首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   21篇
  免费   1篇
  国内免费   2篇
化学   12篇
力学   3篇
数学   1篇
物理学   8篇
  2019年   1篇
  2017年   1篇
  2016年   2篇
  2015年   1篇
  2014年   2篇
  2012年   2篇
  2011年   1篇
  2010年   4篇
  2009年   2篇
  2008年   2篇
  2006年   1篇
  2005年   3篇
  2002年   1篇
  1998年   1篇
排序方式: 共有24条查询结果,搜索用时 15 毫秒
11.
We have carried out the hohlraum experiments about radiation temperature scaling on the Shenguang-Ⅱ (SG- Ⅱ) laser facility with eight laser beams of 0.35#m, pulse duration of about 1.0ns and total energy of 2000J. The reradiated x-ray flux through the laser entrance hole was measured using a soft x-ray spectrometer. The measured peak radiation temperature was 170eV for the standard hohlraum and 150 eV for the 1.5-scaled one. We have derived the radiation temperature scaling law, in which the laser hohlraum coupling efficiency is included. With an appropriate coupling efficiency, the coincidences between experimental and scaling hohlraum radiation temperatures are rather good.  相似文献   
12.
以球形大孔树脂(SMR)、聚乙二醇分别作聚乙烯亚胺(PEI)的载体和黏结剂,制得PEI/SMR吸附材料.考察了PEI/SMR材料对CO2的吸脱附性能,并对吸附过程进行了分析.研究结果表明:(1)当PEI担载量为40%、吸附温度为30℃时,PEI/SMR样品对C02的平衡吸附量达4.02mrnol/g,并具有良好的吸脱附循环性能;(2)当模拟烟道气中的湿度为14.5%时,由于部分H20参与了化学反应,使得PEI/SMR样品对C02的平衡吸附量提高了5.7%;(3)C02在PEI/SMR的吸附,先是CO2分子吸附在SMR材料的表面,然后被吸附的CO2分子从表面扩散进入PEI主体相进行化学反应.  相似文献   
13.
不同碳源对LiFePO4/C复合正极材料性能的影响   总被引:6,自引:1,他引:6  
唐致远  阮艳莉 《化学学报》2005,63(16):1500-1504
采用固相反应法在惰性气氛下合成了橄榄石型LiFePO4/C复合正极材料. 采用XRD, SEM和激光粒度分布(LSD)以及电化学测试等手段对目标材料进行了结构表征和性能测试. 考察了葡萄糖、乙炔黑以及石墨等不同碳源对目标材料性能的影响. 结果表明, 以葡萄糖作为碳源的正极材料具有优良的电化学性能, 首次放电比容量达142.5 mAh/g, 循环30次后, 容量衰减只有2.5%. 分析了不同碳源对目标材料性能影响的原因.  相似文献   
14.
NCO和NCS是大气化学中非常引人关注的自由基,它们均有三个原子并且两个端基原子均可作为电子给体形成σ-型氢/卤键.本文在MP2/aug-cc-pVDZ水平上研究了NCO/NCS...XY(X=H,Cl;Y=F,Cl,Br)体系中的弱化学键.计算结果表明,氢/卤原子与N原子相连形成的复合物比与O/S原子相连形成的复合物稳定;氢/卤键的稳定性由分子静电势决定,而非原子电负性;对相同的电子给体B(B=N,O/S)和相同的卤原子来说,化学键的强度按Y=F,Cl,Br的顺序逐渐减弱.在氢/卤键形成过程中,自旋电子密度在电子给体和电子受体间的转移较少,但它在自由基内部发生重排,就本文研究的所有复合物而言,自旋电子密度均转移向XY分子的相反位置.  相似文献   
15.
目前治疗阿尔茨海默症(Alzheimer’s disease,AD)的主要药物为乙酰胆碱酯酶抑制剂(AChEI).为探讨石松碱类化合物对AChE的抑制作用,以6-羟基石松碱(6-hydroxylycopodine,HLD)为对象,应用核磁共振、分子对接、酶活性测定、分子动力学模拟及自由能分析,研究了HLD与AChE的相互作用.研究发现6-羟基石松碱对乙酰胆碱酯酶具有混合型抑制作用,其结合作用主要来自氢键和范德华作用.  相似文献   
16.
Microscopic phase field simulation is performed to study antisite defect type and temporal evolution characteristic of D022-Ni3V structure in Ni75AlxV25-x ternary system.The result demonstrates that two types of antisite defect VNi and NiV coexist in D022 structure;however,the amount of NiV is far greater than VNi;when precipitates transform from D022 singe phase to two phases mixture of D022 and L12 with enhanced Al:V ratio,the amount of VNi has no evident response to the secondary L12 phase,while NiV exhi...  相似文献   
17.
18.
[60]Fullerenes attached with piperidinodithiocarboxylate dyad (1) and 7-chloro-1,2,3,4-tetrahydrophenazine (2) were efficiently synthesized through Diels-Atder cycloaddition with dienes. The physical properties of the triplet states of these compounds, in which strong electron acceptor moieties were covalently attached to C60 cores, were investigated by nanosecond laser flash photolysis. The excited triplet states in benzonitrite have been evaluated by observing the transient absorption bands in the near-IR region. The HOMO and LUMO were calculated by semiempirical methods AM1, which could predict the intramolecular photoinduced electron transfer in 1 and 2, and the nanosecond transient absorption spectra observed experimentally in solution were in excellent agreement with the calculated ones.  相似文献   
19.
In this paper, the semi-dimpled slit fin is proposed and the characteristics of heat transfer and fluid flow are analyzed based on the orthogonal experiment design method. A serial studies on the effects of fin pitch, arrangement of semi-dimple, dimple radius on heat transfer and flow characteristics of semi-dimpled slit fin are investigated. The computational results show fin pitch (Fp) has significantly effected on the performance of heat transfer and fluid flow, the influence of arrangement of semi-dimple, the dimple radius (R) and the opening direction of semi-dimples dwindle. At the same time, compared to the general semi-dimpled slit fin, the heat transfer coefficient and JF factors of the optimized fin increase by 10.7–25.1 and 2.6–7.7 %, respectively. When Re ≤ 1,521, the overall performance of slit fin is better than that of optimized fin; while Re > 1,521, the overall performance of optimized fin is better than that of slit fin. Finally, the performance evaluation plot of enhanced heat transfer of heat exchanger is applied to analyze the optimized fin, it can be seen that optimization fin have better heat transfer performance under the same power consumption.  相似文献   
20.
An amperometric enzyme electrode based on direct covalent immobilization of tyrosinase on a boron-doped diamond (BDD) electrode has been developed for the detection of phenolic compounds. Combined chemical and electrochemical modifications of the BDD film with 4-nitrobenzenediazonium tetrafluoroborate, an aminophenyl-modified BDD (AP–BDD) surface was produced, and then the tyrosinase was covalently immobilized on the BDD surface via carbodiimide coupling. The response dependences of the enzyme electrode (Tyr–AP–BDD electrode) on pH of solution, applied potential, oxygen level and phenolic compounds diffusion were studied. The Tyr–AP–BDD electrode shows a linear response range of 1–200, 1–200 and 1–250 μM and sensitivity of 232.5, 636.7 and 385.8 mA M−1 cm−2 for phenol, p-cresol and 4-chlorophenol, respectively. 90 percent of the enzyme activity of the Tyr–AP–BDD electrode is retained for 5 weeks storing in 0.1 M PBS (pH 6.5) at 4 °C.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号