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951.
Xiao-qing Liu Fang Kong Jia-li Liao Song-dong Ding Yuan-you Yang Huang Huang Shun-zhong Luo Guo-ping Liu Xing-liang Li Ji-jun Yang Jun Tang Ning Liu 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(3):1069-1076
The extraction kinetics of uranium(VI) and thorium(IV) with Tri-iso-amyl phosphate (TiAP) from nitric acid medium has been investigated using a Lewis Cell. Especially, dependences of the extraction rate on stirring speed, temperature, interfacial area were firstly measured to elucidate the extraction kinetics regimes. The experimental results demonstrated that extraction kinetic of U(VI) is governed by chemical reactions at interface with an activation energy, Ea, of 43.41 kJ/mol, while the rate of Th(IV) extraction is proved to be intermediate controlled, of which the Ea is 23.20 kJ/mol. Reaction orders with respect to the influencing parameters of the extraction rate are determined, and the rate equations of U(VI) and Th(IV) at 293 K have been proposed as $$ {\text{r}} = - {\text{dcUO}}_{ 2} \left( {{\text{NO}}_{ 3} } \right)_{ 2} /{\text{dt}} = 1. 80 \times 10^{ - 3} \left[ {{\text{UO}}_{ 2} \left( {{\text{NO}}_{ 3} } \right)_{ 2} } \right]^{ 1.0 1} \left[ {\text{TiAP}} \right]^{0. 5 5} , $$ $$ {\text{r}} = - {\text{dcTh }}\left( {{\text{NO}}_{ 3} } \right)_{ 4} /{\text{dt}} = 1. 8 8\times 10^{ - 3} \left[ {{\text{Th }}\left( {{\text{NO}}_{ 3} } \right)_{ 4} } \right]^{ 1.0 4} \left[ {\text{TiAP}} \right]^{ 1. 7 7} \left[ {{\text{HNO}}_{ 3} } \right]^{0. 3 8} , $$ respectively. 相似文献
952.
This paper proposes an adaptive parameter identification method
for breaking chaotic shift key communication from the
transmitted signal in public channel. The sensitive dependence
property of chaos on parameter mismatch is used for chaos adaptive
synchronization and parameter identification. An index function
about the synchronization error is defined and conjugate gradient
method is used to minimize the index function and to search the
transmitter's parameter (key). By using proposed method, secure key
is recovered from transmitted signal generated by low dimensional
chaos and hyper chaos switching communication. Multi-parameters can
also be identified from the transmitted signal with noise. 相似文献
953.
The heteropolytungstate (NH4)21{La(H2O)5[Ni(H2O)]2As4W40O140}·53H2O is obtained by the reaction of Na27[NaAs4W40O140]· 60H2O with NiCl2·6H2O, La(NO3)3·6H2O and NH4Cl at pH‐4.5. The structure and chemical composition are determined by X‐ray diffraction analysis and elemental analysis. The crystal data and main structure refinement are a = 1.9551(3) nm, b = 2.4156(4) nm, c= 3.7068(6) nm, β = 91.505(3)°, V = 17.500 (5) nm3, monoclinic crystal system with space group P21/n, Z = 4, R1 = 0.0573, wR2 = 0.0717 [I >2<s?(I)], R1, = 0.2463 and wR2 = 0.1199 (all data). [La(H2O)5] {Ni(H2O)}2AS4W40O140 has C2, symmetry. IR spectra of the ligand [NaAs4W40O140]27‐ and its three complexes were discussed. 相似文献
954.
The incompressible two-phase flows are simulated using combination of an etching multiblock method and a diffuse interface (DI) model, particularly in the complex domain that can be decomposed into multiple rectangular subdomains. The etching multiblock method allows natural communications between the connected subdomains and the efficient parallel computation. The DI model can consider two-phase flows with a large density ratio, and simulate the flows with the moving contact line (MCL) when a geometric formulation of the MCL model is included. Therefore, combination of the etching method and the DI model has potential to deal with a variety of two-phase flows in industrial applications. The performance is examined through a series of numerical experiments. The convergence of the etching method is firstly tested by simulating single-phase flows past a square cylinder, and the method for the multiphase flow simulation is validated by investing drops dripping from a pore. The numerical results are compared with either those from other researchers or experimental data. Good agreement is achieved. The method is also used to investigate the impact of a droplet on a grooved substrate and droplet generation in flow focusing devices. 相似文献
955.
A series of a-Si:H films are deposited by hot wire assisted microwave
electron cyclotron resonant chemical vapour deposition
(HW-MWECR-CVD), subsequently exposed under simulated illumination for
three hours. This paper studies the microstructure change during
illumination by Fourier Transformation Infrared (FTIR) spectra. There
are two typical transformation tendencies of microstructure after
illumination. It proposes a model of light induced structural change
based on the experimental results. It is found that all samples
follow the same mechanism during illumination, and intrinsic
structure of samples affect the total H content. 相似文献
956.
The structural and optical properties of the novel porous iron oxide fabricated by wood template have been investigated. The obtained porous iron oxide was characterized to be α- Fe2O3 by Fourier transform infrared and Raman spectroscopy. X-ray absorption fine structure measurement revealed that the bond length of Fe-O1 of the porous iron oxide has good agreement with that reported for the α- Fe2O3 crystal structure while the bond lengths for Fe-O2 and Fe-Fe deviate slightly from those of the α- Fe2O3 crystal structure. Photoluminescence from the porous iron oxide exhibited broad emission bands around 760 and 890 nm, which are believed to be due to the unique nanoscale structure of the porous iron oxide. 相似文献
957.
镍基合金-碳化铬复合涂层耐磨特性的研究 总被引:7,自引:1,他引:7
用真空熔烧法在45#钢表面制取了镍基合金-碳化铬复合涂层,用扫描电子显微镜和X射线衍射仪分析了这种涂层的微观结构、物相组成和性能,并对这种涂层的耐磨特性进行了试验研究.结果表明:镍基合金-碳化铬复合涂层与底材形成了牢固的冶金结合,同时还含有较高比例的硬质相;碳化铬的加入使涂层的耐磨性显著提高,在给定的试验条件下分别于干摩擦和20#机械油润滑时,镍基合金-碳化铬复合涂层的耐磨性比45#钢的分别高5倍和10倍以上 相似文献
958.
Dielectric microspheres can confine light in a three-dimensional (3D) region called photonic nanojet is shown when they are illuminated by different polarized beams. The influence of incident light polarization on photonic nanojet using the finite-difference time-domain (FDTD) method is demostrated. The axial field intensity profiles of photonic nanojets for both the linear and circular polarization incident beams are very similar. Azimuthal polarization incident beam induces a doughnut beam along the optical axis, while the radial polarization incident beam permits one to reach an effective volume as small as 0.7(λ/n) 3 . 相似文献
959.
Yanhong Ding Tian QiuXuan Liu Yi LongYongqin Chang Rongchang Ye 《Journal of magnetism and magnetic materials》2006
Under various amplitude of AC magnetic fields domain wall motion is the main mechanism in the magnetization process. This includes domain wall bulging and domain wall displacing. In this paper complex permeability-frequency spectra of (Fe1−xCox)73.5Cu1Nb3Si13.5B9 (x=0,0.5) nanocrystalline alloys were measured as a function of the AC magnetic field, ranging from 0.001 to 0.04 Oe. Obvious changes have been found in complex permeability spectra for alloy x=0 with the change of the amplitude of AC magnetic field, but variation of AC magnetic field has little effect on complex permeability spectra for alloy x=0.5. This is attributed to the increased pinning field after substitution of Fe with Co in Fe73.5Cu1Nb3Si13.5B9 nanaocrystalline alloy. 相似文献
960.
研究了超短超强激光脉冲与薄膜靶相互作用中产生的电子热发射.当超短激光脉冲与薄膜靶相互作用时,首先入射超短脉冲激光对吸收深度内的自由电子进行热激发,接下来热激发电子将能量传递到附近的晶格,再通过电子和晶格二体系的热传导,以及电子晶格间的热耦合,将能量传递到材料的内部.因此,电子在皮秒级甚至更短的时间内不能与晶格进行能量耦合,使电子温度超出晶格温度很多,电子热发射就变得非常明显了.用双温方程联合Richardson-Dushman方程的方法对飞秒脉冲激光照射金属靶的电子热发射进行了研究,结果发现电子热发射对飞 相似文献