Surface modification of polyimide films, filter papers, and cotton clothes by HMDSO/toluene plasma at low pressure and its wettability

This study demonstrates the hydrophobic and super-hydrophobic coating of various substrates by 3:1 HMDSO/toluene glow plasma discharge at low pressure and investigates the hydrophobic and super-hydrophobic behavior of the polyimide films, filter papers, and cotton clothes. The effect of 3:1 HMDSO/toluene plasma treatments on the surface of polyimide films, filter papers, and cotton clothes were investigated in terms of total surface free energy by measuring the contact angles with probe liquids. In representation, the total surface free energies of the polyimide films before and after the 3:1 HMDSO/toluene plasma modification estimated from the Owens–Wendt equation decreased from 44.5 mN/m to 13.94 mN/m, showing the significant improvement of hydrophobicity of all sample surfaces treated by 3:1 HMDSO/toluene plasma.     

One-step implementation of the Toffoli gate via quantum Zeno dynamics

Based on the quantum Zeno dynamics, we present a scheme for one-step implementation of a Toffoli gate via manipulating three rf superconducting quantum interference device (SQUID) qubits to resonantly interact with a superconducting cavity. The effects of decoherence such as spontaneous emission and the loss of cavity are also considered.     

Syntheses of biodegradable polymer networks based on polycaprolactone and glutamic acid

Biodegradable trifunctional oligomer was synthesized from polycaprolactone and glutamic acid and characterized by Fourier‐transform infrared (FTIR) and proton nuclear magnetic resonance (¹H NMR) spectroscopies. Injectable and in situ crosslinkable polymer networks were fabricated by the copolymerization of oligomer with triethylene glycol dimethacrylate (TEGDMA) and used to evaluate the initial compressive strengths, viscosities, shrinkages, thermal stabilities, and biodegradabilities in the forms of polymer network neat resin and their composites with β‐tricalcium phosphate. The initial compressive strengths (CS) values of neat resins ranged from 9.54 to 187.6 MPa. Both neat resins and composites had polymerization shrinkage ranging from 0% to 11.7%, which increased with increasing of TEGDMA contents in resin. Moreover, in polymer composite resins, shrinkage values decreased with increasing filler level from 0% to 4.6%, and exothermic evolution values decreased from 33.5°C to 29.7°C as increasing filler level. The composite with the formulation of (polycaprolactone)‐glutamate triacrylate (PCLGTA)/TEGDMA (25/75) and powder/liquid (P/L) ratio of 1.0 exhibited the highest exothermal and lowest shrinkage values. The increase of oligomer in the formulation led to an increase in viscosity.     

Lewis acid-mediated cross-coupling reaction of 7-azaindoles and aldehydes: Cytotoxic evaluation of C3-linked bis-7-azaindoles

The synthesis of 3,3′-bis-7-indolylmethane derivatives is important for their further development as pharmaceutical compounds and other synthetic purposes. Herein, we describe the zinc- or acid-mediated cross-coupling reaction of 7-azaindoles with aldehydes, such as paraformaldehyde, alkyl aldehydes, aryl aldehydes, enal, and α-ketoaldehyde, providing the corresponding C3-linked bis-7-azaindole derivatives, which are a crucial class towards the development of novel bioactive compounds. High levels of site selectivity and functional group tolerance were observed. Synthesized 3,3′-bis-7-azaindole derivatives were evaluated against human breast adenocarcinoma cells (MCF-7) and human ovarian carcinoma cells (SKOV-3), respectively. Notably, compounds 3s and 4e displayed promising anticancer properties competitive with anticancer doxorubicin as a positive control.     

Synthesis of high-quality monolayer graphene by low-power plasma

The growth of high-quality graphene on copper substrates has been intensively investigated using chemical vapor deposition (CVD). It, however, has been considered that the growth mechanism is different when graphene is synthesized using a plasma CVD. In this study, we demonstrate a dual role of hydrogen for the graphene growth on copper using an inductively coupled plasma (ICP) CVD. Hydrogen activates surface-bound carbon for the growth of high-quality monolayer graphene. In contrast, the role of an etchant is to manipulate the distribution of the graphene grains, which significantly depends on the plasma power. Atomic-resolution transmission electron microscopy study enables the mapping of graphene grains, which uncovers the distribution of grains and the number of graphene layers depending on the plasma power. In addition, the variation of electronic properties of the synthesized graphene relies on the plasma power.     

Enhanced betatron radiation by a modulating laser pulse in laser wakefield acceleration

We propose a new idea to enhance and control the betatron radiation by using a modulating laser pulse in laser wakefield acceleration. In this scheme, a high-power laser pulse is used for self-trapping and acceleration of the plasma electrons and the accelerated electron beam is modulated by a separately-propagating laser pulse for large amplitude betatron oscillations and microbunching. In this way, the relatively low power modulating laser pulse can enhance the X-ray photon flux and energy significantly. We performed two-dimensional particle-in-cell simulations to demonstrate the idea and the results show that a sub-TW laser pulse is enough for electron beam modulation and it can generate easily-controllable fs X-ray pulses with a wide range of photon energies from soft X-rays to hard X-rays.     

Quantum logic operations on two distant atoms trapped in two optical-fibre-connected cavities

Based on the coupling of two distant three-level atoms in two separate optical cavities connected with two optical fibres, schemes on the generation of several two-qubit logic gates are discussed under the conditions of Δ = δ - 2ν cos πk/2 >> g/2 and ν ~ g. Discussion and analysis of the fidelity, gate time and experimental setups show that our schemes are feasible with current optical cavity, atomic trap and optical fibre techniques. Moreover, the atom-cavity- fibre coupling can be used to generate an N-qubit nonlocal entanglement and transfer quantum information among N distant atoms by arranging N atom-cavity assemblages in a line and connecting each two adjacent cavities with two optical fibres.     

Experimental study of pitching and plunging airfoils at low Reynolds numbers

Measurements of the unsteady flow structure and force time history of pitching and plunging SD7003 and flat plate airfoils at low Reynolds numbers are presented. The airfoils were pitched and plunged in the effective angle of attack range of 2.4°–13.6° (shallow-stall kinematics) and ?6° to 22° (deep-stall kinematics). The shallow-stall kinematics results for the SD7003 airfoil show attached flow and laminar-to-turbulent transition at low effective angle of attack during the down stroke motion, while the flat plate model exhibits leading edge separation. Strong Re-number effects were found for the SD7003 airfoil which produced approximately 25 % increase in the peak lift coefficient at Re = 10,000 compared to higher Re flows. The flat plate airfoil showed reduced Re effects due to leading edge separation at the sharper leading edge, and the measured peak lift coefficient was higher than that predicted by unsteady potential flow theory. The deep-stall kinematics resulted in leading edge separation that led to formation of a large leading edge vortex (LEV) and a small trailing edge vortex (TEV) for both airfoils. The measured peak lift coefficient was significantly higher (~50 %) than that for the shallow-stall kinematics. The effect of airfoil shape on lift force was greater than the Re effect. Turbulence statistics were measured as a function of phase using ensemble averages. The results show anisotropic turbulence for the LEV and isotropic turbulence for the TEV. Comparison of unsteady potential flow theory with the experimental data showed better agreement by using the quasi-steady approximation, or setting C(k) = 1 in Theodorsen theory, for leading edge–separated flows.