Effect of temperature gradient on Marangoni condensation heat transfer for ethanol–water mixtures

This paper experimentally studied the effect of macroscopic temperature gradient on Marangoni condensation of ethanol–water vapor mixtures under a wide range of concentrations. For each concentration, the experiment was performed at different velocities and pressures. An oblique copper block was employed to create surface temperature gradient. The results indicated that local heat flux was varied along transversal condensation surface, which was caused by surface temperature gradient. This difference in heat flux might be attributed to the variation of condensate thickness on condensation surface. In addition, a mean heat transfer coefficient was derived along transversal condensation surface. For low ethanol concentration (0.5%, 1%), the coefficient kept a high value over a relative wide range of vapor-to-surface temperature difference (<10 K) and could be augmented as much as 15% as compared with literature under similar experimental condition. Moreover, the mean heat transfer coefficient generally increased with increasing velocity or pressure for all concentrations of the ethanol–water mixtures.     

An Efficient One-Pot Synthesis of Nitriles from Carboxylic Acids Without Solvent Under Microwave Irradiation

Nitriles were prepared from alkyl and aryl carboxylic acids in dry media conditions, under microwave irradiation. Heating of the carboxylic acid, urea and amidosulfonic acid adsorbed on alumina support in a microwave oven affords nitriles in 20–93% yields.     

Simple and Efficient Synthesis of Belinostat

A novel synthesis of belinostat (1) starting from 3-nitrobenzaldehyde has been developed. The key step in this sequence involves the conversion of (2E)-3-(3-aminophenyl)acrylic acid methyl ester to (2E)-3-(3-chlorosulfonylphenyl)acrylic acid methyl ester via diazotization and sulfonylation.     

IRMPD Action Spectroscopy of Alkali Metal Cation–Cytosine Complexes: Effects of Alkali Metal Cation Size on Gas Phase Conformation

The gas-phase structures of alkali metal cation-cytosine complexes generated by electrospray ionization are probed via infrared multiple photon dissociation (IRMPD) action spectroscopy and theoretical calculations. IRMPD action spectra of five alkali metal cation–cytosine complexes exhibit both similar and distinctive spectral features over the range of ~1000–1900 cm^-1. The IRMPD spectra of the Li⁺(cytosine), Na⁺(cytosine), and K⁺(cytosine) complexes are relatively simple but exhibit changes in the shape and shifts in the positions of several bands that correlate with the size of the alkali metal cation. The IRMPD spectra of the Rb⁺(cytosine) and Cs⁺(cytosine) complexes are much richer as distinctive new IR bands are observed, and the positions of several bands continue to shift in relation to the size of the metal cation. The measured IRMPD spectra are compared to linear IR spectra of stable low-energy tautomeric conformations calculated at the B3LYP/def2-TZVPPD level of theory to identify the conformations accessed in the experiments. These comparisons suggest that the evolution in the features in the IRMPD action spectra with the size of the metal cation, and the appearance of new bands for the larger metal cations, are the result of the variations in the intensities at which these complexes can be generated and the strength of the alkali metal cation-cytosine binding interaction, not the presence of multiple tautomeric conformations. Only a single tautomeric conformation is accessed for all five alkali metal cation–cytosine complexes, where the alkali metal cation binds to the O2 and N3 atoms of the canonical amino-oxo tautomer of cytosine, M⁺(C₁).

Characterization of Polymers by Direct Pyrolysis/Chemical Ionization Mass Spectrometry

The characterization of polymers by pyrolysis directly in the ion source of a double focusing magnetic sector mass spectrometer, operating in the chemical ionization mode, is described. Pyrolysis is achieved by two different probe techniques. A low temperature, slow heating rate direct insertion probe (DIP) is used at 400°C, and a specifically constructed high temperature, fast heating rate, high temperature pyrolysis (HTP) probe is used at 1000°C. This probe is capable of achieving pyrolysis temperatures of 1200°C at controlled heating rates up to 20,000°C/s. The mass spectrometric analysis of the pyrolysis products was achieved under chemical ionization (CI) conditions utilizing methane, isobutane, and ammonia as reagent gases. Under CI conditions the molecular ions formed in the mass spectrometer show little tendency to fragment. The CI mass pyrograms are very simple, with each peak in the spectra ascribable to a particular component in the pyrolysis product mixture. The results of the two probe pyrolysis techniques are compared and the utility of each technique for the characterization of polymers is demonstrated using the vinyl polymers polymethyl methacrylate, polyvinyl chloride, and polystyrene.     

Selective recognition and electrochemical detection of p-nitrophenol based on a macroporous imprinted polymer containing gold nanoparticles

We have combined the molecular imprinting and the layer-by-layer assembly techniques to obtain molecularly imprint polymers (MIPs) for the electrochemical determination of p-nitrophenol (p-NPh). Silica microspheres functionalized with thiol groups and gold nanoparticles (Au-NPs) were assembled on a gold electrode surface layer by layer. The electrode was then immersed into a solution of pyrrole and p-NPh (the template), and electropolymerization led to the creation of a polymer-modified surface. After the removal of the silica spheres and the template, electrochemical impedance spectroscopy and differential pulse voltammetry (DPV) were employed to characterize the surface. The results demonstrated the successful fabrication of macroporous MIPs embedded with Au-NPs on the gold electrode. The effects of monomer concentration and scan rate on the performance of the electrode were optimized. Excellent recognition capacity is found for p-NPh over chemically similar species. The DPV peak current is linearly related to concentration of p-NPh in the 0.1 μM to 1.4 mM range, with a 0.1 μM limit of detection (at S/N?=?3).

Entanglement of n-heptane and iso-butanol chemistries in flames fueled by their mixtures

This paper concerns itself with the entanglement of the high-temperature oxidation chemistry of n-heptane and iso-butanol in flames fueled by their mixtures. While in many cases the chemistries of the individual fuel components do not interact in mixture flames, in this work, we revealed interactions between the individual species pools originating from n-heptane and iso-butanol oxidation. In a coordinated experimental and modeling effort, chemical structures of three low-pressure premixed flames fueled by different blends of n-heptane and iso-butanol were determined using flame-sampling molecular-beam mass spectrometry with synchrotron-based single-photon ionization and chemical kinetic modeling. The chemical kinetic model, which is based on the reaction set that was used previously [Braun-Unkhoff et al., Proc. Combust. Inst., 2017, 36, 1311–1319], was now extended by an n-heptane sub-mechanism. The overall good performance of the model allows for an extraction of chemically relevant information that highlights the entanglement between the individual fuel-specific species pools. For example, it was shown that methyl radicals, in part from iso-butanol oxidation (i.e., from the decomposition of α-iso-butanol radicals) can participate in n-heptane consumption processes through H-abstraction reactions. Further interactions are related to the formation of the methylallyl radical and aromatics formation. The relevance of such interactions is also discussed regarding the formation of oxygenated byproducts.     

Fluorescein-bridged Perylene Bisimide Dimer for Use as Liquid Crystal: Studies on Mesomorphic and Fluorescence Properties

Journal of Fluorescence - A novel fluorescein-bridged perylene bisimide (PBI) dimer for liquid crystal (LC) with geometrically symmetric structure was developed. The mesomorphic results indicated...