首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   13884篇
  免费   2002篇
  国内免费   2800篇
化学   11691篇
晶体学   250篇
力学   561篇
综合类   214篇
数学   1394篇
物理学   4576篇
  2024年   45篇
  2023年   214篇
  2022年   464篇
  2021年   503篇
  2020年   515篇
  2019年   555篇
  2018年   459篇
  2017年   488篇
  2016年   634篇
  2015年   707篇
  2014年   891篇
  2013年   1182篇
  2012年   1253篇
  2011年   1343篇
  2010年   1022篇
  2009年   941篇
  2008年   1087篇
  2007年   995篇
  2006年   875篇
  2005年   721篇
  2004年   606篇
  2003年   490篇
  2002年   473篇
  2001年   426篇
  2000年   340篇
  1999年   268篇
  1998年   196篇
  1997年   136篇
  1996年   136篇
  1995年   121篇
  1994年   109篇
  1993年   83篇
  1992年   64篇
  1991年   61篇
  1990年   66篇
  1989年   30篇
  1988年   38篇
  1987年   19篇
  1986年   28篇
  1985年   24篇
  1984年   20篇
  1983年   16篇
  1982年   7篇
  1981年   6篇
  1980年   5篇
  1979年   5篇
  1976年   3篇
  1974年   2篇
  1973年   3篇
  1957年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Retractable structures which alter their geometries according to practical requirements are widely used in roof structures of stadiums for their versatility. A retractable structure based on threefold-symmetric Bricard linkages and rotating rings of tetrahedra is proposed and developed in this paper. By replacing each link of a threefold-symmetric Bricard linkage with a tetrahedron, a retractable structure is obtained which can repeatedly open and close by rotating the tetrahedra. The geometric relationship between the retractable structure and the threefold-symmetric Bricard linkage is derived and ranges of main geometric parameters are determined to ensure a continuous and smooth movement in the deployment of the structure. Then the relative displacement of the support and the open rate of the structure, two main parameters concerned in practical applications, are investigated. Preferred ranges of main geometric parameters are proposed and a physical model is manufactured to verify them. A discussion on some possible improvements and modifications of the structure is also presented.  相似文献   
22.
23.
瑶药野葛花中6种无机元素的测定   总被引:2,自引:0,他引:2  
用原子吸收光谱法测定野葛花原生药、野葛花汤剂中的 Ca、Mg、Cu、Zn、Fe、Mn等 6种无机元素含量。结果表明 ,原药和水煎液中 Ca、Mg含量比较丰富 ;各种元素的煎出率存在着较大的差异 ,其中 Cu、Zn、Fe的煎出率较高 ,Zn最高 ,达到了 82 .5 6 % ;Ca最低 ,为 5 .5 8%。并且将其结果与葛根的无机元素做了比较。为探讨无机元素与中药药效之间的关系提供了基础数据。  相似文献   
24.
Using pulse echo overlap measurement, the elastic behavior of amorphous carbon has been studied at ambient and low temperatures. The smaller ratio B/G of the bulk modulus to shear modulus and smaller Poisson's ratio σ at room temperature indicate that there is an intrinsic stiffening of transverse acoustic phonons in the amorphous carbon. The acoustic velocity and attenuation for longitudinal modes have been measured between 2.1 and 300 K at three frequencies of 7, 21 and 35 MHz, respectively. Their frequency and temperature dependence are observed. The elastic constant C11 increases with decreasing temperature and show enhanced stiffening at low temperatures. In the 130-220 K region, the abnormal change and effect of longitudinal velocity and attenuation with temperature and frequency, and a phase transition associated with structure relaxations are discussed.  相似文献   
25.
陈克应  方爱农 《数学学报》2003,46(3):581-590
本文在Q-正则Loewner空间中用环模不等式刻划了拟对称映射.另外,在 Q-维Ahlfors-David正则空间中建立了拟对称映射作用下的Grotzsch-Teichmuller型 模不等式,它是通过伸张系数的积分平均来表示.  相似文献   
26.
27.
In this paper we give a theorem of Grünwald-type for (0, 1,...,m-1) Hermite-Fejér interpolation (m=2, 4,...), which extends the famous result for a strongly normal system of nodes in the casem=2 given by Grünwald in [1].  相似文献   
28.
A viscosity-splitting scheme for the initial boundary value problems of the Navier-Stokes equations is considered. In the scheme, the Stokes equation is solved in conjunction with a nonhomogeneous boundary condition which connects the tangent flow with a no-slip flow. Convergence is proved.  相似文献   
29.
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007  相似文献   
30.
Crosslinked polymeric materials, which exhibit thermal remendability and removability through Diels–Alder (DA) and retro‐DA reactions, were obtained from using multifunctional maleimide and furan compounds as monomers. The synthesized monomers possess low melting points and good solubility in organo solvents to show excellent processing properties. The performance of DA and retro‐DA reactions were demonstrated with DSC and FTIR measurements. High performance of thermal remendablility and removability of the crosslinked materials were observed with SEM and solvent tests. These materials were applicable in advanced encapsulants and structural materials. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 905–913, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号