全文获取类型
收费全文 | 34002篇 |
免费 | 5852篇 |
国内免费 | 4696篇 |
专业分类
化学 | 25716篇 |
晶体学 | 447篇 |
力学 | 1842篇 |
综合类 | 438篇 |
数学 | 3587篇 |
物理学 | 12520篇 |
出版年
2024年 | 73篇 |
2023年 | 678篇 |
2022年 | 1094篇 |
2021年 | 1112篇 |
2020年 | 1336篇 |
2019年 | 1353篇 |
2018年 | 1110篇 |
2017年 | 1068篇 |
2016年 | 1641篇 |
2015年 | 1652篇 |
2014年 | 1875篇 |
2013年 | 2444篇 |
2012年 | 3016篇 |
2011年 | 3207篇 |
2010年 | 2189篇 |
2009年 | 2062篇 |
2008年 | 2316篇 |
2007年 | 2194篇 |
2006年 | 2009篇 |
2005年 | 1813篇 |
2004年 | 1355篇 |
2003年 | 1188篇 |
2002年 | 1162篇 |
2001年 | 874篇 |
2000年 | 808篇 |
1999年 | 771篇 |
1998年 | 540篇 |
1997年 | 536篇 |
1996年 | 469篇 |
1995年 | 423篇 |
1994年 | 410篇 |
1993年 | 342篇 |
1992年 | 263篇 |
1991年 | 245篇 |
1990年 | 220篇 |
1989年 | 146篇 |
1988年 | 109篇 |
1987年 | 115篇 |
1986年 | 83篇 |
1985年 | 62篇 |
1984年 | 51篇 |
1983年 | 33篇 |
1982年 | 30篇 |
1981年 | 24篇 |
1980年 | 17篇 |
1975年 | 5篇 |
1974年 | 2篇 |
1973年 | 4篇 |
1957年 | 8篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
This paper is devoted to a detailed theoretical study of an ion pair SN2 reaction LiNCO+CH3F in the gas phase and in solution at the level of MP2(full)/6-31+G**//HF/6-31+G**. Two possible reaction mechanisms, inversion and retention, are discussed. There are eight possible reaction pathways. The inversion mechanism is more favorable no matter in the gas phase or in solution based on analyses of the transition structures. Methyl isocyanate should form preferentially in the gas phase and more stable methyl cyanate is the main product in solution. The retardation of the reaction in solvents was attributed to the difference in solvation in the separated reactants and in the transition state. 相似文献
62.
63.
S. H. Park J. H. Chang M. Yang H. S. Ahn S. N. Yi K. Goto M. W. Cho T. Yao J. S. Song 《Current Applied Physics》2004,4(6):607-610
Photoluminescence (PL) linewidth broadening of CdxZn1 − xSe/ZnSe triple quantum wells, grown on GaAs substrates by molecular beam epitaxy (MBE), has been investigated. Various quantum well (QW) samples have been prepared with different QW thickness and composition (Cd-composition). Measured and calculated PL linewidth are compared. Both composition and thickness fluctuations are considered for the calculation with the parameters such as the volume of exciton, nominal thickness and composition of QWs. Surface roughness measured by atomic force microscopy (AFM) is used to estimate the interface roughness. Results show that when Cd-composition increases additional linewidth broadening due to Zn/Cd interdiffusion is enhanced. 相似文献
64.
乐毅 《宁波大学学报(理工版)》2004,17(4):437-440
从正交各向异性三维弹性动力学的控制方程出发,在求得四边简支矩形板自由振动频率和位移振型的基础上,构造了受迫振动的位移函数;利用自由振动位移振型的正交性,将控制方程的空间变量和时间变量分离,得到了广义质量、广义力和频率表示的关于时间的2阶常微分方程,从而得到了正交各向异性弹性矩形板在受迫振动下的位移场和应力场.给出了本文方法与薄板理论的算例. 相似文献
65.
Wang Qing-Lun Zhao Bin Liao Dai-Zheng Yan Shi-Ping Cheng Peng Jiang Zong-Hui 《Transition Metal Chemistry》2003,28(3):326-330
The copper(II) complex Na2[Cu(pba)] · 6H2O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na+ bridge in the same layer. 相似文献
66.
67.
Briand et al. (Electron. Comm. Probab. 5 (2000) 101–117) gave a counterexample and proposition to show that given g,g-expectations usually do not satisfy Jensen's inequality for most of convex functions. This yields a natural question, under which conditions on g, do g-expectations satisfy Jensen's inequality for convex functions? In this paper, we shall deal with this question in the case that g is convex and give a necessary and sufficient condition on g under which Jensen's inequality holds for convex functions. To cite this article: Z. Chen et al., C. R. Acad. Sci. Paris, Ser. I 337 (2003). 相似文献
68.
A new stochastic method of reconstructing porous media 总被引:1,自引:0,他引:1
We present a new stochastic method of reconstructing porous medium from limited morphological information obtained from two-dimensional
micro- images of real porous medium. The method is similar to simulated annealing method in the capability of reconstructing
both isotropic and anisotropic structures of multi-phase but differs from the latter in that voxels for exchange are not selected
completely randomly as their neighborhood will also be checked and this new method is much simpler to implement and program.
We applied it to reconstruct real sandstone utilizing morphological information contained in porosity, two-point probability
function and linear-path function. Good agreement of those references verifies our developed method’s powerful capability.
The existing isolated regions of both pore phase and matrix phase do quite minor harm to their good connectivity. The lattice
Boltzmann method (LBM) is used to compute the permeability of the reconstructed system and the results show its good isotropy
and conductivity. However, due to the disadvantage of this method that the connectivity of the reconstructed system’s pore
space will decrease when porosity becomes small, we suggest the porosity of the system to be reconstructed be no less than
0.2 to ensure its connectivity and conductivity. 相似文献
69.
研究了具有非线性项|u|~αu的半线性波动方程的Cauclly问题,利用仿积分解及交换子估计等技术,证明了当α为一般的实数且满足一定的限制时,Cauchy问题自相似解的存在性。本文的结果回答了Planchon在其工作中所遗留的问题。 相似文献
70.
The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of etha- nolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystal- lizes in orthorhombic, space group P212121 with a = 6.048(2), b = 9.146(3), c = 21.955(7)(A), C9H11N3O7, Mr = 273.21, Z = 4, V = 1214.3(7)(A)3, Dc = 1.494 g/cm3, F(000) = 568, μ(MoKα) = 0.131 mm-1, R1 = 0.0338 and wR2 = 0.0497. The new organic adduct is composed of one ethanolamine and one 3,5-dinitrobenzoic acid, which are linked up by O-H…O and N-H…O types of hydrogen bonds to form a nine-membered ring and an eleven-membered ring, extending into a one-dimensional network structure. 相似文献