首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   8848篇
  免费   1465篇
  国内免费   1050篇
化学   6344篇
晶体学   128篇
力学   479篇
综合类   53篇
数学   1203篇
物理学   3156篇
  2024年   26篇
  2023年   194篇
  2022年   351篇
  2021年   329篇
  2020年   353篇
  2019年   347篇
  2018年   301篇
  2017年   294篇
  2016年   461篇
  2015年   462篇
  2014年   602篇
  2013年   652篇
  2012年   839篇
  2011年   841篇
  2010年   539篇
  2009年   483篇
  2008年   559篇
  2007年   442篇
  2006年   457篇
  2005年   408篇
  2004年   347篇
  2003年   271篇
  2002年   238篇
  2001年   204篇
  2000年   133篇
  1999年   196篇
  1998年   133篇
  1997年   100篇
  1996年   123篇
  1995年   122篇
  1994年   98篇
  1993年   61篇
  1992年   57篇
  1991年   60篇
  1990年   70篇
  1989年   48篇
  1988年   29篇
  1987年   22篇
  1986年   29篇
  1985年   14篇
  1984年   14篇
  1983年   14篇
  1982年   8篇
  1981年   10篇
  1979年   3篇
  1976年   2篇
  1975年   2篇
  1974年   2篇
  1973年   2篇
  1928年   2篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
This paper analyses and models the dynamic interaction among permeable multi-cracks in a piezoelectric strip under anti-plane shear waves by the Schmidt method. The Fourier transform is applied and then two pairs of triple integral equations can be solved using the Schmidt method. The results show that the stress and the electric displacement intensity factors of cracks depend on not only the crack length and the piezoelectric coefficient, but also the thickness of the piezoelectric strip, the distance between multi-cracks and the frequency of incident wave.  相似文献   
32.
HL-1装置中LHCD和等离子体参数的关系   总被引:1,自引:1,他引:0  
本文研究了在HL-1托卡马克的不同放电阶段的低混杂波驱动特性。给出了驱动电流及驱动效率和等离子体参数,如电子平均密度ne、等离子体电流Ip及纵向磁场的关系。也给出和分析了波驱动和入射波功率的关系。在放电平段,对正反向驱动效率进行了研究和比较。  相似文献   
33.
The centrosymmetric structure of {Cd[S2CN(CH2Ph)2]2}2 features both bridging and chelating dithiocarbamate ligands so that a square pyramidal S5 coordination geometry results. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
34.
This paper applies the compensated compactnessmethod to the study of a class of quasilinear parbolic equations of higher order with doubly strong degeneration. Some existence and uniqueness results are proved under certain conditions.  相似文献   
35.
Cellulose carbamate, an environmentally friendly material presents an interesting alternative to petroleum-based polymers because of its renewable, biodegradable, biocompatible nature and its solubility in conventional solvents. In synthesis process of cellulose carbamate, urea was firstly impregnated into the cellulose pulp by supercritical CO2(scCO2), followed by the esterification of cellulose. The structure of cellulose carbamate was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The rheological properties of these cellulose carbamates in 9% sodium hydroxide solution were investigated, using a range of the nitrogen content, concentrations and shear rates.  相似文献   
36.
Cu nanotube arrays were fabricated by electroless deposition using porous anodic aluminium oxide membranes as templates. This was accomplished by a four-step procedure, i.e. pore-wall modification, polishing treatment, sensitization-activation and electroless deposition. The as-synthesized Cu nanotubes possess controllable inner diameter and open ends.  相似文献   
37.
Wear resistant Cu-based solid solution (Cuss) toughened Cr5Si3 metal silicide composite coatings were fabricated on austenitic stainless steel AISI321 by laser cladding process. Due to the rapidly solidified microstructural characteristics and the excellent toughening effect of Cuss on Cr5Si3, the Cuss/Cr5Si3 coatings have outstanding wear resistance and low coefficient of friction under room temperature dry sliding wear test conditions coupling with hardened 0.45% C steel.  相似文献   
38.
A series of branched/crosslinked sulfonated polyimide (B/C‐SPI) membranes were prepared and evaluated as proton‐conducting ionomers based on the new concept of in situ crosslinking from sulfonated polyimide (SPI) oligomers and triamine monomers. Chemical branching and crosslinking in SPI oligomers with 1,3,5‐tris(4‐aminophenoxy)benzene as a crosslinker gave the polymer membranes very good water stability and mechanical properties under an accelerated aging treatment in water at 130 °C, despite their high ion‐exchange capacity (2.2–2.6 mequiv g?1). The resulting polymer electrolytes displayed high proton conductivities of 0.2–0.3 S cm?1 at 120 °C in water and reasonably high conductivities of 0.02–0.03 S cm?1 at 50% relative humidity. In a single H2/O2 fuel‐cell system at 90 °C, they exhibited high fuel‐cell performances comparable to those of Nafion 112. The B/C‐SPI membranes also displayed good performances in a direct methanol fuel cell with methanol concentrations as high as 50 wt % that were superior to those of Nafion 112. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3751–3762, 2006  相似文献   
39.
A series of sulfonated poly(aryl ether ether ketone ketone)s statistical copolymers with high molecular weights were synthesized via an aromatic nucleophilic substitution polymerization. The sulfonation content (SC), defined as the number of sulfonic acid groups contained in an average repeat unit, could be controlled by the feed ratios of monomers. Flexible and strong membranes in sodium sulfonate form could be prepared by the solution casting method, and readily transformed to their proton forms by treating them in 2 N sulfuric acid. The polymers showed high Tgs, which increased with an increase in SC. Membranes prepared from the present sulfonated poly(ether ether ketone ketone) copolymers containing the hexafluoroisopropylidene moiety (SPEEKK‐6F) and copolymers containing the pendant 3,5‐ditrifluoromethylphenyl moiety (SPEEKK‐6FP) had lower water uptakes and lower swelling ratios in comparison with previously prepared copolymers containing 6F units. All of the polymers possessed proton conductivities higher than 1 × 10?2 S/cm at room temperature, and proton conductivity values of several polymers were comparable to that of Nafion at high relative humidity. Their thermal stability, oxidative stability, and mechanical properties were also evaluated. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2299–2310, 2006  相似文献   
40.
Two novel dithienylethenes with ferrocene units were synthesized by Wittig reaction. The structure of 2a has been established by X‐ray diffraction studies. They could reversibly interconvert between two thermally stable forms, an open and a closed one, using light of different wavelengths as triggers. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号