全文获取类型
收费全文 | 44043篇 |
免费 | 6450篇 |
国内免费 | 5152篇 |
专业分类
化学 | 31507篇 |
晶体学 | 471篇 |
力学 | 2539篇 |
综合类 | 528篇 |
数学 | 4816篇 |
物理学 | 15784篇 |
出版年
2024年 | 146篇 |
2023年 | 842篇 |
2022年 | 1352篇 |
2021年 | 1472篇 |
2020年 | 1658篇 |
2019年 | 1659篇 |
2018年 | 1395篇 |
2017年 | 1281篇 |
2016年 | 1997篇 |
2015年 | 2033篇 |
2014年 | 2353篇 |
2013年 | 3157篇 |
2012年 | 3834篇 |
2011年 | 3944篇 |
2010年 | 2567篇 |
2009年 | 2577篇 |
2008年 | 2736篇 |
2007年 | 2552篇 |
2006年 | 2383篇 |
2005年 | 2027篇 |
2004年 | 1568篇 |
2003年 | 1347篇 |
2002年 | 1345篇 |
2001年 | 1007篇 |
2000年 | 958篇 |
1999年 | 955篇 |
1998年 | 761篇 |
1997年 | 746篇 |
1996年 | 821篇 |
1995年 | 635篇 |
1994年 | 577篇 |
1993年 | 477篇 |
1992年 | 438篇 |
1991年 | 372篇 |
1990年 | 297篇 |
1989年 | 237篇 |
1988年 | 179篇 |
1987年 | 161篇 |
1986年 | 150篇 |
1985年 | 137篇 |
1984年 | 96篇 |
1983年 | 70篇 |
1982年 | 46篇 |
1981年 | 41篇 |
1980年 | 22篇 |
1978年 | 19篇 |
1977年 | 25篇 |
1976年 | 20篇 |
1975年 | 31篇 |
1974年 | 29篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
171.
Cross-lingual document retrieval, which aims to take a query in one language to retrieve relevant documents in another, has attracted strong research interest in the last decades. Most studies on this task start with cross-lingual comparisons at the word level and then represent documents via word embeddings, which leads to insufficient structure information. In this work, the cross-lingual comparison at the document level is achieved through the cross-lingual semantic space. Our method, MDL (deep multilabel multilingual document learning), leverages a six-layer fully connected network to project cross-lingual documents into a shared semantic space. The semantic distances can be calculated when the cross-lingual documents are transformed into embeddings in semantic space. The supervision signals are automatically extracted from the data and then used to construct the semantic space via a linear classifier. The ambiguity of manual labels could be avoided and the multilabel supervision signals can be acquired instead of a single label. The representation of the semantic space is enriched by multilabel supervision signals, which improves the discriminative ability of the embeddings. The MDL is easy to extend to other fields since it does not depend on specific data. Furthermore, MDL is more efficient than the models training all languages jointly, since each language is trained individually. Experiments on Wikipedia data showed that the proposed method outperforms the state-of-the-art cross-lingual document retrieval methods. 相似文献
172.
Facile construction of functional nanomaterials with laccase-like activity is important in sustainable chemistry since laccase is featured as an efficient and promising catalyst especially for phenolic degradation but still has the challenges of high cost, low activity, poor stability and unsatisfied recyclability. In this paper, we report a simple method to synthesize nanozymes with enhanced laccase-like activity by the self-assembly of copper ions with various imidazole derivatives. In the case of 1-methylimidazole as the ligand, the as-synthesized nanozyme (denoted as Cu-MIM) has the highest yield and best activity among the nanozymes prepared. Compared to laccase, the Km of Cu-MIM nanozyme to phenol is much lower, and the vmax is 6.8 times higher. In addition, Cu-MIM maintains excellent stability in a variety of harsh environments, such as high pH, high temperature, high salt concentration, organic solvents and long-term storage. Based on the Cu-MIM nanozyme, we established a method for quantitatively detecting phenol concentration through a smartphone, which is believed to have important applications in environmental protection, pollutant detection and other fields. 相似文献
173.
Xingxiu Yan Shengchun Wang Zhao Liu Yujie Luo Pengjie Wang Wenyan Shi Xiaotian Qi Zhiliang Huang Aiwen Lei 《中国科学:化学(英文版)》2022,65(4):762-770
Reported here is a precise electro-reduction strategy for radical defluorinative alkylation towards the synthesis of gem-difluoroalkenes from α-trifluoromethylstyrenes. According to the redox-potential difference of the radical precursors, direct or indirect electrolysis is respectively adopted to realize the precise reduction. An easy-to-handle, catalyst-and metal-free condition is developed for the reduction of alkyl radical precursors that are generally easier to be reduced than α-trifluorome... 相似文献
174.
175.
We study two aspects of higher dimensional operators in standard model effective field theory.We first introduce a perturbative power counting rule for the entries in the anomalous dimension matrix of operators with equal mass dimension.The power counting is determined by the number of loops and the difference of the indices of the two operators involved,which in turn is defined by assuming that all terms in the standard model Lagrangian have an equal perturbative power.Then we show that the operators with the lowest index are unique at each mass dimension d,i.e.,(H~?H)~(d/2)for even d≥4,and(L~TεH)C(L~TεH)~T(H~?H)~((d-5)/2)for odd d≥5.Here H,L are the Higgs and lepton doublet,andε,C the antisymmetric matrix of rank two and the charge conjugation matrix,respectively.The renormalization group running of these operators can be studied separately from other operators of equal mass dimension at the leading order in power counting.We compute their anomalous dimensions at one loop for general d and find that they are enhanced quadratically in d due to combinatorics.We also make connections with classification of operators in terms of their holomorphic and anti-holomorphic weights. 相似文献
176.
Feng Xia Yanrong Zhao Meijun Xing Zhenning Sun Yizhou Huang Jianghua Feng Guiping Shen 《Molecules (Basel, Switzerland)》2022,27(9)
The difference of nutrient composition between organic eggs and conventional eggs has always been a concern of people. In this study, 1H nuclear magnetic resonance (NMR) technique combined with multivariate statistical analyses was conducted to identify the metabolite different in egg yolk and egg white in order to reveal the nutritional components information between organic and conventional eggs. The results showed that the nutrient content and composition characteristics were different between organic and conventional eggs, among which the content of glucose, putrescine, amino acids and their derivatives were found higher in the organic eggs yolk, while phospholipids were demonstrated higher in conventional eggs yolk. Organic acid, alcohol, amine, choline and amino acids were higher in conventional eggs white, but glucose and lactate in organic egg were higher. Our study demonstrated that there are more nutritive components and higher nutritional value in organic eggs than conventional eggs, especially for the growth and development of infants and young children, and conventional eggs have more advantages in promoting lipid metabolism, preventing fatty liver, and reducing serum cholesterol. Eggs have important nutritional value to human body, and these two kinds of eggs can be selected according to the actual nutrient needs. 相似文献
177.
We report on our study of the interactions between coconut protein extracted from coconut meat and three hydrocolloids (gelatin, xanthan gum, and soybean polysaccharide) and their interfacial adsorption and emulsification properties. We used Zeta potential, fluorescence spectroscopy scanning and ITC to investigate the interactions between a fixed concentration (1%) of coconut protein and varying concentrations of hydrocolloid. Through the interfacial tension and interfacial viscoelasticity, the interfacial properties of the hydrocolloid and coconut protein composite solution were explored. The physical stability of the corresponding emulsion is predicted through microstructure and stability analysis. Xanthan gum forms a flocculent complex with coconut protein under acidic conditions. Soy polysaccharides specifically bind to coconut protein. Under acidic conditions, this complex is stabilized through the steric hindrance of soy polysaccharides. Due to gelatin-coconut protein interactions, the isoelectric point of this complex changes. The interfacial tension results show that as time increases, the interfacial tensions of the three composite solutions decrease. The increase in the concentration of xanthan gum makes the interfacial tension decrease first and then increase. The addition of soybean polysaccharides reduces the interfacial tension of coconut protein. The addition of xanthan gum forms a stronger elastic interface film. Emulsion characterization showed that the gelatin-added system showed better stability. However, the addition of xanthan gum caused stratification quickly, and the addition of soybean polysaccharides also led to instability because the addition of polysaccharides led to a decrease in thermodynamic compatibility. This research lays the foundation for future research into coconut milk production technology. 相似文献
178.
Wang R Huang J Ma T Zhang Q 《The Journal of the Acoustical Society of America》2010,128(6):EL361-EL365
This letter presents an improved space time prewhitening method for linear frequency modulation (LFM) reverberation. The proposed method transforms the reverberation to fractional Fourier domain to whiten using fractional Fourier transform. The linear varying frequency in LFM reverberation is focused on a stationary frequency, and the adjacent block signal is used as the reference signal of prewhitening. Finally, experiment results with real reverberation data verify that the proposed method improves the detection performance of active sonar in shallow sea significantly. 相似文献
179.
Ji-Wu Huang Chuang-Jun Li Jing-Zhi Yang Chuan Li Yu Zhang Ke Liu Yue Yu Jian-Dong Jiang Dong-Ming Zhang 《中国化学》2021,(5):1129-1137
Main observation and conclusion
Eight new polycyclic phloroglucinol meroterpenoids guajamers A-H (1-8),a methylated benzoylphloroglucinol meroterpenoid guajamer... 相似文献
180.
Benefiting from the environmental friendliness of organic electrodes and the high security of aqueous electrolyte,an all-organic aqueous potassium dual-ion full... 相似文献