全文获取类型
收费全文 | 28543篇 |
免费 | 4736篇 |
国内免费 | 4172篇 |
专业分类
化学 | 21790篇 |
晶体学 | 449篇 |
力学 | 1456篇 |
综合类 | 308篇 |
数学 | 3117篇 |
物理学 | 10331篇 |
出版年
2024年 | 99篇 |
2023年 | 521篇 |
2022年 | 994篇 |
2021年 | 1044篇 |
2020年 | 1129篇 |
2019年 | 1176篇 |
2018年 | 1016篇 |
2017年 | 1053篇 |
2016年 | 1382篇 |
2015年 | 1441篇 |
2014年 | 1783篇 |
2013年 | 2213篇 |
2012年 | 2646篇 |
2011年 | 2710篇 |
2010年 | 2051篇 |
2009年 | 1953篇 |
2008年 | 2069篇 |
2007年 | 1920篇 |
2006年 | 1773篇 |
2005年 | 1419篇 |
2004年 | 1026篇 |
2003年 | 814篇 |
2002年 | 774篇 |
2001年 | 683篇 |
2000年 | 606篇 |
1999年 | 508篇 |
1998年 | 377篇 |
1997年 | 336篇 |
1996年 | 298篇 |
1995年 | 268篇 |
1994年 | 251篇 |
1993年 | 180篇 |
1992年 | 153篇 |
1991年 | 150篇 |
1990年 | 145篇 |
1989年 | 103篇 |
1988年 | 84篇 |
1987年 | 64篇 |
1986年 | 68篇 |
1985年 | 51篇 |
1984年 | 19篇 |
1983年 | 18篇 |
1982年 | 20篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1979年 | 9篇 |
1976年 | 3篇 |
1971年 | 4篇 |
1957年 | 5篇 |
1936年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
941.
942.
Zhang Han Liu Shang-Hao Liu Feng Yan Shi-Long Li Wei-Yi 《Journal of Thermal Analysis and Calorimetry》2018,132(1):327-336
Journal of Thermal Analysis and Calorimetry - The thermogravimetric techniques and differential thermal analysis have been employed in this work to analyze the macro-reactions mechanism of the... 相似文献
943.
讨论了3种变形谐振子势:左右两边不同参数的谐振子势、左边方形势加右边谐振子势和谐振子势中间加δ势中的能量本征态函数.这些函数都可以由厄米函数表示.由波函数及其一次导数在原点的衔接条件,得到了能谱方程. 相似文献
944.
Synthesis and rheological investigation of self‐healable deferoxamine grafted alginate hydrogel 下载免费PDF全文
Guanzhe Xu Yan Xiao Liang Cheng Runhua Zhou Heng Xu Yimin Chai Meidong Lang 《Journal of Polymer Science.Polymer Physics》2017,55(11):856-865
Deferoxamine grafted alginate (SA‐DFA) was successfully synthesized via amidation of sodium alginate with deferoxamine mesylate as determined by H‐NMR and elemental analysis. SA‐DFA with different graft yield was obtained by adjusting the ratio of sodium alginate and deferoxamine mesylate. It was found that aqueous solution of SA‐DFA could form hydrogel spontaneously due to hydrogen bonding interactions, which also endowed the SA‐DFA hydrogel with self‐healing capability. The healing efficiency of SA‐DFA hydrogels ranged from 53.64 to 90.16%. In addition, surface morphologies of SA‐DFA hydrogels before/after self‐healing process were demonstrated by SEM images. We anticipated that such self‐healable alginate hydrogel would be applied in the field of wound healing. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 856–865 相似文献
945.
Dr. Yong Guo Dr. Wengang Li Dr. Jingjing Yan Dr. Basem Moosa Dr. Ma'an Amad Prof. Charles J. Werth Prof. Niveen M. Khashab 《化学:亚洲杂志》2012,7(12):2842-2847
Metal‐free fullerene (C60) was found to be an effective catalyst for the reduction of azo groups in basic aqueous solution under UV irradiation in the presence of NaBH4. Use of NaBH4 by itself is not sufficient to reduce the azo dyes without the assistance of a metal catalyst such as Pd and Ag. Experimental and theoretical results suggest that C60 catalyzes this reaction by using its vacant orbital to accept the electron in the bonding orbital of azo dyes, which leads to the activation of the N?N bond. UV irradiation increases the ability of C60 to interact with electron‐donor moieties in azo dyes. 相似文献
946.
为了减小常规L波段高功率微波测量接收天线的结构尺寸及增益,设计了一种基于轴向缝隙馈电的小型化同轴扩张型天线.通过理论分析和数值模拟,选择了较优的结构尺寸,得到天线的增益及方向图特性:在1.3~1.6 GHz范围内,增益从-2.0 dBi变化至0.8 dBi;天线最大辐射方向在物理结构轴向.基于矢量网络分析仪E8362B的天线特性测量结果与数值计算结果基本一致:工作频率从1 3~1 6GHz变化时,增益从-2.3 dBi变化至1.2 dBi;E面方向图主瓣宽度大于 60°,轴向轴比大于35dB,结果表明设计的天线能够满足L波段高功率微波渊量天线低增益小型化要求. 相似文献
947.
A nonsmooth Levenberg-Marquard (LM) method with double parameter adjusting strategies is presented for solving vertical complementarity problems based on the computation of an element of a vextor-valued minimum function’s B-differential in this paper. At each iteration, the LM parameter is adjusted based on the norm of the vector-valued minimum function and the ratio between the actual reduction and the predicted reduction. Under the local error bound condition, which is strictly weaker than nonsingular assumption, the local convergence rate is discussed. Finally, the numerical tests indicate that the present algorithm is effective. 相似文献
948.
Poly(aryl ether ketone) composite membrane as a high‐performance lithium‐ion batteries separator 下载免费PDF全文
Min Xie Mingying Yin Guangdi Nie Jun Wang Ce Wang Danming Chao Xincai Liu 《Journal of polymer science. Part A, Polymer chemistry》2016,54(17):2714-2721
We described the design and synthesis of a modified poly(aryl ether ketone) bearing phenolphthalein and allyl groups (P‐PAEK) via nucleophilic polycondensation. A new kind of composite separator, crosslinked P‐PAEK/polyvinylidene fluoride (c‐P‐PAEK/PVDF) membrane was successfully prepared using phase separation, phase inversion method, and UV crosslinking technique. As a separator of lithium‐ion battery, c‐P‐PAEK/PVDF membrane demonstrates high porosity and uniform distribution of pores with interconnected pathways. Low thermal shrinkage, distinct shut‐down effect, high liquid electrolyte uptake capacity, and exciting liquid electrolyte wettability of the prepared c‐P‐PAEK/PVDF membrane have been revealed through comprehensive study. Moreover, the c‐P‐PAEK/PVDF membrane was applied to assemble a conventional Li/LiFePO4 coin cell, which exhibited hopeful cell performance. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2714–2721 相似文献
949.
S. G. Li Q. Gong C. F. Cao X. Z. Wang J. Y. Yan Y. Wang H. L. Wang 《Optical and Quantum Electronics》2014,46(5):623-640
Since the external cavity quantum dot laser was first demonstrated, the performances have been improved in terms of operation temperature, output power, pulse generator and tuneability based on the naturally size fluctuation of quantum dot. Nowadays, the external cavity quantum dot sources have been successfully used in different absorption spectroscope techniques, in industry, biomedical and research. In this paper we reviewed the recent developments of quantum dot lasers operated in a grating-coupled external cavity system where a single frequency and wide tunable wavelength range were easily obtained by adjusting the grating angle. In all cases, we mainly stressed the significant progresses in understanding of basic optical and electronic properties to enable the importance steps forward. The prospects for further progress directed towards stability, mode-hoping-free tuning range, miniaturization and integration of the external cavity quantum dot lasers also reviewed. 相似文献
950.
With the consideration of mechanism of prevention and control for the spread of viral diseases, in this paper, we propose two novel virus dynamics models where state feedback control strategies are introduced. The first model incorporates the density of infected cells (or free virus) as control threshold value; we analytically show the existence and orbit stability of positive periodic solution. Theoretical results imply that the density of infected cells (or free virus) can be controlled within an adequate level. The other model determines the control strategies by monitoring the density of uninfected cells when it reaches a risk threshold value. We analytically prove the existence and orbit stability of semi-trivial periodic solution, which show that the viral disease dies out. Numerical simulations are carried out to illustrate the main results. 相似文献