全文获取类型
收费全文 | 702篇 |
免费 | 57篇 |
国内免费 | 79篇 |
专业分类
化学 | 446篇 |
晶体学 | 7篇 |
力学 | 55篇 |
综合类 | 22篇 |
数学 | 161篇 |
物理学 | 147篇 |
出版年
2024年 | 2篇 |
2023年 | 19篇 |
2022年 | 45篇 |
2021年 | 29篇 |
2020年 | 53篇 |
2019年 | 37篇 |
2018年 | 30篇 |
2017年 | 26篇 |
2016年 | 38篇 |
2015年 | 36篇 |
2014年 | 34篇 |
2013年 | 55篇 |
2012年 | 39篇 |
2011年 | 58篇 |
2010年 | 28篇 |
2009年 | 41篇 |
2008年 | 39篇 |
2007年 | 34篇 |
2006年 | 35篇 |
2005年 | 18篇 |
2004年 | 14篇 |
2003年 | 10篇 |
2002年 | 16篇 |
2001年 | 13篇 |
2000年 | 14篇 |
1999年 | 12篇 |
1998年 | 13篇 |
1997年 | 14篇 |
1996年 | 9篇 |
1995年 | 8篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有838条查询结果,搜索用时 10 毫秒
91.
Cheng Yanping 《高等学校计算数学学报(英文版)》2000,9(1):71-82
1 IntroductionWeshallconsiderthemodelformiscibledisplacementofonecompressiblefluidbyanotherinahorizontalreservoirΩ R2 ofunitthicknessdescribedbythenonlinearparabolicsystem[6]d(c) p t+ ·u =d(c) p t- · (a(c) p) =q ,(1.1)φ c t+b(c) p t+u· c - · (D(u) c =(^c -c)q ,(1.2 )u·ν =(D(u) c-cu)… 相似文献
92.
Yanping Sun Qingsong Tang Cheng Zhao Yuejian Peng 《Journal of Optimization Theory and Applications》2014,163(1):57-79
The Graph-Lagrangian of a hypergraph has been a useful tool in hypergraph extremal problems. In most applications, we need an upper bound for the Graph-Lagrangian of a hypergraph. Frankl and Füredi conjectured that the \({r}\) -graph with \(m\) edges formed by taking the first \(\textit{m}\) sets in the colex ordering of the collection of all subsets of \({\mathbb N}\) of size \({r}\) has the largest Graph-Lagrangian of all \(r\) -graphs with \(m\) edges. In this paper, we show that the largest Graph-Lagrangian of a class of left-compressed \(3\) -graphs with \(m\) edges is at most the Graph-Lagrangian of the \(\mathrm 3 \) -graph with \(m\) edges formed by taking the first \(m\) sets in the colex ordering of the collection of all subsets of \({\mathbb N}\) of size \({3}\) . 相似文献
93.
Within the framework of effective-mass approximation, the effects of a laser field on the ground-state donor binding energy in zinc-blende (ZB) GaN/AlGaN quantum well (QW) have been investigated variationally. Numerical results show that the donor binding energy is highly dependent on QW structure parameters and Al composition in ZB GaN/AlGaN QW. The laser field effects are more noticeable on the donor binding energy of an impurity localized inside the QW with small well width and low Al composition. However, for the impurity located in the vicinity of the well edge of the QW, the donor binding energy is insensible to the variation of Al composition, well width and laser field intensity in ZB GaN/AlGaN QW. In particular, the competition effects between laser field and quantum confinement on impurity states have also been investigated in this paper. 相似文献
94.
95.
Yanping Liu 《Applied Surface Science》2007,253(21):8571-8574
Three-dimensional (3D) composite colloidal photonic crystals with SiO2 core and ZnO shell were fabricated on borosilicate glass (BSG) substrate by a two-stage deposition method. Scanning electron microscopy (SEM) measurements show that both the pre-deposited SiO2 and SiO2/ZnO core-shell structures are oriented with their (1 1 1) axes parallel to the substrates. Optical measurement reveals that the periodic arrays exhibit a photonic band gap in the (1 1 1) direction. The optical properties of SiO2/ZnO core-shell structures strongly depend on the size dispersions of colloidal spheres and the intrinsic defects in the sample. 相似文献
96.
97.
Pingping Yao Yunfeng Qiu Dr. Penglei Chen Dr. Yanping Ma Dr. Shenggui He Prof. Dr. Jian‐Yu Zheng Prof. Dr. Minghua Liu Prof. Dr. 《Chemphyschem》2010,11(3):722-729
Molecular assemblies of metalloporphyrins trans‐dichloro(5,10,15,20‐tetra‐p‐tolylporphyrinato)tin(IV) (SnCl2TPPMe) and trans‐dihydroxo(5,10,15,20‐tetra‐p‐tolylporphyrinato)tin(IV) (Sn(OH)2TPPMe), which have two trans axial ligands, as well 5,10,15,20‐tetrakis(4‐methoxyphenyl)‐21H,23H‐porphine iron(III) chloride (FeClTPPOMe) and 5,10,15,20‐tetraphenyl‐21H,23H‐porphine manganese(III) chloride (MnClTPP), which have one axial ligand, are interfacially organized by Langmuir and Langmuir–Blodgett (LB) techniques. SnCl2TPPMe and Sn(OH)2TPPMe form nanofibrous structures which can display distinct supramolecular chirality, although the molecular units themselves are achiral, while FeClTPPOMe and MnClTPP form irregular nanoparticles that display negligible supramolecular chirality. An interpretation in terms of the effects of the axial ligands is proposed for this interesting phenomenon. Moreover, compared with assemblies of the diprotonated free‐base porphyrins, which are fabricated by interfacial (air/2.4 M HCl) organization of free‐base porphyrin, those of SnCl2TPPMe and Sn(OH)2TPPMe display higher stability in terms of supramolecular chirality. These results indicate that the assembly properties of metalloporphyrins can essentially be affected by the axial ligands that are attached to their chromophores, and that stable chiral porphyrin supramolecular associations can be easily produced by using achiral metalloporphyrins bearing two trans axial ligands. 相似文献
98.
Synthesis and Characterization of Three Diverse Coordination Frameworks under Co-ligand Intervention
The chelating organic ligands of 2,2’-bipyridine (2,2’-bipy), di(pyrid-2-yl)amine (dpa) and 2,6-di(pyrid-2-ylamino)pyridine (dpap) were respectively applied to react with H2fum (fumaric acid) and copper salts, affording three different complexes [Cu2(fum)(2,2’-bipy)4]•2ClO4 (1), [Cu2(µ-OH)2(fum)(dpa)2]•2H2O (2) and [Cu(SO4)(H2O)(dpap)]•H2O (3). These complexes were determined by single-crystal X-ray diffraction. Each penta-coordinated Cu(II) ion exhibits a distorted trigonal bipyramidal geometry in 1. The fum ligand links copper ions to form a dinuclear copper unit. While in 2, the fum ligands connect [Cu2(µ-OH)2(dpa)2] unit to construct a 1D zigzag chain. Unexpectedly, when dpap instead of dpa was used under the same conditions, only one mononuclear complex 3 was formed. Crystal packings show that 1—3 form 3D supramolecular architectures through non-covalent interactions (multiple hydrogen bonds and C—H…π/π-π interactions). In addition, the study of the magnetic property reveals dominating ferromagnetic interactions between Cu(II) atoms in 1. 相似文献
99.
Jingjing Yuan Yanping Zhu Mi Lian Qinghe Gao Meicai Liu Fengcheng Jia Anxin Wu 《Tetrahedron letters》2012,53(10):1222-1226
Eight unsymmetrical N and/or O-bridged calixarene derivatives were obtained by 1 (naphthalene-2,7-diol), 2 (bis(4-hydroxyphenyl)methanone), 3 (4,4′-methylenedianiline), 4 (3,3′-methylenedianiline), 5 (4,4′-oxydianiline) and 6 (4,4′-(perfluoropropane-2,2-diyl)dianiline) reacting with fragment a (4,4′-bis(dichloro-s-triazinyloxy)propane-2,2-diyldibenzene) and b (N,N′-bis(dichloro-s-triazinyl)-4,4′-methylenedianiline) under very mild reaction conditions via efficient fragment coupling strategy. We also obtained the crystal structure of 1a (tetraoxocalix[2](propane-2,2-diyldibenzene,naphthalene)[2]triazine) which can form a molecular capsule by two dimers with C–H?N and C–H?O quadruple hydrogen bonds, and it has the encapsulation ability toward solvent molecules. 相似文献
100.
全球约有1.7亿人感染丙型肝炎病毒(HCV),至今尚无有效的疫苗和治疗药物。目前干扰素-α和利巴韦林联用抗HCV 的标准治疗方案存在严重不良反应。近年来,新型抗HCV的研究主要集中于针对病毒感染的特异性靶点寻找新的抑制剂。NS5B聚合酶因其在HCV RNA基因组复制中的关键性作用,是目前抗HCV药物设计的重要靶点之一。NS5B聚合酶抑制剂可分为核苷类抑制剂(NIs)和非核苷类抑制剂(NNIs)。自从第一个NS5B NNIs苯并咪唑类化合物被报道以来,大量不同结合位点NS5B NNIs相继被报道,一些化合物在临床研究中表现出了可喜的疗效。本文综述了苯并噻二嗪类、苯并咪唑类、吲哚类、噻吩羧酸类、喹啉酮类、二氢吡喃类和二酮酸类等 NS5B NNIs的研究进展,旨在为该类抑制剂的开发研究提供参考。 相似文献