全文获取类型
收费全文 | 24305篇 |
免费 | 3928篇 |
国内免费 | 2670篇 |
专业分类
化学 | 17038篇 |
晶体学 | 296篇 |
力学 | 1443篇 |
综合类 | 240篇 |
数学 | 2668篇 |
物理学 | 9218篇 |
出版年
2024年 | 78篇 |
2023年 | 504篇 |
2022年 | 821篇 |
2021年 | 835篇 |
2020年 | 988篇 |
2019年 | 907篇 |
2018年 | 755篇 |
2017年 | 728篇 |
2016年 | 1104篇 |
2015年 | 1038篇 |
2014年 | 1302篇 |
2013年 | 1678篇 |
2012年 | 2086篇 |
2011年 | 2091篇 |
2010年 | 1432篇 |
2009年 | 1373篇 |
2008年 | 1547篇 |
2007年 | 1411篇 |
2006年 | 1347篇 |
2005年 | 1092篇 |
2004年 | 879篇 |
2003年 | 734篇 |
2002年 | 630篇 |
2001年 | 531篇 |
2000年 | 530篇 |
1999年 | 598篇 |
1998年 | 499篇 |
1997年 | 433篇 |
1996年 | 442篇 |
1995年 | 396篇 |
1994年 | 358篇 |
1993年 | 325篇 |
1992年 | 270篇 |
1991年 | 231篇 |
1990年 | 235篇 |
1989年 | 160篇 |
1988年 | 123篇 |
1987年 | 88篇 |
1986年 | 104篇 |
1985年 | 65篇 |
1984年 | 37篇 |
1983年 | 41篇 |
1982年 | 37篇 |
1981年 | 21篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1976年 | 1篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
21.
Yaping Chen Dr. Kun Rui Prof. Jixin Zhu Prof. Shi Xue Dou Dr. Wenping Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(3):703-713
Developing clean and sustainable energies as alternatives to fossil fuels is in strong demand within modern society. The oxygen evolution reaction (OER) is the efficiency-limiting process in plenty of key renewable energy systems, such as electrochemical water splitting and rechargeable metal–air batteries. In this regard, ongoing efforts have been devoted to seeking high-performance electrocatalysts for enhanced energy conversion efficiency. Apart from traditional precious-metal-based catalysts, nickel-based compounds are the most promising earth-abundant OER catalysts, attracting ever-increasing interest due to high activity and stability. In this review, the recent progress on nickel-based oxide and (oxy)hydroxide composites for water oxidation catalysis in terms of materials design/synthesis and electrochemical performance is summarized. Some underlying mechanisms to profoundly understand the catalytic active sites are also highlighted. In addition, the future research trends and perspectives on the development of Ni-based OER electrocatalysts are discussed. 相似文献
22.
Single-crystalline gallium nitride nanobelts have been synthesized through the reaction of gallium vapor with flowing ammonia using nickel as a catalyst. The as-synthesized products were characterized using X-ray powder diffraction (XRD), scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, and selected-area electron diffraction (SAED). XRD and SAED results revealed that the products are pure, single-crystalline GaN with hexagonal structure. The widths and thickness of the nanobelts ranged from 80 to 200 nm, and 10 to 30 nm, respectively. The lengths were up to several tens of micrometers. The nanobelts had smooth surface with no amorphous sheath, and a sharp-tip end. The growth mechanism of nanobelts was discussed. 相似文献
23.
超临界流体色谱流程设计及其应用 总被引:1,自引:1,他引:0
本文设计了多功能超临界流体色谱流程,流程中包括毛细管/微填充柱SFC,GC,计算机控制温度、压力、密度及信号采集、处理,配置有超临界流体萃取池,解决了超临界流体色谱分流口易堵问题。利用该流程,将石腊、DC-200气相色谱固定相、黄油、蜂蜡、救心油、红花油等样品进行超临界流体色谱分离。 相似文献
24.
25.
26.
设计合成了用以检测过渡金属离子的荧光化学敏感器体系,它们是由1,8-萘二酰亚胺为荧光团,多胺衍生物为金属离子受体组成.在室温下对其光物理性质的研究中发现,在没有加入过渡金属离子时,由于体系内存在有效的光诱导电子转移过程使得荧光团的荧光被淬灭.加入过渡金属离子后,金属离子受体中的氮原子和过渡金属离子之间的配位作用阻断了光诱导电子转移过程,体系的荧光增强.不同的金属离子受体表现出了和过渡金属离子不同的配位识别能力,并且通过荧光的变化传递出受体-金属离子作用的信息. 相似文献
27.
We employ a first-principles plane wave method with the
relativistic analytic pseudopotential of Hartwigsen, Goedecker and Hutter
(HGH) scheme in the frame of DFT to calculate
the equilibrium lattice parameters and the thermodynamic properties of
AlB2 compound with hcp structure. The obtained lattice parameters are in
good agreement with the available experimental data and those calculated by
others. Through the quasi-harmonic Debye model, obtained successfully are
the dependences of the
normalized lattice parameters a/a0 and c/c0 on pressure P, the normalized
primitive cell volume V/V0 on pressure P, the variation of the thermal
expansion α with pressure P and temperature T, as well as the Debye
temperature \ThetaD and the heat capacity CV on pressure P and
temperature T. 相似文献
28.
Gang Wang Xiulin Zhu Zhenping Cheng Jian Zhu 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):2912-2921
A series of (di)picolinic acids and their derivates are investigated as novel complexing tridentate or bidentate ligands in the iron‐mediated reverse atom transfer radical polymerization of methyl methacrylate in N,N‐dimethylformamide at 100 °C with 2,2′‐azobisisobutyrontrile as an initiator. The polymerization rates and polydispersity indices (1.32–1.8) of the resulting polymers are dependent on the structures of the ligands employed. Different iron complexes may be involved in iron‐mediated reverse atom transfer radical polymerization, depending on the type of acid used. 1H NMR spectroscopy has been used to study the structure of the resulting polymers. Chain‐extension reactions have been performed to further confirm the living nature of this catalytic system. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2912–2921, 2006 相似文献
29.
〈I〉型三角剖分下非张量积连续小波基的构造 总被引:1,自引:0,他引:1
多维非张量积小波是近年小波研究领域中的热点问题之一 ,它们与多维张量积小波相比具有更多的优势 .关于高维张量积、非张量积小波 ,目前已有一些很好的工作 (见文[2 ] [3 ] [4 ] ) ,但关于样条小波 ,还有许多问题有待于研究 .本文针对〈I〉型三角剖分下的二维线性元空间 ,讨论其具有紧支集和对称性的半正交样条小波基 .给定 x1 x2 平面上的〈I〉型三角剖分 (图 1 ( a)所示 ) ,记 j=( j1 ,j2 ) ,| j| =j1 + j2 ,πm= { 0≤ |j|≤ mCj1j2 xj11 xj22 ,Cj1,j2 是任意实数 }为次数不超过 m的代数多项式全体 .引入剖分尺度为 1的线性元空间 V0… 相似文献
30.
A FUNDAMENTAL SOLUTION FOR THE LAPLACE OPERATOR ON THE QUATERNIONIC HEISENBERG GROUP 总被引:2,自引:0,他引:2
朱理 《数学物理学报(B辑英文版)》2002,22(3)
In this paper, the author studies the Laplace operator on the quaternionic Heisenberg group, construct a fundamental solution for it and use this solution to prove the Lp-boundedness and the weak (1-1) boundedness of certain singular convolution operators on the quaternionic Heisenberg group. 相似文献