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91.
An efficient solid-phase methodology has been developed for the synthesis of 2-aminobenzoxazole derivatives. The key step in this procedure involves preparation of polymer-bound 2-mercaptobenzoxazole resins 3 by reaction of the Merrifield resin with 2-aminophenols and CS(2) in the presence of DIC in MeCN. Oxidation of the resulting resins followed by treatment with amines gives the desired 2-aminobenzoxazole products 5. Further diversification can be introduced to the key resin 11, derived from the nitro group containing resin 3c. This process produces the corresponding amine, which upon reaction with acid chlorides and isocyanates can be used to generate various 6-functionalized 2-aminobenzoxazole analogues 13 and 15. 相似文献
92.
Tae Hee Kim Jai Keun Kim Wooyoung Shim Sun Yong Kim Tae Jun Park Jae Yeon Jung 《Magnetic resonance imaging》2010
In vivo visualization of transplanted stem cells with noninvasive technique is essential for the monitoring of cell implantation, homing and differentiation. At present, superparamagnetic iron oxide (SPIO) is most commonly used for cell labeling. However, stem cells lack phagocytic capacity and transfection agent is required for sufficient internalization of SPIO for cellular imaging. However, the potential hazards of transfection agents are not fully investigated. Instead of SPIO, we used commercially available new tagging material, fluorescent magnetic nanoparticle (MNP) containing rhodamine B isothiocyanate within a silica shell (Biterials, Seoul, Korea). This tagging material does not require transfection agents for the cell labeling. In addition to that, the core of this MNP is composed of ferrite and the inner portion of silica shell contains fluorescent materials, therefore, it has both magnetic and optical features. This study was designed to track intrasplenically injected bone marrow mesenchymal stem cells (MSCs) labeled with fluorescent MNP in liver cirrhosis rat model with 3-T magnetic resonance equipment. We compared magnetic resonance imaging (MRI) of livers in rats which were injected with non-labeled stem cells or labeled stem cells with MNP or SPIO. We found that the respective liver-to-muscle contrast-to-noise ratios at 3 and 5 h after MNP or SPIO-labeled stem cell injection was significantly lower than that of pre-injection and non-labeled group. There was no significant difference between MNP-labeled group and SPIO-labeled group. We can effectively detect intrasplenically injected MNP-labeled MSCs in an experimental rat model of liver cirrhosis with 3-T MRI. 相似文献
93.
Yeon Hwa Jo 《Applied Surface Science》2010,256(22):6819-6823
This work reports unexpected crystallization and segregation behavior of CuIn0.7Ga0.3Se2 (CIGS) thin films deposited on flexible Cu foils by pulsed laser deposition. A composite-type microstructure containing nanometer-scaled CIGS crystallites embedded in amorphous Cu-rich matrix is observed even at the high temperature of 500 °C. The findings are attributed to very fast condensation of the ablated species and random nucleation induced from the amorphous matrix. Cu-rich particulates tend to precipitate on the film surface, and their average size, shape, number density and composition exhibit a strong dependence on the substrate temperature up to 500 °C. The similar crystallization properties of the films on Cu foils and glass substrates are noticeable to the use of Cu foils for flexible solar cells. 相似文献
94.
Han Mo Jeong Ah Young Jo Mi Yeon Choi Man Jae Han Jae Young Jho 《Journal of Macromolecular Science: Physics》2013,52(5):789-799
The characteristics and performance of an ionic polymer–metal composite (IPMC), prepared with an anion‐exchange acrylic copolymer, was examined. The acrylic copolymer was synthesized by the radical copolymerization of fluoroalkyl methacrylate and 2‐(dimethyl amino)ethyl methacrylate(AMA). Effects of the AMA repeating unit's content in the copolymer and effects of the anion type present on the actuation of the IPMC were observed. The optimal content of 19.4 wt% AMA in the IPMC copolymer yielded the best actuation. The actuation also improved according to the type of anion present in the composite, in the following order: Br???4 ?. 相似文献
95.
Yeon Hyang Kim 《Journal of Fourier Analysis and Applications》2013,19(4):857-876
The problem of estimating the AP-norm of univariate almost-periodic functions using a Gabor system or a wavelet system was studied by several authors, and culminated in the characterization given in a recent paper of the present author. The present article unifies and generalizes the various efforts via the study of this problem in the context of (multivariate) generalized shift-invariant (GSI) systems. The main result shows that the sought-for norm estimation of the AP functions is valid if and only if the given GSI system is an $L_{2}({\mathbb{R}}^{d})$ -frame. Moreover, the frame bounds of the system are also the sharpest bounds in our estimation. 相似文献
96.
Marcela R. Beltrán Fernando Buendía Zamudio Vikas Chauhan Prasenjit Sen Haopeng Wang Yeon Jae Ko Kit Bowen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2013,67(3):1-8
We present an analysis of Na-He collisional profiles at high density and very low temperature in a unified line shape semi-classical theory which contains the impact as well the quasistatic limits. Clearly understanding the variation of shape of the two fine-structure components of the 3s?3p line with increasing helium density allows us to understand experimental spectra of a Na atom attached to He nanodroplets. We compare our collisional approach to path integral Monte Carlo calculations using the same ab initio Na-He molecular potentials. 相似文献
97.
Amol Maruti Jadhav Sandip Gangadhar Balwe Jong Su Kim Kwon Taek Lim Yeon Tae Jeong 《Tetrahedron letters》2019,60(7):560-565
An efficient, inexpensive and environmentally friendly synthesis of novel 3-amino-2-benzoyl-1-aryl-1H-pyrazolo[1,2-b]phthalazine-5,10-dione and 3-amino-2-benzoyl-1-aryl-1H-pyrazolo[1,2-a]pyridazine-5,8-dione derivatives has been developed via one-pot three-component reaction of phthalhydrazide or maleic hydrazide, aldehydes and arylacetonitrile in the presence of catalytic amount of InCl3 as a Lewis acid catalyst under solvent-free conditions. The most important features of the present protocol are mild reaction conditions, short reaction times, high yields, and a wide range of functional group tolerance. 相似文献
98.
Electrochemical oxidative radical sulfonylation/semipinacol rearrangement sequences of alkenylcyclobutanols have been developed. The reaction proceeds in an undivided electrochemical cell equipped with platinum plate electrodes employing sodium iodide as a redox catalyst and a supporting electrolyte. This approach is environmentally benign by using shelf-stable arylsulfonyl hydrazides as arylsulfonyl radical precursor and electrons as oxidizing reagents. The present protocol offers a facile way to prepare β-sulfonated cyclic ketone derivatives. 相似文献
99.
A convenient and highly efficient method for the synthesis of novel polyheterocyclic chromeno pyrimido[1,2-b]indazolone derivatives via a three-component condensation of 1H-indazol-3-amine, aldehydes and 4-hydroxycoumarin catalyzed by Bronsted acid ionic liquid [Et3NH][HSO4] under solvent-free reaction conditions is presented. This ionic liquid is air and water stable and easy to prepare from amine and acid. The main advantages of this protocol includes short reaction time, excellent yield, easy work-up, operational simplicity, a wide range of functional group tolerance and column chromatography-free method. The catalyst can be recovered and reused for at least four runs without any significant impact on the product yields. 相似文献
100.
The SU(1,1) coherent states, so-called Barut-Girardello coherent state and Perelomov coherent state, for the generalized two-mode time-dependent quadratic Hamiltonian system are investigated through SU(1,1) Lie algebraic formulation. Two-mode Schrödinger cat states defined as an eigenstate of $\hat{K}_{-}^{2}The SU(1,1) coherent states, so-called Barut-Girardello coherent state and Perelomov coherent state, for the generalized two-mode
time-dependent quadratic Hamiltonian system are investigated through SU(1,1) Lie algebraic formulation. Two-mode Schr?dinger
cat states defined as an eigenstate of
are also studied. We applied our development to two-mode Caldirola-Kanai oscillator which is a typical example of the time-dependent
quadratic Hamiltonian system. The time evolution of the quadrature distribution for the probability density in the coherent
states are analyzed for the two-mode Caldirola-Kanai oscillator by plotting relevant figures. 相似文献