全文获取类型
收费全文 | 26195篇 |
免费 | 4324篇 |
国内免费 | 4036篇 |
专业分类
化学 | 20347篇 |
晶体学 | 426篇 |
力学 | 1279篇 |
综合类 | 297篇 |
数学 | 2947篇 |
物理学 | 9259篇 |
出版年
2024年 | 63篇 |
2023年 | 465篇 |
2022年 | 727篇 |
2021年 | 901篇 |
2020年 | 1043篇 |
2019年 | 1106篇 |
2018年 | 915篇 |
2017年 | 965篇 |
2016年 | 1256篇 |
2015年 | 1272篇 |
2014年 | 1617篇 |
2013年 | 2025篇 |
2012年 | 2429篇 |
2011年 | 2544篇 |
2010年 | 1950篇 |
2009年 | 1846篇 |
2008年 | 1951篇 |
2007年 | 1806篇 |
2006年 | 1690篇 |
2005年 | 1350篇 |
2004年 | 996篇 |
2003年 | 783篇 |
2002年 | 740篇 |
2001年 | 651篇 |
2000年 | 574篇 |
1999年 | 481篇 |
1998年 | 352篇 |
1997年 | 312篇 |
1996年 | 266篇 |
1995年 | 254篇 |
1994年 | 233篇 |
1993年 | 168篇 |
1992年 | 145篇 |
1991年 | 135篇 |
1990年 | 121篇 |
1989年 | 89篇 |
1988年 | 73篇 |
1987年 | 53篇 |
1986年 | 60篇 |
1985年 | 49篇 |
1984年 | 18篇 |
1983年 | 18篇 |
1982年 | 18篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1971年 | 4篇 |
1957年 | 4篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
891.
892.
Molecular dynamics simulations of the displacement cascades in Fe-10%Cr systems are used to simulate the primary knocked-on atom events of the irradiation damage at temperatures 300,600,and 750 K with primary knockedon atom energies between 1 and 15 keV.The results indicate that the vacancies produced by the cascade are all in the central region of the displacement cascade.During the cascade,all recoil Fe and Cr atoms combine with each other to form Fe-Cr or Fe-Fe interstitial dumbbells as well as interstitial clusters.The number and the size of interstitial clusters increase with the energy of the primary knocked-on atom and the temperature.A few large clusters consist of a large number of Fe interstitials with a few Cr atoms,the rest are Fe-Cr clusters with small and medium sizes.The interstitial dumbbells of Fe-Fe and Fe-Cr are in the 111 and 110 series directions,respectively. 相似文献
893.
Dr. Tarun Kumar Yan Yang Sirine Sghaier Dr. Yassir Zaid Dr. Xavier F. Le Goff Dr. Elodie Rousset Dr. Fabien Massicot Dr. Dominique Harakat Agathe Martinez Dr. Marc Taillefer Prof. Laurent Maron Prof. Jean-Bernard Behr Dr. Florian Jaroschik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(12):4016-4021
The development of new fluorine-containing building blocks and their efficient synthetic access is currently a challenging research field. Herein, the highly regio- and stereoselective addition of a large range of aldehydes onto trifluoromethylated benzofulvenes was achieved using a simple La/I2/DIBAL-Cl system via a selective C−F bond activation process. This versatile methodology provided homodienyl alcohols bearing a terminal CF2-alkene with potential further applications, as shown by the dehydration to the first benzofulvenes carrying a difluorovinyl group. In addition, for certain electron-poor aldehydes, unprecedented ipso substitution of the CF3 group in a diene was observed, which, according to DFT studies, is related to the presence of the large, Lewis-acidic lanthanum metal. 相似文献
894.
895.
896.
897.
898.
A Pronounced Halogen Effect on the Organogelation Properties of Peripherally Halogen Functionalized Poly(benzyl ether) Dendrons
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Prof. Dr. Yu Feng Hui Chen Zhi‐Xiong Liu Yan‐Mei He Prof. Dr. Qing‐Hua Fan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(14):4980-4990
An interesting halogen‐substituent effect on the organogelation properties of poly(benzyl ether) dendrons is reported. A new class of poly(benzyl ether) dendrons with halo substituents decorating their periphery was synthesized and fully characterized. A systematic study on the gelation abilities, thermotropic behaviors, aggregated microstructures, and mechanical properties of self‐assembled organogels was performed to elucidate the halogen‐substituent effects on their organogelation propensity. It was found that the exact halogen substitutions on the periphery of dendrons exert a profound effect on the organogelation propensity, and dendrons G n ‐Cl (n=2, 3) and G2‐I proved to be highly efficient organogelators. The cooperation of multiple π–π, dispersive halogen, CH–π, and weak C?H ??? X hydrogen‐bonding interactions were found to be the key contributor to forming the self‐assembled gels. Dendritic organogels formed from G n ‐Cl (n=2, 3) in 1,2‐dichloroethane exhibited thixotropic‐responsive properties, and such thixotropic organogels are promising materials for future research and applications. 相似文献
899.
900.
Facile Fabrication of Well‐Dispersed Pt Nanoparticles in Mesoporous Silica with Large Open Spaces and Their Catalytic Applications
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Xianchun Liu Dashu Chen Lin Chen Renxi Jin Dr. Shuangxi Xing Dr. Hongzhu Xing Prof. Yan Xing Prof. Zhongmin Su 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(27):9293-9298
In this paper, a facile strategy is reported for the preparation of well‐dispersed Pt nanoparticles in ordered mesoporous silica (Pt@OMS) by using a hybrid mesoporous phenolic resin‐silica nanocomposite as the parent material. The phenolic resin polymer is proposed herein to be the key in preventing the aggregation of Pt nanoparticles during their formation process and making contributions both to enhance the surface area and enlarge the pore size of the support. The Pt@OMS proves to be a highly active and stable catalyst for both gas‐phase oxidation of CO and liquid‐phase hydrogenation of 4‐nitrophenol. This work might open new avenues for the preparation of noble metal nanoparticles in mesoporous silica with unique structures for catalytic applications. 相似文献