亚酞菁:一种新的信息光子学材料

亚酞菁是一种可望在信息光子学技术中获得重要应用的新型染料,其优良的非红性光学性质源于它特有非中心对称三维近平面锥形结构以及较大的共轭体和丰富的π电子,此外,基于它的短波长光学特性,这类材料也可能在高密度光存储中得到应用,文章综述了亚酞菁的一般结构和性能及其在非红性光学和光存储等方面的应用。     

两种教学模式在独立学院理工类课程中教学的应用——以可编程控制技术课程教学为例

针对独立学院学生积极思维分析能力相对较弱从而造成理工类课程的教学存在一定困难的问题,本文基于可编程控制技术课程的教学及实验,分析了独立学院学生学习的特殊性,探讨了两种不同的教学模式在其实际教学应用中出现的问题,并且提出一种基于实例的循序渐进的教学方法.     

求解高次方程的一个C＋＋/MPI并行程序

本文用C＋＋/MPI并行程序实现了一个高次方程的大范围收敛并行求解算法（正项分解-半线性化技术），通过在微机机群和单机上测试表明，该程序在微机机群上求解高次方程的速度明显高于单机的求解速度，该程序具有实用价值。     

Excess volumes and densities of binary mixtures of γ-butyrolactone + 1, 3, 5-trimethylbenzene or 1, 2, 4-trimethylbenzene at several temperatures

Densities of two binary mixtures formed by γ-butyrolactone with 1,3,5-trimethylbenzene and 1,2,4-trimethylbenzene have been determined over the full range of compositions over the temperature range (288.15 K to 308.15 K) and the local barometric pressure using a vibrating-tube densimeter. From these experiments, excess molar volumes () have been calculated. It is found to be positive with a maximum at about the mole fraction of 0.5. Excess volumes were also fitted to a Redlich–Kister type equation. Our result shows increases when temperature increases in the studied systems.     

Synthesis and optical properties of 10 mol% Ce, 5 mol% Tb co-doped KGdF4 and GdF3 submicro/nanocrystals

By controlling the pH values of prepared solutions, the 10 mol% Ce³⁺, 5 mol% Tb³⁺ co-doped KGdF₄ (synthesized with pH = 3) and the 10 mol% Ce³⁺, 5 mol% Tb³⁺ co-doped GdF₃ (synthesized with pH = 1) submicro/nanocrystals have been synthesized based on a citric acid assisted hydrothermal method. For comparison, the samples synthesized by co-precipitation method (without hydrothermal treatment) with pH = 3 and 1 were also collected. The X-ray diffraction data illustrate that the hydrothermal treated KGdF₄ sample crystallizes in the cubic phase and the GdF₃ sample crystallizes in the orthorhombic phase. However, the samples synthesized by co-precipitation method with pH = 3 and 1 are both cubic phase KGdF₄. The field emission scanning electron microscopy images suggest that the hydrothermal treated KGdF₄ submicro/nanocrystals present spherical morphology and the GdF₃ submicrocrystals are rhombic-shaped. And the photoluminescence excitation and emission spectra as well as the luminescent dynamic curves demonstrate the difference in optical properties of the two hydrothermal treated samples.     

Luminescent properties of La2LiTaO6:Mn4+ and its application as red emission LEDs phosphor

A novel phosphor, Mn⁴⁺ doped La₂LiTaO₆, was developed by solid-state reaction method. The luminescent spectra and emission efficiencies of La₂LiTaO₆:Mn _x ⁴⁺ (x = 0.001, 0.003, 0.005 and 0.01) were discussed. The effects of co-doped charge compensation ions, M = Mg²⁺, Ca²⁺, Na⁺, were investigated, respectively. The excitation spectra indicated that La₂LiTaO₆:Mn⁴⁺ could be effectively excited by both NUV light and blue light. The emission spectra of the phosphor exhibit a broadband ranging from 670 to 720 nm with the maximum at about 709 nm in deep red region. The co-doping of Mg²⁺ could significantly improve the luminescent properties of La₂LiTaO₆:Mn⁴⁺. Thus, phosphor La₂LiTaO₆:Mn⁴⁺, Mg²⁺ can serve as a key component to improve color rendering of blue-chip white-LEDs.     

Lepton flavor violating <Emphasis Type="Italic">Z</Emphasis>-decays in supersymmetric seesaw model

In the supersymmetric seesaw model, large flavor mixings of sleptons induce the lepton flavor violating (LFV) interactions ( ), which give rise to various LFV processes. In this work we examine the LFV decays . Subject to the constraints from the existing neutrino oscillation data and the experimental bounds on the decays , these LFV Z-decays are found to be sizable, and among them the largest-rate channel can occur with a branching ratio of 10^-8 and may be accessible at the LHC or GigaZ experiment.Received: 1 September 2003, Published online: 20 November 2003     

Parity-violating electron deuteron scattering and the proton's neutral weak axial vector form factor

We report on a new measurement of the parity-violating asymmetry in quasielastic electron scattering from the deuteron at backward angles at Q2=0.038 (GeV/c)2. This quantity provides a determination of the neutral weak axial vector form factor of the nucleon, which can potentially receive large electroweak corrections. The measured asymmetry A=-3.51+/-0.57 (stat)+/-0.58 (syst) ppm is consistent with theoretical predictions. We also report on updated results of the previous experiment at Q2=0.091 (GeV/c)2, which are also consistent with theoretical predictions.     

Anisotropic defect reduction in non-polar a-plane GaN grown by hydride vapor phase epitaxy on maskless patterned templates

Several non-polar a-plane GaN films had been grown by hydride vapor phase epitaxy (HVPE) on different designed metal organic chemical deposition (MOCVD) GaN templates, which exhibited various ridge-like sidewall facets surface morphologies. The templates induced a lateral growth at the early stage of the HVPE growth, and resulted in a kind of maskless epitaxy lateral overgrown (ELO) process. It is found that the dislocation reduced differently along [1 0 0 0] and [] directions in these HVPE a-plane GaN layers. In [0 0 0 1] direction, the dislocation reduction resulted from the optimal surface roughness value of the template. In [] direction, the inclined facet might be a main factor for the dislocation reduction in HVPE-GaN films. The maskless ELO process had a significant influence on decreasing the dislocation density.     

A simple pathway to ordered silica nanopattern from self-assembling of block copolymer containing organic silicon block

Self-assembly of block copolymer is an effective strategy to prepare periodic structures at nanoscale. In this paper an unique and very simple method to prepare inorganic silica nanopattern is demonstrated from self-assembling of poly(styrene-block-dimethylsiloxane) (PS-b-PDMS) on the surface of silicon wafer. To simplify the patterning process, at first we obtain highly ordered PDMS microdomains, which are covered with PS layer by controlling solvent vapor annealing conditions. Following exposure to UV/O₃ irradiation, nanopatterned surface consisting of silicon oxide is fabricated directly via selectively etching PS phase and converting PDMS phase into silicon oxide. As tuning the composition of the block copolymer, hexagonally packing dot and straight stripe pattern can be obtained. Finally, the time evolution from spheres morphology to aligned long cylinders is discussed. These results hold promise for nanolithography and the fabrication of nanodevices.