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851.
Simple and compact 1-Hz laser system via an improved mounting configuration of a reference cavity 总被引:1,自引:0,他引:1
We report an improved mounting configuration for a passive optical cavity used for laser frequency stabilization. The associated reduction of the vibration sensitivity of the effective cavity length has led to a simple and compact reference cavity system for laser stabilization at the level of 1 Hz linewidth. 相似文献
852.
We theoretically and experimentally demonstrate coherence phenomena in optical parametric amplification inside a cavity. The mode splitting in the transmission spectra of a phase-sensitive optical parametric amplifier is observed. Especially, we show that a very narrow dip and peak, which are the shape of a delta function, appear in the transmission profile. The origin of the coherence phenomenon in this system is the interference between the harmonic pump field and the subharmonic seed field in cooperation with dissipation of the cavity. 相似文献
853.
854.
A family of halogenated liquids with densities ranging from 1.95 to 2.80 g cm(-3) was readily synthesized by a one-pot procedure. These liquids exhibit characteristics of ionic liquids with melting/transition points lower than room temperature, long liquid ranges, and marked hydrolytic and thermal stabilities. 相似文献
855.
McArthur EA Ye T Cross JP Petoud S Borguet E 《Journal of the American Chemical Society》2004,126(8):2260-2261
Detection and quantification of submonolayer coverage surface species is not trivial. We have developed a novel method sensitive to surface-bound chemical functional groups as low as 10(11) molecules/cm(2) by specific covalent attachment of fluorescent chromophores. This enables the intermediates of the UV photochemistry of alkylsiloxane self-assembled monolayers to be identified. 相似文献
856.
Eric?R.?HudsonEmail author J.?R.?Bochinski H.?J.?Lewandowski Brian?C.?Sawyer Jun?Ye 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2004,31(2):351-358
Stark deceleration has been utilized for slowing and trapping several species of neutral, ground-state polar molecules generated in a supersonic beam expansion. Due to the finite physical dimension of the electrode array and practical limitations of the applicable electric fields, only molecules within a specific range of velocities and positions can be efficiently slowed and trapped. These constraints result in a restricted phase space acceptance of the decelerator in directions both transverse and parallel to the molecular beam axis; hence, careful modeling is required for understanding and achieving efficient Stark decelerator operation. We present work on slowing of the hydroxyl radical (OH) elucidating the physics controlling the evolution of the molecular phase space packets both with experimental results and model calculations. From these results we deduce experimental conditions necessary for efficient operation of a Stark decelerator. 相似文献
857.
A new 1,4-phenanthraquinone was isolated from the roots of Menispermum dauricum. The structure was elucidated as 7-hydroxy-3,6-dimethoxy-1,4-phenanthraquinone on the basis of spectral evidence. 相似文献
858.
An improved first Rayleigh-Sommerfeld method (IRSM1) is proposed and applied to the analysis of cylindrical microlenses with small f-numbers. Numerical results obtained by both the IRSM1 and the original Rayleigh-Sommerfeld method (ORSM1) are compared with those obtained by the rigorous boundary element method (BEM). For both refractive and diffractive lenses, the results obtained by the IRSM1 are close to those obtained by the BEM even for small f-numbers; by contrast, the results by the ORSM1 differ significantly from those obtained by the BEM. Moreover, the IRSM1 uses much less time and computer memory in the computations than the BEM. 相似文献
859.
Gordon PM Fong R Deb SK Li NS Schwans JP Ye JD Piccirilli JA 《Chemistry & biology》2004,11(2):237-246
The 2'-hydroxyl group contributes inextricably to the functional behavior of many RNA molecules, fulfilling numerous essential chemical roles. To assess how hydroxyl groups impart functional behavior to RNA, we developed a series of experimental strategies using an array of nucleoside analogs. These strategies provide the means to investigate whether a hydroxyl group influences function directly (via hydrogen bonding or metal ion coordination), indirectly (via space-filling capacity, inductive effects, and sugar conformation), or through interactions with solvent. The nucleoside analogs span a broad range of chemical diversity, such that quantitative structure activity relationships (QSAR) now become possible in the exploration of RNA biology. We employed these strategies to investigate the spliced exons reopening (SER) reaction of the group II intron. Our results suggest that the cleavage site 2'-hydroxyl may mediate an interaction with a water molecule. 相似文献
860.
We have implemented a coupled-cluster equation of motion approach combined with the intermediate neglect of differential overlap parametrization and applied it to study the excited states and optical absorptions in positively and negatively charged conjugated oligomers. The method is found to be both reliable and efficient. The theoretical results are in very good agreement with experiments and confirm that there appear two subgap absorption peaks upon polaron formation. Interestingly, the relative intensities of the polaron-induced subgap absorptions can be related to the extent of the lattice geometry relaxations. 相似文献