实验研究二维圆柱后尾流中涡脱落的有序和混沌现象

本文给出了在Re=50—400范围内二维圆柱后涡脱落的有序和混沌现象的一些初步实验结果。涡脱落由有序到混沌的转捩发生在Re=184.6—193.5之间,但是它不是通过准周期途径。在涡脱落频率与Re数的关系曲线上有两个间断。在Re=70处的间断可能对应于倾斜涡脱落模式的变化,在Re≈193.5处的第二间断对应于由有序到混沌状态的转捩。     

拉曼放大器中放大的自发拉曼散射与拉曼开-关增益关系的研究

研究了拉曼放大器中放大的自发拉曼散射对拉曼开－关增益的影响，并提出了一种利用自发拉曼散射谱来调整拉曼放大器位曼开－关增益平坦的方法，实验采用4个波长为14xx nm的激光二极管作为抽运源，75km的G．652光纤作为传输介质，获得了C波段附近的光放大，同时对此给出了合理的理论解释。     

Roles of rhenium diimine complexes as metal‐ion probes and photosensitizers in functional polyurethanes

Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10^?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003     

Synthesis of New 13-O-Acylavermectin Bl Aglycones

Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae.     

The First and Facile Synthesis of (±) Syringaresinol

The first and facile synthesis of (±)syringaresinol was described.     

Bounded Positive Solutions of Schrödinger Equations in Two-Dimensional Exterior Domains

We prove under quite general assumptions the existence of a bounded positive solution to the semilinear Schrödinger equation in a two-dimensional exterior domain.     

On potentially <Emphasis Type="Italic">H</Emphasis>-graphic sequences

For given a graph H, a graphic sequence π = (d ₁, d ₂,..., d _n) is said to be potentially H-graphic if there is a realization of π containing H as a subgraph. In this paper, we characterize the potentially (K ₅ − e)-positive graphic sequences and give two simple necessary and sufficient conditions for a positive graphic sequence π to be potentially K ₅-graphic, where K _r is a complete graph on r vertices and K _r-e is a graph obtained from K _r by deleting one edge. Moreover, we also give a simple necessary and sufficient condition for a positive graphic sequence π to be potentially K ₆-graphic. Project supported by National Natural Science Foundation of China (No. 10401010).     

Normalization and Fermi–Coulomb and Coulomb hole sum rules for approximate wave functions

For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007     

p+209Bi核反应微观数据的理论计算

利用光学模型、激光模型、蒸发模型及扭曲波玻恩近似理论,对入射能量从阈能到300MeV,p+²⁰⁹Bi的中子反应截面、剩余核截面、出射粒子的多重数进行了理论计算及分析,并将计算结果与实验数据进行了比较.同时得到一组能量到50?0MeV与实验数据符合很好的光学势参数.