Nano-Co3O4-catalyzed microwave-assisted one-pot synthesis of some seleno [2 , 3-b ] pyridine/quinoline derivatives

For the efficient synthesis of transition-metal cobalt oxide nanoparticles (Co₃O₄ NPs) without using any costly and toxic solvent or complicated equipment, the co-precipitation method was used in this work. Using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), UV–Vis spectrophotometry, Fourier-transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD), the prepared Co₃O₄ NPs were characterized and identified. The influence of prepared Co₃O₄ NPs on the developmental synthesis of some selenopyridine/quinoline derivatives under different microwave irradiation powers and irradiation times was investigated via click (reaction) chemistry. The reusable Co₃O₄ nanoparticles have high catalytic activity under microwave irradiation for the synthesis of organoselenium compounds with higher yields (>?90%), milder reaction conditions and shorter time without significantly decreasing the reaction rates and yields.

     

Antimicrobial properties of modified and electrospun poly(vinyl phenol)

Antimicrobial polymeric systems were prepared from poly(vinyl phenol) (PVP). Four systems were prepared, two of these based on the modification of the poly(vinyl phenol) by sulfonation with fuming sulfuric acid (SPVP 100k) or by formation of lithium salt of the sulfonated poly(vinyl phenol) brought about by its reaction with lithium hydroxide (LiSPVP 100k). The other two systems were prepared by the electrospinning of poly(vinyl phenol) with molecular weight 20 × 10³ (PVP 20k spun) and 100 × 10³ (PVP 100k spun). The antimicrobial activity of the polymers was examined against different test microorganisms. The plug-cutting technique revealed the potency of SPVP 100k and LiSPVP 100k as antimicrobial agents. SPVP 100k was inhibitory to the growth of gram-negative bacteria (E. coli and Salmonella choleraesius) and gram-positive bacteria (B. subtilis and S. aureus). On the other hand, LiSPVP 100k had antifungal activity against A. niger, T. rubrum and C. albicans. Generally, it was found that polymer morphology and molecular weight affect the activities against test microorganisms. For example, PVP 20k and PVP 100k in their powder form showed no antimicrobial activity. However the results showed that PVP 20k spun has antibacterial activity against B. subtilis, and there is no growth of the tested microorganisms on the electrospun fibers of PVP 100k spun, revealing its property of being a self-sterilizing material (SSM).

Growth inhibition of different concentrations of polymer SPVP. Inoculation: 6 × 10⁴ cells · ml⁻¹, B. subtilis, S. choleraesius, S. aureus and E. coli.     

On the refracted patterns produced by liquid vortices

A theoretical analysis of the refracted shadows produced by steady and time-decaying liquid vortices under uniform illumination from above is given in this article. An expression for the induced shadow intensity is derived and found to be a function of the vortex’s free surface profile, i.e., function of the static pressure distribution. The patterns for different focusing depth are given and compared with previous visualization results from the literature. The phenomenon is examined and illustrated as a bench mark case by using both steady and time-decaying algebraic vortex models. However, this study can be extended to check the feasibility of recovering the main flow properties by analyzing the luminous image intensity of the refracted patterns. The present analysis is valid only when the swirl velocity is order of magnitude higher than the meridional flow components and the vorticity is concentrated within the core region and of intense conditions.     

Conformational Stability, Raman and Infrared Spectra, Vibrational Assignment, and Ab Initio Calculations of Allyltrifluorosilane

The Raman spectra (3500 to 30 cm^–1) of allyltrifluorosilane, CH₂CHCH₂SiF₃, in the liquid with quantitative depolarization ratios and solid states, and the infrared spectra (3500 to 30 cm^–1) of the gas and solid have been recorded. Additionally, the mid-infrared spectra of the sample dissolved in liquified xenon as a function of temperature (–100° to –55°C) have been recorded. All of these data indicate there are two conformers, the more stable gauche rotamer and a very small amount of the cis conformer in the fluid states, but only the gauche form remains in the polycrystalline solid. The variable temperature studies of the infrared spectrum of the xenon solution indicate a relatively large enthalpy difference of 354±30 cm^–1 (4.23±0.36 kJ/mol) between the conformers. The fundamental frequencies for the asymmetric (54 cm^–1) and SiF₃ (48 cm^–1) torsions for the gauche conformer were observed in the far infrared spectrum, and from the SiF₃ torsional frequency the barrier to internal rotation is calculated to have a value of 525 cm^–1 (6.28 kJ/mol). A complete vibrational assignment is presented for the gauche conformer that is consistent with the predicted wavenumbers utilizing the force constants from ab initio MP2/6-31G* calculations. The optimized geometries, conformational stabilities, harmonic force fields, infrared intensities, Raman activities, depolarization ratios, and vibrational wavenumbers have been obtained from RHF/6-31G* and/or MP2/6-31G* ab initio calculations. These quantities are compared to the corresponding experimental quantities when appropriate as well as with corresponding results for some similar molecules.Taken in part from the dissertation of Y. E. Nashed, which will be submitted to the Department of Chemistry in partial fulfillment of the Ph.D. degree     

Pulsating flow in a channel filled with a porous medium under local thermal non-equilibrium condition: an exact solution

Journal of Thermal Analysis and Calorimetry - The present work investigates analytically the problem of forced convection heat transfer of a pulsating flow, in a channel filled with a porous medium...     

L-Glutaminase Synthesis by Marine Halomonas meridiana Isolated from the Red Sea and Its Efficiency against Colorectal Cancer Cell Lines

L-glutaminase is an important anticancer agent that is used extensively worldwide by depriving cancer cells of L-glutamine. The marine bacterium, Halomonas meridian was isolated from the Red Sea and selected as the more active L-glutaminase-producing bacteria. L-glutaminase fermentation was optimized at 36 h, pH 8.0, 37 °C, and 3.0% NaCl, using glucose at 1.5% and soybean meal at 2%. The purified enzyme showed a specific activity of 36.08 U/mg, and the molecular weight was found to be 57 kDa by the SDS-PAGE analysis. The enzyme was highly active at pH 8.0 and 37 °C. The kinetics’ parameters of Km and Vmax were 12.2 × 10⁻⁶ M and 121.95 μmol/mL/min, respectively, which reflects a higher affinity for its substrate. The anticancer efficiency of the enzyme showed significant toxic activity toward colorectal adenocarcinoma cells; LS 174 T (IC50 7.0 μg/mL) and HCT 116 (IC50 13.2 μg/mL). A higher incidence of cell death was observed with early apoptosis in HCT 116 than in LS 174 T, whereas late apoptosis was observed in LS 174 T more than in HCT 116. Also, the L-glutaminase induction nuclear fragmentation in HCT 116 was more than that in the LS 174T cells. This is the first report on Halomonas meridiana as an L-glutaminase producer that is used as an anti-colorectal cancer agent.     

Preparation of produced water reference material for analyzing 226Ra by gamma spectrometry

Journal of Radioanalytical and Nuclear Chemistry - Produced water reference material containing high concentration of 226Ra activity was prepared in 2009 and used for ALMERA worldwide proficiency...     

The removal of methylene blue as a remedy of dye-based marine pollution: a photocatalytic perspective

Research on Chemical Intermediates - The effluents containing the discarded water from the textile industry are graded as one of the foremost pollutants in all industrial sectors. The wide...     

Aluminum(III)-Selective Screen Printed Sensor Based on Methyl Red

Russian Journal of Electrochemistry - Modified screen printed electrode (MSPE) with 2-[[4-(dimethyl amino) phenyl] diazenyl] benzoic acid (Methyl Red) was prepared for determination of aluminum...     

Silicon‐grafted Ag/AgX/rGO nanomaterials (X = Cl or Br) as dip‐photocatalysts for highly efficient p‐nitrophenol reduction and paracetamol production

In this work, plasmonic Ag/AgX/rGO (X = Cl or Br) nano‐photocatalysts were grafted with silicon by adding trimethylsilyl chloride as silicon precursor. The synthesized Ag/AgX/rGO‐Si hybrids showed a large improvement of photocatalytic activity towards the synthesis of p‐aminophenol (PAP) as well as paracetamol (acetaminophen; APAP) through the photoreduction of p‐nitrophenol (PNP). The prepared catalysts Ag/AgX/rGO were characterized using SEM, XRD, FTIR and the reduction reaction of p‐nitrophenol was monitored by UV–Vis measurements, GC/MS and ¹HNMR data. From the results, it was demonstrated that the rate order of reduction process of the PNP to PAP and to APAP under visible light irradiation of the samples was as follows; Ag/AgBr/rGO‐Si > Ag/AgCl/rGO‐Si > Ag/AgBr/rGO > Ag/AgCl/rGO. The reaction mechanism had been postulated that was supported with the spectroscopic data. In addition, the catalysts were recovered from the reaction medium and re‐used in three cycles that indicated the reusability and stability of the catalysts. This study was featured by the following; i) fast reaction, ii) the reduction of p‐nitrophenol to paracetamol was performed in a facile one‐pot reaction compared to previous approaches that tends to reduce the production cost, and iii) investigations on the catalytic properties of Ag/AgX/rGO in organic transformations open the door to find a benefice of these catalysts in other organic reactions and in the development in the synthesis of pharmaceutical products.