初步的实验结果. 相似文献
922.
923.
通过自行研制的光纤传感器对不同黏度液体中材料靶后的力学作用进行研究,获得了液体黏度变化对等离子体烧蚀力、射流冲击力及空泡生存周期的影响. 实验结果表明:液体黏度相同时,靶材所受冲击力幅值随作用激光能量的增加单调上升;液体黏度增加时,靶材所受的冲击力减小,靶材的空化空蚀程度亦减小;受液体黏度增大的影响,空泡膨胀或收缩过程减缓,相应的生存周期也增大. 此外,对空泡溃灭周期公式进行修正, 结果表明修正后的理论估算值与实验值的一致性较好. 相似文献
924.
Xiao-Fan Jiang Dr. Song-De Han Dr. A-Ni Wang Dr. Jie Pan Prof. Dr. Guo-Ming Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(4):1410-1415
The intermarriage of neutral and tripodal imidazole ligand, tris(4-(1H-imidazol-1-yl)phenyl)amine (TIPA), with zinc phosphite yields two hybrid phosphites, [Zn2(HPO3)2(TIPA)]⋅2 H2O ( 1 ) and [Zn3(HPO3)3(TIPA)]⋅6 H2O ( 2 ). Compound 1 has a hybrid sheet with neutral zinc-phosphite chains as supramolecular building blocks (SBBs), whereas 2 exhibits a 3D hybrid architecture with other neutral zincophosphite chains as supramolecular building blocks. The structural discrepancy between 1 and 2 is mainly due to the distinct linkage modes between organic TIPA ligands and inorganic zincophosphite chains. Interestingly, compounds 1 and 2 feature fast photochromism in response to UV light irradiation under ambient conditions. The discrepancy of photochromic performance between 1 and 2 is mainly due to the different geometrical configuration of the TIPA ligand. Different to majority of reported hybrid photochromic compounds driven by photochromic active units, the photochromism in 1 and 2 is derived from the electron transfer (ET) between phosphite and non-photochromic triimidazole-derivative ligand TIPA. Compared with the widely explored nonphotochromic polypyridine-derivative as electron acceptors (EAs), our work provides a new EA model for the design of hybrid photochromic materials based on the ligand-to-ligand ET mechanism. A multiple anti-counterfeiting application based on 1 and 2 was investigated. 相似文献
925.
Weizhong Yuan Jinchun Zhang Jingren Wei Hua Yuan Jie Ren 《Journal of polymer science. Part A, Polymer chemistry》2011,49(18):4071-4080
Novel and well‐defined amphiphilic dendrimer‐star copolymer poly(ε‐caprolactone)‐block‐(poly(2‐(2‐methoxyethoxy)ethylmethacrylate‐co‐oligo(ethylene glycol) methacrylate))2 with Y‐shaped arms were synthesized by the combination of ring‐opening polymerization (ROP) and atom transfer radical polymerization (ATRP). The investigation of thermal properties and the analysis of crystalline morphology indicate that the high‐branched structure of dendrimer‐star copolymers with Y‐shaped arms and the presence of amorphous P(MEO2MA‐co‐OEGMA) segments together led to the complete destruction of crystallinity of the PCL segments in the dendrimer‐star copolymer. In addition, the hydrophilicity–hydrophobicity transition of the dendrimer‐star copolymer film can be achieved by altering the external temperatures. The amphiphilic copolymers can self‐assemble into spherical nanomicelles in water. Because the lower critical solution temperature of the copolymers can be adjusted by varying the ratio of MEO2MA and OEGMA, the tunable thermosensitive properties can be observed by transmittance, dynamic laser light scattering, and transmission electron microscopy (TEM). The release rate of model drug chlorambucil from the micelles can be effectively controlled by changing the external temperatures, which indicates that these unique high‐branched amphiphilic copolymers have the potential applications in biomedical field. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
926.
927.
928.
929.
A novel and facile synthetic protocol for the construction of benzazepine and benzoxepine derivatives through a copper(I)‐catalyzed reaction of 2‐(2‐ethynylphenyl)‐1‐tosylaziridine or 2‐(2‐ethynylphenyl)oxirane with sulfonyl azides is disclosed. A ketenimine is the key intermediate during the reaction process. 相似文献
930.
Recently, thioredoxin reductase as a target for treatment of tumors has attracted the attention of scientists. 1,2‐[Bis(1,2‐benzisoselenazolone‐3(2 H)‐ketone)]ethane (ethaselen, BBSKE, PCT: CN02/00412), designed and synthesized previously, is an effective thioredoxin reductase inhibitor; presently it is in phase II clinical trials, targeting gastric cancer, lung cancer and colon cancer. To seek more novel and effective anticancer drugs, we have developed many selenazole‐based compounds. Evaluation of the thioredoxin reductase inhibitory effect and investigation of the mechanism of anticancer drugs require abundant thioredoxin reductase, but since commercial thioredoxin reductase is expensive its use is often limited. Therefore, the preparation of thioredoxin reductase is necessary. Base on the above investigation, in this work we have prepared thioredoxin reductase and evaluated selenazole‐based compounds, and found that 44 compounds have high inhibitory effect on thioredoxin reductase with IC50 < 10 µ m , of which 16 compounds have IC50 values below 1 µ m . This is helpful in investigating and elucidating the mechanism of this kind of compound. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献