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181.
Two homologous series of mesogenic materials which incorporate a 1,4-tetrafluorophenylene moiety and a terminal cyano- or nitro-substituent have been synthesized by using palladiumcatalysed coupling procedures. The compounds exhibit nematic and/or smectic A phases. 相似文献
182.
双(十二烷基亚磺酰)乙烷溶剂萃取钯及其机理的研究 总被引:2,自引:0,他引:2
本文研究用双(十二烷基亚磺酰)乙烷萃取钯的性能,在KI存在下从7mol/L盐酸介质中用含有BDSE的氯仿能定量萃取钯,有机的钯可被硫脲或氨溶液反萃继之用TMK-TritonX-100光度法测定,研究了萃取的最佳条件及干扰情况,斜率法测得萃合物组成为Pd:I:BDSE=1:2:1,红外光谱证实萃合物中BDSE的二个亚砜以硫原子与钯配位,萃合物为异位体络合物,提出了选择性萃取分离钯的新方法。 相似文献
183.
Y. Jao W. L. Cheng H. J. Chen C. C. Shaeh C. C. Huang Y. M. Lin 《Journal of Radioanalytical and Nuclear Chemistry》1995,194(2):411-417
This study was performed under the joint TRMC/INER program for the determination of low level85Kr and133Xe concentrations in the environmental air samples. Based on cryogenic adsorption of krypton and xenon on charcoal followed by chromatographic separation from other gases, the85Kr and133Xe recovered from 200 liters of atmospheric air can be determined by either on-line gas flow proportional counter or liquid scintillation counting. The recovery yields of krypton and xenon examined by using85Kr and133Xe tracers were nearly 100%. The minimum detectable activity of85Kr and133Xe by gas flow proportional counting is about 7.40 Bq. The method is satisfactory for environmental monitoring applications under abnormal conditions of nuclear facilities. However, for lower level environmental85Kr and133Xe measurements, the liquid scintillation counting method can be applied due to their extremely low detection limits (i.e. 0.107 Bq and 0.093 Bq for85Kr and133Xe, respectively). Using this method, the measurable limits of concentrations are 0.535 Bq/m3 and 0.466 Bq/m3 for85Kr and133Xe, respectively. 相似文献
184.
酞菁钴薄膜的折射率及吸收特性 总被引:3,自引:1,他引:2
通过真空镀法在单晶硅片上制备了酞菁钴薄膜,在波长扫描和入射角可变全自动椭圆偏振光谱仪上研究了CoPc薄膜的椭偏光谱并分析了其电子结构。 相似文献
185.
186.
187.
188.
This article concerns the existence of global smooth solution for scalar conservation laws with degenerate viscosity in 2-dimensional space. The analysis is based on successive approximation and maximum principle. 相似文献
189.
C. Scheidenberger K. Beckert P. Beller F. Bosch C. Brandau D. Boutin L. Chen B. Franzke H. Geissel R. Knöbel C. Kozhuharov J. Kurcewicz S. A. Litvinov Yu. A. Litvinov M. Mazzocco G. Münzenberg F. Nolden W. R. Plaß M. Steck B. Sun H. Weick M. Winkler 《Hyperfine Interactions》2006,173(1-3):61-66
One important goal of the ILIMA project at FAIR is the study of masses and decay properties of relativistic isomeric beams
stored and cooled in the planned storage-ring complex. A new scheme is described, where a storage-cooler ring is used for
high-resolution mass separation. Experimental results on the separation of the isobaric pair 140Pr-140Ce are presented.
P. Beller, deceased. 相似文献
190.
On the basis of Tsallis’ entropy and the joint probability factorization condition, two controversial problems existing in Tsallis’ statistics are investigated, where one is whether energy is extensive or not and the other is whether it is necessary to introduce the so-called generalized zeroth law of thermodynamics or not. The results obtained show clearly that like entropy, energy is also nonextensive in Tsallis’ statistics, and that the zeroth law of thermodynamics has been implicitly used in Tsallis’ statistics since 1988. Moreover, it is expounded that the standard energy additivity rule adopted by a great number of researchers is not suitable in Tsallis’ statistics, because its corollary is in contradiction with the zeroth law of thermodynamics. 相似文献