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121.
The metastable phase of well-faceted, hexagonal, prism-like molybdenum oxide hydrate (MoO3·0.55H2O) was successfully synthesized by evaporating molybdic acid solution prepared through cation membrane electrolysis of Na2MoO4·2H2O aqueous solution. The obtained crystals were characterized by X-ray diffraction (XRD), thermogravimetric (TG), scanning electronic microscopy (SEM) and photoluminescence (PL) spectrophotometry. The as-prepared MoO3·0.55H2O rods were of 2–4 μm in width and 5–12 μm in length. The MoO3·0.55H2O microrods displayed photoluminescence properties at room temperature and were transformed into stable orthorhombic α-MoO3 after air annealing at 380 °C. Moreover, the influence of temperature factor on the phase transformation process, morphology and photoluminescence properties of MoO3·0.55H2O was investigated in detail. 相似文献
122.
Ying Jie Shen Rui Jun Lan Yin Chang Zhao Chuan Peng Qian Tong Yu Dai Bao Quan Yao 《Journal of Russian Laser Research》2017,38(6):559-563
We design a continuous-wave Tm:YLF laser with a composite slab crystal end-pumped by two fiber-coupled laser diodes at room temperature. We achieve a maximum continuous wave output power of 105 W for the bonded slab Tm:YLF laser; the corresponding slope efficiency is 47.7% and the optical-to-optical conversion efficiency is 42.0% with respect to the incident pump power. The laser operated at 1,907.5 nm with a beam quality factor of M2 ~3.2 at the highest output power. 相似文献
123.
为了探究PVK对倒置平面异质结钙钛矿太阳能电池电子传输层的影响,向电子传输层PCBM中添加了一种富电子的聚乙烯基咔唑(PVK).采用原子力显微镜、PL光谱对薄膜进行了表征.实验结果表明:少量PVK的添加提高了覆盖在钙钛矿薄膜上PCBM层的平整度.当PVK的添加质量分数为4%时得到最佳器件效率,相比于纯PCBM作为电子传输层的器件,器件效率由(5.11±0.14)% 提升到(9.08±0.46)%.当PVK的添加质量分数大于4%时,粗糙度又趋于变大.PL光谱显示,少量PVK的加入使钙钛矿/电子传输层薄膜的PL强度降低,并使PL峰蓝移.研究表明:向PCBM中掺杂适量PVK能够改善钙钛矿/电子传输层/Al的界面接触,减少漏电流,并能够减少钙钛矿表面陷阱和晶界缺陷,减少电荷复合,从而提高了器件性能. 相似文献
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Pattern时延差编码水声通信体制利用信息码元的时延值调制信息,他的抗多途扩展干扰能力与码型种类及码型脉宽有关.扩频通信可获得扩频增益,可胜任远程水声通信,但其通信速率低是使用受限的重要原因.提出将扩频通信与Pattern时延差编码水声通信体制相结合,并采用M元扩频、多通道工作方式,构成一种新的适用于水声环境的通信方案,既可获得扩频通信的优良性能,又可提高通信速率.湖试结果验证了本文提出的M元混沌扩频多通道Pattern时延差编码水声通信方案的鲁棒性及可行性. 相似文献
129.
Structures and luminescence properties of Yb3+ in the double perovskites Ba2YB'O6 (B'=Ta5+, Nb5+) phosphors 下载免费PDF全文
The Yb3+ doped Ba2YB'O6 (B'=Ta5+, Nb5+) were prepared by high temperature solid-state reaction method, their structures were determined by x-ray diffraction and refined by Rietveld method. The diffuse reflection absorption, excitation and emission spectra of Yb3+:Ba2YB'O6 (B'=,Ta5+, Nb5+) were measured at room temperature. Under the excitation of ultraviolet light, these phosphors exhibit broad charge transfer band emissions of TaO6 or NbO6 centre with large Stokes shift. The Yb3+ doped into these hosts are situated at Y3+ sites of cubic symmetry (Oh). The experimental energy levels of Yb3+ in Ba2YTaO6 and Ba2YNbO6 were determined by photoluminescence and diffuse reflection absorption spectra. Their wavefunctions and theoretical energy levels were obtained by diagonalising the Hamiltonian matrix. The experimental energy levels were fitted by Levenberg--Marquardt iteration algorithm to determine crystal field parameters. Then, the magnetic-pole transition line strengths of Yb3+:Ba2YB'O6(B'=Ta5+, Nb5+) from (2F5/2)Γ8- to the low-energy states were calculated. 相似文献
130.
Zhigang Yin Nuofu Chen Shulin Song Jun Zhong Kurash Ibrahim 《Solid State Communications》2005,135(7):430-433
Nickel-doped ZnO (Zn1−xNixO) have been produced using rf magnetron sputtering. X-ray diffraction measurements revealed that nickel atoms were successfully incorporated into ZnO host matrix without forming any detectable secondary phase. Ni 2p core-level photoemission spectroscopy confirmed this result and suggested Ni has a chemical valence of 2+. According to the magnetization measurements, no ferromagnetic but paramagnetic behavior was found for Zn0.86Ni0.14O. We studied the electronic structure of Zn0.86Ni0.14O by valence-band photoemission spectroscopy. The spectra demonstrate a structure at ∼2 eV below the Fermi energy EF, which is of Ni 3d origin. No emission was found at EF, suggesting the insulating nature of the film. 相似文献