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51.
Shmuel Yariv Isaak Lapides Mikhail Borisover 《Journal of Thermal Analysis and Calorimetry》2012,110(1):385-394
Na-montmorillonite was loaded with tetraethylammonium cations (TEA) or with benzyltrimethylammonium cations (BTMA) by replacing 77 and 81% of the exchangeable Na with TEA or BTMA, labeled TEA-MONT and BTMA-MONT, respectively. TEA- and BTMA-MONT were heated in air up to 900?°C. Thermally treated organoclays are used in our laboratory as sorbents of organic compounds from water. The two organoclays were studied by TG and DTG in air and under nitrogen. Carbon content in each of the heated sample was determined. They were diffracted by X-ray, and fitting calculations of d(001) peaks were performed on each diffractogram. TG and thermo-C analysis showed that at 150 and 250?°C both organoclays lost water but not intercalated ammonium cations. DTG peak of the first oxidation step of the organic cation with the formation of low-temperature stable charcoal (LTSC) appeared at 364 and 313?°C for TEA- and BTMA-MONT, respectively. The charcoal was gradually oxidized by air with further rise in temperature. DTG peak of the second oxidation step with the formation of high-temperature stable charcoal (HTSC) appeared at 397 and 380?°C for TEA- and BTMA-MONT, respectively. DTG peak of the final oxidation step of the organic matter appeared at 694 and 705?°C for TEA- and BTMA-MONT, respectively, after the dehydroxylation of the clay. Thermo-XRD analysis detected TEA-MONT tactoids with spacing 1.40 and 1.46?nm up to 300?°C. At 300 and 360?°C, LTSC-MONT tactoids were detected with spacing of 1.29?nm. At higher temperatures, HTSC-MONT-?? and -?? tactoids were detected with spacings of 1.28 and 1.13?nm, respectively. BTMA-MONT tactoids with spacings 1.46 and 1.53?nm were detected up to 250?°C. At 300 and 360?°C, LTSC-MONT tactoids were detected with a spacing of 1.38?nm. At higher temperatures, HTSC-MONT-?? and -?? tactoids were detected with spacings of 1.28 and 1.17?nm, respectively. At 650?°C, both clays were collapsed. HTSC-??-MONT differs from HTSC-??-MONT by having carbon atoms keying into the ditrigonal holes of the clay-O-planes. At 900?°C, the clay fraction is amorphous. Trace amounts of spinel and cristobalite are obtained from thermal recrystallization of amorphous meta-MONT. 相似文献
52.
Rapid colorimetric detection of antibody-epitope recognition at a biomimetic membrane interface. 总被引:2,自引:0,他引:2
Biomolecular recognition of antigens and epitopes by antibodies is a fundamental event in the initiation of immune response and plays a central role in a variety of biochemical processes. Peptide binding requires, in many cases, presentation of the peptides at interfaces, such as protein surfaces, cellular membranes, and synthetic polymer surfaces. We describe a novel molecular system in which interactions between antibodies and peptide epitopes displayed at a biomimetic membrane interface can be detected through induction of visible, rapid color transitions. The colorimetric assembly consists of a phospholipid/polydiacetylene matrix anchoring a hydrophobic peptide displaying the epitope at its N-terminus. The colorimetric transitions observed in the assembly, corresponding to perturbation of the polydiacetylene framework, are induced only upon recognition of the displayed epitope by its specific antibody present in the aqueous solution. Significantly, the color changes occur after a single mixing step, without further chemical reactions or enzymatic processing. The new molecular system could be utilized for studying antigen-antibody interactions and peptide-protein recognition, epitope mapping, and rapid screening of biological and chemical libraries. 相似文献
53.
S. Yariv A. Nasser Y. Deutsch K. H. Michaelian 《Journal of Thermal Analysis and Calorimetry》1991,37(7):1373-1388
The reaction occurring during the wet grinding of kaolinite with CsBr was studied by simultaneous Differential Thermal Analysis -Thermogravimetry (DTA-TG), supplemented by infrared spectroscopy of isothermally treated CsBr disks. The DTA and TG curves were compared with those of untreated kaolinite and of kaolinite mixed or air ground with different alkali halides. A new endothermic DTA peak at 75–115°, accompanied by weight loss, is due to the desorption of surface and interparticle water located mainly at the interface between the mineral and the salt. A second endothermic peak at about 500° represents the simultaneous dehydroxylation of the clay and thermal hydrolysis of CsBr. The presence of a separate CsBr phase was identified from two endothermic peaks which characterize melting and boiling of the salt; only mixtures with more than 140 mmol CsBr per 100 g kaolinite show the presence of this phase. All of the CsBr below this concentration occurs in the CsBrHOH-kaolinite intercalation complex. This degree of saturation is smaller than that obtained previously for CsCl.
Dedicated to Professor Dr. H. J. Seifert on the occasion of his 60th birthday
S. Y. and A. N. are grateful to the Internal Fund of the Hebrew University of Jerusalem for financial support. 相似文献
Zusammenfassung Mittels simultaner DTA-TG wurde die sich während des Naßmahlens von Kaolinit mit CsBr stattfindende Reaktion untersucht, ergänzt durch IR-spektroskopische Untersuchungen von isotherm wärmebehandelten CsBr-Plättchen. Die DTA und TG Kurven wurden mit denen von unbehandeltem Kaolinit und von Kaolinit, vermischt oder an Luft gemahlen mit verschiedenen Alkalihalogeniden. Ein neuer endothermer DTA-Peak bei 75–115°C., begleitet von einem Gewichtsverlust, wird der Desorption von Oberflächen- oder interpartikelgebundenem Wasser zugeschrieben, das hauptsächlich an den Übergangsflächen Mineral/Salz lokalisiert ist. Ein zweiter endothermer Peak bei 500°C steht für die gleichzeitige Dehydroxylierung der Tonerde und die thermische Hydrolyse von CsBr. Aus zwei für Schmelzen und Sieden des Salzes charakteristischen endothermen Peaks konnte auf eine separate CsBr-Phase geschlossen werden; nur Gemische mit mehr als 141 mmol CsBr pro 100 g Kaolinit zeigen die Gegenwart einer solchen Phase. Unterhalb dieser Konzentrationsgrenze ist alles CsBr in CsBr-HOH-Kaolinit Durchdringungskomplexen vorhanden. Dieser Sättigungsgrad ist niedriger als der für CsCl.
Dedicated to Professor Dr. H. J. Seifert on the occasion of his 60th birthday
S. Y. and A. N. are grateful to the Internal Fund of the Hebrew University of Jerusalem for financial support. 相似文献
54.
We present a coupled-mode theory of fiber-optic add-drop filters, which involve directional coupling between two fibers combined with fiber Bragg gratings defined inside the coupling region. The analysis self-consistently accounts for both the directional and the reflection coupling, and the propagation constants and structure of the supermodes of the combined structure are derived. We present a detailed analysis of a filter design based on identical fibers. The calculated device parameters satisfy the requirements for dense wavelength-division multiplexing applications. 相似文献
55.
Palladium(II) catalysts based on a ferrocenyloxazoline palladacyclic (FOP) scaffold were synthesized and evaluated for the rearrangement of prochiral allylic N-(4-methoxyphenyl)benzimidates. When iodide-bridged dimer FOP precatalysts are activated by reaction with excess silver trifluoroacetate, the allylic rearrangement of both E and Z prochiral primary allylic N-(4-methoxyphenyl)benzimidates takes place at room temperature to give the corresponding chiral allylic N-(4-methoxyphenyl)benzamides in high yield and good ee (typically 81-95%). Several allylic imidate motifs were evaluated also. Because the corresponding enantioenriched allylic amide products can be deprotected in good yield to give enantioenriched allylic amines, allylic N-aryltrifluoroacetimidates were identified as promising substrates. 相似文献
56.
An intense blue organo-clay color pigment was obtained by adding naphthyl-1-ammonium chloride to a Na-montmorillonite aqueous
suspension followed by treatment with sodium nitrite. This treatment resulted in the synthesis of the azo dye 4-(1-naphthylazo)-1-naphthylamine
adsorbed onto the clay. The pigment was subjected to thermo-XRD-analysis and the diffractograms were curve-fitted. Heating
naphthylammonium-montmorillonite at 360°C resulted in the evolution of the amine at temperatures lower than those required
for the formation of charcoal and consequently the clay collapsed. On the other hand, heating the pigment at 360°C resulted
in the conversion of the adsorbed azo dye into charcoal. The clay did not collapse, thus proving that the azo dye was located
inside the interlayer space. Before the thermal treatment a short basal spacing in the pigment compared with that in the ammonium
clay (1.28 and 1.35 nm, respectively) indicated stronger surface π interactions between the clayey O-plane and the azo dye
than between this plane and naphthylammonium cation. The amount of dye after one aging-day of the synthesis-suspension increased
with [NaNO2]/[C10H7NH3] ratio but did not increase with naphthylammonium when the [NaNO2]/[C10H7NH3] ratio remained 1. After 7 and 56 aging days it decreased, indicating that some of the dye decomposed during aging. 相似文献
57.
E. T. Stepkowska S. Yariv J. L. Pérez-Rodríguez A. Justo A. Ruiz-Conde P. Sánchez-Soto 《Journal of Thermal Analysis and Calorimetry》1997,49(3):1449-1466
A dredged sludge was studied to investigate the influence of ageing and of pretreatment on its drying rate, water sorption/retention, thermal mass loss, XRD and microstructure (SEM).Ageing caused change in particle thickness and specific surface, a gradual aggregation to form units of the size 10–50 m, formation of macropores of similar size, unhomogeneity and fissures between aggregates and super-aggregates. Macropores were detectable by the initial drying rate especially at 45°C. They indicated a tendency of collapsing at a lower drying rate at 30°C. This is consistent with SEM observations. With ageing the aggregates were more compact and less sensitive to drying.The aggregated system indicated a higher initial drying rate (higher permeability), whereas stirring induced a lower drying rate, favouring the formation of compact laminar structure.XRD peak intensity was lowered with ageing due to decrease in crystallinity (stacking faults and/or decrease in crystallite size). The content of amorphous material was lowered as well, reducing water sorption/desorption, which indicated that the specific surface is lower.From the suitable microstructure induced by ageing some new phases may form (feldspar, zeolites), preferably in the coarser fraction of the sludge. This is disturbed by stirring which operation expels also carbonates from the particle edges and this may reduce the structural strength of the sludge. In aged bentonite suspension a similar tendency was observed of formation of specific microstructures capable of phase transformation, e.g. to feldspar. 相似文献
58.
U. Shuali L. Bram M. Steinberg S. Yariv 《Journal of Thermal Analysis and Calorimetry》1991,37(7):1569-1578
The catalytic activity of sepiolite and palygorskite in cracking and disproportionation reactions of cumene was studied. The formation of benzene, diisopropylbenzene and propylene characterizes Brönsted acid sites whereas that of ethylbenzene characterizes Lewis acid sites. At 150 and 250°C the reactions are determined mainly by the presence of acid sites in the channels of these clays. The yields are significantly higher in sepiolite as compared to palygorskite. The concentration of acid sites and their strength increase with the thermal loss of zeolitic and part of the bound water. At 350°C the reactions are determined by the acidity of the external surface of both minerals and yields are only slightly higher in sepiolite. At 150°C most acid sites are of the Brönsted type. With the rise in temperature the relative concentration of Lewis acid sites increases.
Dedicated to Prof. Dr. H. J. Seifert on the occasion of his 60th birthday 相似文献
Zusammenfassung Es wurde die katalytische Aktivität von Sepiolith und Palygorskit in Krack- und Disproportionierungsreaktionen von Kumol untersucht. Die Bildung von Benzol, Diisopropyl-benzol und Propylen charakterisieren Aziditätsstellen nach Bronsted, während die Bildung von Ethylbenzol Aziditätsstellen nach Lewis charakterisiert. Bei 150°C und 250°C werden die Reaktionen hauptsächlich durch die Gegenwart von Aziditätsstellen in den Tunnelgebilden dieser Tonerden bestimmt. Bezogen auf Palygorskit sind die Ausbeuten bei Sepiolith eindeutig höher. Die Konzentration der Aziditätsstellen und ihre Stärke nehmen mit der thermischen Abgabe von zeolithischem und eines Teiles des gebundenen Wassers zu. Bei 350°C werden die Reaktionen durch die Azidität der externen Oberfläche beider Mineralien bestimmt und die Ausbeuten sind in Sepiolith kaum höher. Bei 150°C sind die meisten Aziditätsstellen vom Brönsted-Typ. Mit ansteigender Temperatur nimmt auch die relative Anzahl von Lewis-Aziditätsstellen zu.
Dedicated to Prof. Dr. H. J. Seifert on the occasion of his 60th birthday 相似文献
59.
Transition metal montmorillonites were saturated with benzidine (BEN) and heated gradually to 200°C, in a vacuum cell supported by KBr windows. IR spectra were recorded before and after the thermal treatment and at various temperatures during this treatment. X-ray diffractions were recorded before and after the thermal treatment. Hg clay shows properties similar to those of Mg and Ca clays. In the interlayer BEN is bound to Hg through a water molecule bridge, either by proton accepting (typeA) or by proton donation (typeB). Some BEN is also protonated (typeD). Initially typeA predominates, but after the thermal treatment, when the film is rehydrated, the amounts of typesB andD increase. With Mn-, Co-, Ni-, Zn- and Cd-montmorillonite a direct coordination of the benzidine by the dehydrated metallic cation is obtained (typeC), in addition to small amounts of typesA,B andD. During the thermal treatment water is evolved and associationsA andB are completely transformed toC. At elevated temperatures the following associations were identified in trace amounts, ammonium-amine, BEN bound to non-structured water, hydrophobic adsorbed BEN and BEN bound to the oxygen plane (typesE, F, H andJ, respectively). During the thermal treatment of Co and Cd clays some of the benzidine was oxidized, probably to semiquinone and quinoidal cation. 相似文献
60.
Landau A. Zaban A. Lapides I. Yariv S. 《Journal of Thermal Analysis and Calorimetry》2002,70(1):103-113
The mechanochemical solid-state adsorption of the cationic dye rhodamine-6G (R6G) by montmorillonite was investigated by XRD
and simultaneous DTA-TG. Five different mixtures of R6G and montmorillonite were investigated. They contained 10, 20, 35,
50 and 100 mmol R6G per 100 g clay. The solid R6G was ground with the clay for five minutes. Mixtures were ground both in
the absence of water (dry grinding) and with the adding of drops of water periodically, (wet grinding). There were no differences
between samples obtained by wet or dry grinding. X-ray and DTA data were compared with those of R6G-montmorillonite obtained
from aqueous suspensions. The mechanochemical products were different from those obtained from aqueous suspensions. The X-ray
and DTA studies suggest that the mechanochemical adsorption of organic cations takes place on the external surfaces of the
clay whereas in suspensions the adsorption takes place into the interlayer space. In the latter case the final stages of oxidation
occur in temperatures higher than those of the neat dye whereas in the former they occur at lower temperatures.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献