全文获取类型
收费全文 | 722篇 |
免费 | 28篇 |
国内免费 | 23篇 |
专业分类
化学 | 398篇 |
晶体学 | 10篇 |
力学 | 17篇 |
综合类 | 2篇 |
数学 | 61篇 |
物理学 | 285篇 |
出版年
2024年 | 5篇 |
2023年 | 14篇 |
2022年 | 20篇 |
2021年 | 22篇 |
2020年 | 19篇 |
2019年 | 14篇 |
2018年 | 12篇 |
2017年 | 10篇 |
2016年 | 24篇 |
2015年 | 19篇 |
2014年 | 13篇 |
2013年 | 36篇 |
2012年 | 38篇 |
2011年 | 47篇 |
2010年 | 23篇 |
2009年 | 25篇 |
2008年 | 28篇 |
2007年 | 26篇 |
2006年 | 29篇 |
2005年 | 37篇 |
2004年 | 37篇 |
2003年 | 34篇 |
2002年 | 33篇 |
2001年 | 17篇 |
2000年 | 5篇 |
1999年 | 12篇 |
1998年 | 13篇 |
1997年 | 20篇 |
1996年 | 14篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1985年 | 12篇 |
1984年 | 7篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 8篇 |
1975年 | 8篇 |
1974年 | 7篇 |
1973年 | 3篇 |
1967年 | 4篇 |
1965年 | 3篇 |
1964年 | 4篇 |
1961年 | 4篇 |
1934年 | 3篇 |
1924年 | 3篇 |
排序方式: 共有773条查询结果,搜索用时 15 毫秒
41.
Drutskoy A Abe K Abe K Abe T Aihara H Akatsu M Asano Y Aulchenko V Aushev T Bakich AM Ban Y Bay A Bedny I Behera PK Bizjak I Bondar A Bozek A Bracko M Browder TE Casey BC Chao Y Cheon BG Chistov R Choi Y Chuvikov A Danilov M Dash M Dong LY Eidelman S Eiges V Gabyshev N Garmash A Gershon T Golob B Haba J Hagner C Handa F Hastings NC Hayashii H Hazumi M Hinz L Hokuue T Hoshi Y Hou WS Huang HC Igarashi Y Iijima T Inami K Ishikawa A Itoh R Iwasaki H Iwasaki M Iwasaki Y Jang HK Kang JH Kang JS 《Physical review letters》2004,92(5):051801
The radiative decay B-->phi K gamma is observed for the first time. The branching fraction for the charged B--->phi K- gamma decay mode is measured to be B(B--->phi K- gamma)=(3.4+/-0.9+/-0.4)x10(-6). The photon energy distribution for the B--->phi K- gamma decay is presented. The signal for the neutral B(0)-->phi K(0)gamma decay mode is not statistically significant and an upper limit, B(B(0)-->phi K(0)gamma)<8.3x10(-6) at 90% C.L., is set. The analysis is based on a data set of 90 fb(-1) collected by the Belle experiment at the e(+)e(-) asymmetric collider KEKB. 相似文献
42.
Analysis of vasopressin using capillary electrophoresis with laser-induced fluorescence detector based on competitive immunoassay 总被引:1,自引:0,他引:1
A competitive immunoassay based on CE-LIF has been developed for the determination of vasopressin in biological mixtures. Vasopressin participates in the hormonal control of water metabolism and the constriction of arterioles in humans. Thus, detection of vasopressin is important in diagnosing pathological conditions and physiological water metabolism. The peptides were fluorescently tagged with FITC and purified by HPLC. The purified product was then mixed with the cerebrospinal fluid sample followed with the addition of anti-vasopressin antibody. It was possible to separate antibody-bound and free FITC-tagged vasopressin within 10 min by CE-LIF analysis using uncoated fused-silica capillary with high reproducibility. 相似文献
43.
Ban F Lundqvist MJ Boyd RJ Eriksson LA 《Journal of the American Chemical Society》2002,124(11):2753-2761
DNA-protein cross-linking is one of the many DNA lesions mediated by hydroxyl radicals, the most damaging among the reactive oxygen species in biological systems. Density functional theory methods are employed to investigate the complex reaction mechanisms of the formation of cytosine-tyrosine cross-links as observed in gamma-irradiated aqueous solutions of cytosine and tyrosine, as well as in gamma-irradiated nucleohistone. The majority of the radical addition mechanisms considered are found to have significant barriers and therefore to be thermodynamically unfavorable for the formation of the initial cross-linked product. Our calculated reaction potential energy surfaces suggest that a feasible complete mechanism consists of radical combination forming the initial cross-linked product, a hydrogen shuffle within the initial cross-linked product, and an acid-catalyzed dehydration reaction. Water and hydrogen-bonding interactions are suggested to play a key role in catalyzing the hydrogen-transfer step of the reaction. 相似文献
44.
Transparent aqueous sols of colloidal tetramethylammonium niobate nanocrystals were synthesized by mixing tetramethylammonium hydroxide (TMAOH), niobium ethoxide, and water at TMAOH/Nb≥0.7 at room temperature. The X-ray diffraction patterns of the thin films prepared by evaporating the colloidal solutions on a glass substrate indicated that the colloidal niobate had a layered crystalline structure. Two types of layered structures are known as a layered niobate, i.e. M(4)Nb(6)O(17)·nH(2)O and MNb(3)O(8) (M=H, H(3)O, or alkaline metal). Raman spectra and electron diffraction suggested that the niobate nanocrystals were similar in crystal structure to M(4)Nb(6)O(17)·nH(2)O compounds. Moreover, when niobium oxide thin films were fabricated from the niobate colloidal solutions by the sol-gel method, oriented T-Nb(2)O(5) thin films, whose c-axis was parallel to the substrate surface, were obtained. The orientation of the thin films was probably attributed to the layered structure of the colloidal niobate nanocrystals. 相似文献
45.
Masashi Ban 《International Journal of Theoretical Physics》2008,47(12):3267-3272
It is shown that a completely entangled state belonging to a finite dimensional Hilbert space is equivalent to a simultaneous eigenstate of two unitary operators. These operators are exponentials of sum and difference of two Hermitian operators of a two-mode system that are complementary with each other. 相似文献
46.
The experimental results obtained with the chalcogenide glass Ge15Te81S2As2 with imposed overall pressure up to 700 MPa are presented. The material exhibits the switching effect and the memory effect. It is shown that the overall pressure changes remarkably d.c. electrical conductivity of the amorphous semiconductor. It is assumed that the changes in conductivity are caused by changes in activation energy. The changes in activation energy within the range of considered pressures are, as follows from our measurements, E/p–10·95×10–5 eV/MPa +p × 10·41 W 10–7 eV/MPa2. The assumption of the activation energy dependence on pressurep are confirmed also by measurements of dependence In vs. 1/T at various pressures. 相似文献
47.
X. Fabian F. Mauger G. Quéméner Ph. Velten G. Ban C. Couratin P. Delahaye D. Durand B. Fabre P. Finlay X. Fléchard E. Liénard A. Méry O. Naviliat-Cuncic B. Pons T. Porobic N. Severijns J. C. Thomas 《Hyperfine Interactions》2015,232(1-3):87-95
We performed classical molecular dynamics (MD) simulations in order to search the conditions for efficient sympathetic cooling of highly charged ions (HCIs) in a linear Paul trap. Small two-component ion Coulomb crystals consisting of laser-cooled ions and HCIs were characterized by the results of the MD simulations. We found that the spatial distribution is determined by not only the charge-to-mass ratio but also the space charge effect. Moreover, the simulation results suggest that the temperature of HCIs do not necessarily decrease with increasing the number of laser-cooled ions in the cases of linear ion crystals. We also determined the cooling limit of sympathetically cooled 165Ho14+ ions in small linear ion Coulomb crystals. The present results show that sub-milli-Kelvin temperatures of at least 10 Ho14+ ions will be achieved by sympathetic cooling with a single laser-cooled Be+. 相似文献
48.
E. Liénard G. Ban C. Couratin P. Delahaye D. Durand X. Fabian B. Fabre X. Fléchard P. Finlay F. Mauger A. Méry O. Naviliat-Cuncic B. Pons T. Porobic G. Quéméner N. Severijns J. C. Thomas Ph. Velten 《Hyperfine Interactions》2015,234(1-3):1-7
The experimental achievements and the results obtained so far with the LPCTrap device installed at GANIL are presented. The apparatus is dedicated to the study of the weak interaction at low energy by means of precise measurements of the β ? ν angular correlation parameter in nuclear β decays. So far, the data collected with three isotopes have enabled to determine, for the first time, the charge state distributions of the recoiling ions, induced by shakeoff process. The analysis is presently refined to deduce the correlation parameters, with the potential of improving both the constraint deduced at low energy on exotic tensor currents (6He1+) and the precision on the V u d element of the quark-mixing matrix (35Ar1+ and 19Ne1+) deduced from the mirror transitions dataset. 相似文献
49.
50.
Benzoic acid as a source of proton is widely used in the technology of manufacture of proton exchanged ( PE) waveguide .But the diffusing speed of proton is too fast to make the waveguide stable in the pure benzoic acid. The characteristic of waveguide is improved with mixture of benzoic acid and lithium benzoate . 相似文献