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941.
942.
943.
The construction and performance characteristics of an ion-selective electrode for fentanyl-drug cation, based on an ion-pair complex with tetrakis[3,5-bis-(trifluoromethyl)phenyl]borate anion in a PVC matrix were studied. A linear response for 1 x 10(-5) mol dm-3 to 1 x 10(-2) mol dm-3 drug with a slope of 57.9 +/- 0.5 mV/decade was established. The optimum pH range was 2 to 6. The lower detection limit was 6.29 x 10(-6) mol dm-3 fentanyl citrate (2.1165 micrograms cm-3 fentanyl). There were negligible interferences from a number of inorganic cations, structural analogues, and some common drug additives in injections. The electrode proposed has been successfully applied to determine fentanyl citrate in injections. The results correlated well with those obtained by the United States Pharmacopoeia standard procedure. 相似文献
944.
945.
A mathematical model is developed to study periodic-impact motions and bifurcations in dynamics of a small vibro-impact pile driver. Dynamics of the small vibro-impact pile driver can be analyzed by means of a three-dimensional map, which describes free flight and sticking solutions of the vibro-impact system, between impacts, supplemented by transition conditions at the instants of impacts. Piecewise property and singularity are found to exist in the Poincaré map. The piecewise property is caused by the transitions of free flight and sticking motions of the driver and the pile immediately after the impact, and the singularity of map is generated via the grazing contact of the driver and the pile immediately before the impact. These properties of the map have been shown to exhibit particular types of sliding and grazing bifurcations of periodic-impact motions under parameter variation. The influence of piecewise property, grazing singularities and parameter variation on the performance of the vibro-impact pile driver is analyzed. The global bifurcation diagrams for the impact velocity of the driver versus the forcing frequency are plotted to predict much of the qualitative behavior of the actual physical system, which enable the practicing engineer to select excitation frequency ranges in which stable period one single-impact response can be expected to occur, and to predict the larger impact velocity and shorter impact period of such response. 相似文献
946.
Various structures of CrAPO‐5 clusters are studied via density functional B3LYP exchange‐correlation method. The optimized structures are compared with data from X‐ray absorption. Their total energies and atomic net charges are also analyzed. Results indicate that the substitution of the aluminum site of an AFI framework by chromium is in general not feasible. The chromium ion is more likely docked in between two neighboring 12‐membered rings of the framework of AFI. To further verify our claim, the excitation energies of the representative chromium structures of CrAPO‐5 clusters are calculated via the TDDFT method. The results for excitation energies further support that Cr3+ is not incorporated into the framework. 相似文献
947.
Jennifer A. Aitken Jonathan W. Lekse Jin-Lei Yao Rosalynn Quinones 《Journal of solid state chemistry》2009,182(1):141-8062
EuCu2SnS4 was prepared by a stoichiometric combination of the elements heated to 700 °C for 125 h. The structure was determined by single crystal X-ray diffraction methods. The compound crystallizes in the noncentrosymmetric, orthorhombic space group Ama2 with a=10.4793(1) Å, b=10.3610(2) Å, c=6.4015(1) Å, Z=4, R1=0.99% and wR2=2.37%. The structure type is that of SrCu2GeSe4. The structure can be described as a three-dimensional network built from near perfect SnS4 and distorted CuS4 tetrahedra together with EuS8 square antiprisms. The dark red compound is a semiconductor with an optical bandgap of 1.85 eV. 相似文献
948.
Yuhui Wei Junquan He Hongyan Qin Xin'an Wu Xiaojun Yao 《Biomedical chromatography : BMC》2009,23(10):1116-1120
Ferruginol, a diterpene phenol, has recently received attention for its extensive pharmacological properties, including anti‐tumor, antibacterial, cardio‐protective and gastroprotective effects. In the present study, a high‐performance liquid chromatographic (HPLC) method was developed for determination of ferruginol in rat plasma and applied for the pharmacokinetics study. The HPLC assay was performed with a VP ODS‐C18 column. The mobile phaseconsisted of methanol and 1% acetic acid solution (90:10, v/v). The flow rate was 1.0 mL/min, and the wavelength was set at 270 nm. This method was linear over the studied range of 0.1–10.0 µg/mL for ferruginol. The correlation coefficient was 0.9998. The intra‐day and inter‐day precisions were better than 4 and 5%, respectively. The extraction recovery and accuracy were greater than 97 and 96%, respectively. The detection limit was 30 ng/mL. The mean maximum concentration of ferruginol in rat plasma was 3.14 µg/mL at 40 min after oral administration at a dose of 20 mg/kg. Ferruginol was absorbed quickly p.o. with t1/2ka = 14.86 min and had a high rate of elimination with t1/2 = 41.73 min. The pharmacokinetic process of ferruginol in rat was well described with a one‐compartment model. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
949.
Xin Hou Dongge Huang Xiaomin Chen Zheguo Zhang Kangde Yao 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1674-1682
A novel route to synthesize crosslinked porous polyvinylamine (PVAm) microspheres from acrylonitrile (AN) was developed. In the first step, crosslinked porous polyacrylonitrile (PAN) spheres were prepared by copolymerization of AN and divinylbenzene (DVB). Then they were hydrolyzed to form polyacrylamide (PAM) spheres. And lastly, the porous PVAm spheres were successfully obtained via Hofmann degradation of PAM spheres. Scanning electron microscope (SEM) indicated that these PVAm microspheres have rough surfaces and porous interior structure. The pore size, the amino content, and the content of equilibrium water were also investigated. The pore size of these PVAm microspheres increased with the hydrolytic process. The contents of equilibrium water was changed from 49.6 to 96.5% depending on the different crosslinking degrees, and the amino contents were varied between 9.60 and 15.30 mmol/g depending on the different molar ratio of n(NaClO)/n(NaOH). © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1674–1682, 2008 相似文献
950.
纳米SiC蓝光发射的研究 总被引:4,自引:0,他引:4
在4.68eV的激光激发下,室温CVD合成的纳米SiC粉体,可发射475nm的蓝光,经600~1100℃在N2气氛下进行快速退火(RTA)处理,其荧光强度随退火温度升高而增强,当T≥900℃时,荧光强度下降,但发光峰位与退火温度无关.通过XRD、IR、TEM、XPS等研究,认为纳米SiC中与氧有关的缺陷可能是引起475nm蓝光发射的主要原因 相似文献