首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4076篇
  免费   98篇
  国内免费   14篇
化学   3051篇
晶体学   30篇
力学   69篇
数学   166篇
物理学   872篇
  2022年   30篇
  2021年   37篇
  2020年   39篇
  2019年   49篇
  2018年   31篇
  2017年   34篇
  2016年   63篇
  2015年   79篇
  2014年   73篇
  2013年   189篇
  2012年   169篇
  2011年   184篇
  2010年   97篇
  2009年   97篇
  2008年   181篇
  2007年   175篇
  2006年   208篇
  2005年   225篇
  2004年   208篇
  2003年   168篇
  2002年   214篇
  2001年   138篇
  2000年   106篇
  1999年   73篇
  1998年   48篇
  1997年   42篇
  1996年   63篇
  1995年   55篇
  1994年   59篇
  1993年   55篇
  1992年   77篇
  1991年   63篇
  1990年   54篇
  1989年   49篇
  1988年   44篇
  1987年   37篇
  1986年   48篇
  1985年   70篇
  1984年   61篇
  1983年   24篇
  1982年   50篇
  1981年   29篇
  1980年   30篇
  1979年   46篇
  1978年   38篇
  1977年   43篇
  1976年   30篇
  1975年   29篇
  1974年   30篇
  1973年   34篇
排序方式: 共有4188条查询结果,搜索用时 15 毫秒
91.
We study the electrical transport properties of well-contacted ballistic single-walled carbon nanotubes in a three-terminal configuration at low temperatures. We observe signatures of strong electron-electron interactions: the conductance exhibits bias-voltage-dependent amplitudes of quantum interference oscillation, and both the current noise and Fano factor manifest bias-voltage-dependent power-law scalings. We analyze our data within the Tomonaga-Luttinger liquid model using the nonequilibrium Keldysh formalism and find qualitative and quantitative agreement between experiment and theory.  相似文献   
92.
Interest in the heavy fermion metals has motivated us to examine the quantum phases and their Fermi surfaces within the Kondo lattice model. We demonstrate that the model is soluble asymptotically exactly in any dimension d>1, when the Kondo coupling is small compared with the RKKY interaction and in the presence of antiferromagnetic ordering. We show that the Kondo coupling is exactly marginal in the renormalization group sense, establishing the stability of an ordered phase with a small Fermi surface AFS. Our results have implications for the global phase diagram of the heavy fermion metals, suggesting a Lifshitz transition inside the antiferromagnetic region and providing a new perspective for a Kondo-destroying antiferromagnetic quantum critical point.  相似文献   
93.
The kinetics of carbamate formation from the reaction of carbon dioxide with α‐amino acids in D2O was first investigated by means of nuclear magnetic resonance spectroscopy. Potassium carbonate was used as the CO2 source. For each amino acid, the maximum carbamate yield, the apparent rate constant for the carbamate formation kapp, and the rate constants for the formation k1 and the breakdown k?1 of the carbamate were estimated. Plots of log k1 or log k?1 versus pKa of amino acids indicated that the formation rate k1 increased with the basicity (pKa) of amino acid, while the decomposition rate k?1 decreased. A Br?nsted β value of 0.39 was obtained from the former plot, being in good agreement with the previously reported ones (0.26–0.43). The observed negative pKa dependence of log k?1 (Br?nsted α = 0.34) is reasonable, because the carbamate decomposition is acid‐catalyzed and the steady‐state concentration of H+ should be higher for weaker basic amines. The charge (σ) and the lone‐pair energy (EN) at the nitrogen atom of the amino group were calculated. Although log k1 correlated with σ and EN, log k?1 was unrelated with both of these parameters. Considering that the carbamate formation (k1) is not only base‐catalyzed but should also be promoted by the nucleophilicity of the amino nitrogen, its correlation with σ and EN in addition to pKa is rational. The irrelevance of log k?1 to σ and EN is not surprising, because σ and EN are not a direct measure of [H+] of the solution. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
94.
Optical Review - To quantify the changes in optical properties of in vivo rat liver tissue, we applied diffuse reflectance spectroscopy (DRS) system using single-reflectance fiber probe during...  相似文献   
95.
Propagation of a light pulse through a high-Q optical microcavity containing a few cold atoms (N<10) in its cavity mode is investigated experimentally. With less than ten cold rubidium atoms launched into an optical microcavity, up to 170 ns propagation lead time ("superluminal"), and 440 ns propagation delay time (subluminal) are observed. Comparison of the experimental data with numerical simulations as well as future experiments are discussed.  相似文献   
96.
Electronic states of P donors in Si nanocrystals (nc-Si) embedded in insulating glass matrices have been studied by electron spin resonance. Doping of P donors into nc-Si was demonstrated by the observation of optical absorption in the infrared region due to intraconduction band transitions. P hyperfine structure (hfs) was successfully observed at low temperatures. The observed splitting of the hfs was found to be much larger than that of the bulk Si:P and depended strongly on the size of nc-Si. The observed strong size dependence indicates that the enhancement of the hyperfine splitting is caused by the quantum confinement of P donors in nc-Si.  相似文献   
97.
The magnetic structure of the localized-5f uranium intermetallic compound U3Pd20Si6 has been determined by means of a neutron diffraction experiment. Our data demonstrate that this compound has a collinear coupling of the sublattice ordering of the uranium spins on the 4a and 8c sites. We conclude that higher-order exchange and/or quadrupole interactions are necessary to stabilize this unique collinear structure. We discovered a new type of spin-flop transition against the uniaxial anisotropy induced by this collinear coupling.  相似文献   
98.
We have investigated the structure of Co2MnSi/MgO/Co2MnSi magnetic tunneling junctions with different tunnel magnetoresistance values depending on the in situ annealing temperatures just after the deposition of the upper Co2MnSi electrodes. The nano-beam diffraction patterns indicated that the degree of order of the upper Co2MnSi electrode annealed at 550 °C was higher than that of an electrode annealed at 400 °C. Moreover, the degree of the L21 order of the upper Co2MnSi electrode annealed at 550 °C was even lower than that of the lower Co2MnSi electrode annealed at an almost equal temperature of 600 °C. Atomic-scale observation using a high-angle annular dark-field (HAADF) method distinctly showed the existence of the L21-ordered regions in the B2-ordered matrix in the upper Co2MnSi electrode annealed at 400 °C.  相似文献   
99.
100.
The effect of the ratio of fluctuation field (Hf) to coercivity (Hc) on the temperature coefficient of coercivity [α(Hc)] was investigated for Co55Cr15.5Pt28B1.5/Co63Cr37/Cr, Co69Cr19Pt9Ta3/Cr, and Co86Cr10Ta4/Cr thin films (longitudinal recording media) with very small average grain volume (Vphy). α(Hc) increases markedly with increase in temperature between near 250 and 350 K for Co55Cr15.5Pt28B1.5/Co63Cr37/Cr thin films. α(Hc) is approximately proportional to the ratio Hf/Hc for all thin films, as in the case of advanced data backup tapes prepared from ultrafine particles. α(Hc) and the ratio Hf/Hc increase as Vphy decreases. Smaller Hf/Hc values are necessary for small α(Hc) values, which is very important for the thermal stability of high-density recording media with very small Vphy.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号