不同循环加载应力下花岗岩Kaiser效应特征的试验研究

为了更准确地获取花岗岩的Kaiser效应点对应的应力值σAE,利用RMT-100B岩石力学伺服试验机和Micro-Ⅱ Express型声发射监测系统,研究不同循环加载应力σci下岩石Kaiser效应特征.结果表明:相比单次加载,在循环加载作用下,试样的应力-应变曲线在加载初期下凸减弱,压密阶段变短;由于试样的加卸载曲线...     

Directional growth of Al−Mg<Subscript>2</Subscript>Si eutectic alloy in the SZ2 unmanned spaceship

This paper reports the investigation results on directional growth of Al−Mg₂Si eutectic alloy in the SZ2 unmanned spaceship. The analysis shows that microgravity has influence on the directional growth of Al−Mg₂Si eutectic alloy. The eutectic colony in space-grown sample is larger than that in ground-grown sample, and the directional effect is not so good as that of terrestrial sample. But there is no obvious difference in the lamellar thickness between these samples, and lamellar interspacing in space sample is smaller than that grown on the ground. A simple discussion is done on the gravity effect on the directional growth of Al−Mg₂Si eutectic alloy.     

Production of light alkenes with low CO2 emission from gas phase oxidative cracking (GOC) of hexane

Compared with non-oxidative pyrolysis of hexane, the rupture of C-C bonds of hexane in the GOC process becomes rather easy due to the change of thermodynamics and kinetics of the reaction with introduction of oxygen. CO predominates in the COx produced, and the ratio CO/CO₂ can be as high as 16. The GOC process could be operated in an autothermic way, which would minimize energy consumption of the whole process and greatly decrease the CO₂ emission. GOC seems to be an environmentally benign and promising alternative route for light alkenes production using heavy feedstock. This revised version was published online in August 2006 with corrections to the Cover Date.     

人工神经网络的光学实现

本文讨论了光学神经网络的优势及其所面临的主要问题,简述了它近十年来的发展．光互连是光学实现神经网络最具吸引力的技术,光电混合集成的灵巧象素器件又融合了电子器件灵活、可编程、易控制的特点．二者的结合是当前光学神经网络发展的主要趋势,它们为神经网络的进一步发展和应用,为超大规模神经网络的实现和应用提供了一种很有前途的方案．     

Kinetic and mechanistic studies of the photolysis of metronidazole in simulated aqueous environmental matrices using a mass spectrometric approach

Metronidazole is a nitroimidazole antibiotic derivative used in humans against anaerobic bacteria and protozoa. In light of the recent detection of metronidazole in hospital wastes, sewage treatment plants, and surface waters, along with its known sensitivity toward photolytical degradation, this study aimed to model the photolysis in environmental waters by sunlight as a natural attenuation process. To this end, the degradation of metronidazole in a photoreactor simulating solar radiation (Suntest CPS) was compared in five different aqueous matrices: deionized water, artificial freshwater (AFW), AFW supplemented with nitrate (5 mg/L), AFW containing humic acids, and AFW with both nitrate and humic acids. Irrespective of the test medium, the degradation of the metronidazole solutions (10 and 0.02 mg/L) was found to follow pseudo-first-order kinetics. Degradation rates were dependant on the matrix, with humic acids causing a two to threefold decrease in the rate constants while the presence of nitrate had no marked effect on the kinetics. Therefore, the direct photolysis of metronidazole was apparently attenuated through a filter effect of humic acids. Screening of the irradiated water samples by ultra performance liquid chromatography/quadrupole time-of-flight mass spectrometry allowed separation and characterisation of four principal phototransformation products of the antibiotic. The high-resolution MS data pointed to the formation of two rearrangement products (C₆H₁₀N₃O₃) isobaric with metronidazole, a third product deriving from the elimination of NO from the nitro group (C₆H₁₁N₂O₂), and a fourth unidentified degradate with a likely elemental composition of C₅H₁₀N₃O.     

丰中子锶同位素的投影壳模型研究

利用考虑跨壳激发的投影壳模型（PSM）方法,研究了质子数Z=38、中子数N=63和64大形变丰中子101,102Sr同位素的结构性质。主要计算了转动谱、转动惯量和电磁跃迁性质等（如B（E2）和g因子）,并与相应的实验数据进行系统比较和相关的理论预言。结果表明,PSM可以利用理论计算的能带图解释101,102Sr同位素的转动惯量、电磁跃迁随自旋的变化,分析晕带的结构。PSM理论可以很好地再现实验结果,说明PSM方法及其采用的有效相互作用可以外推研究丰中子核区101,102Sr同位素的原子核结构。对于101,102Sr同位素,核子开始填布质子g_9/2和中子h_11/2轨道,通过更为仔细地分析能带图中来自质子g_9/2和中子h_11/2轨道对各转动带的组态成分的贡献,清晰地表明丰中子核结构性质对不同核子填布的依赖。Recently, we have carried out systematically studies on the structural properties of proton number Z=38, neutron number N=63 and 64 neutron-rich isotopes 101,102Sr by using the projected shell model (PSM) with consideration of cross shell excitation. The rotation spectra, the moment of inertia and the electromagnetic transition properties (such as B(E2) and g-factor) are calculated and compared with the corresponding experimental data in this paper. Furthermore, more high spin states are predicted in the calculation and expected to be confirmed experimentally. The results show that the PSM can not only well analyze the structural properties of yrast bands in 101,102Sr but also interpret the variation of the moment of inertia, electromagnetic transition with spins in terms with the theoretical band diagram. The good agreement with the experimental data suggests that the PSM with the adopted effective interactions can be generalized to study the nuclear structure of 101,102Sr isotopes in neutron-rich mass region. For 101,102Sr isotopes, the nucleons begin to fill proton g_9/2 and neutron h_11/2 orbital, the dependence of nuclear structure and properties on the different orbital occupies is described by carefully analyzing the contribution from proton g_9/2 and neutron h_11/2 orbital to the configuration of rotational bands in band diagram.     

a系语气词特殊发音基频的情感表现*

语气词在日常对话中频繁使用,能表达特定的情感。a系语气词在生活广泛使用,口语中的某些语气词的特殊音调并不是普通话四个标准声调。该文从发音的基频角度出发,认为特殊音调能适用于一类情感的表达,提取特殊音调的基频数据,发现其在基频上的线性变化特征以及发音的规律。从基频上合成特殊音调语气词并应用到句子的语气词中,通过情感识别对比实验和情绪反馈对比实验表明,含有该种特殊音调语气词的情感语句使听音人产生较强烈的正向情绪,感到更加愉悦。     

怀孕期头发中一些元素含量的变化趋势

用同步辐射激发X射线荧光分析,对11个产妇怀孕期间头发内一些元素含量的变化趋势进行了测量,在各自对比的基础上,得到了一些结果。