全文获取类型
收费全文 | 4076篇 |
免费 | 98篇 |
国内免费 | 14篇 |
专业分类
化学 | 3051篇 |
晶体学 | 30篇 |
力学 | 69篇 |
数学 | 166篇 |
物理学 | 872篇 |
出版年
2022年 | 30篇 |
2021年 | 37篇 |
2020年 | 39篇 |
2019年 | 49篇 |
2018年 | 31篇 |
2017年 | 34篇 |
2016年 | 63篇 |
2015年 | 79篇 |
2014年 | 73篇 |
2013年 | 189篇 |
2012年 | 169篇 |
2011年 | 184篇 |
2010年 | 97篇 |
2009年 | 97篇 |
2008年 | 181篇 |
2007年 | 175篇 |
2006年 | 208篇 |
2005年 | 225篇 |
2004年 | 208篇 |
2003年 | 168篇 |
2002年 | 214篇 |
2001年 | 138篇 |
2000年 | 106篇 |
1999年 | 73篇 |
1998年 | 48篇 |
1997年 | 42篇 |
1996年 | 63篇 |
1995年 | 55篇 |
1994年 | 59篇 |
1993年 | 55篇 |
1992年 | 77篇 |
1991年 | 63篇 |
1990年 | 54篇 |
1989年 | 49篇 |
1988年 | 44篇 |
1987年 | 37篇 |
1986年 | 48篇 |
1985年 | 70篇 |
1984年 | 61篇 |
1983年 | 24篇 |
1982年 | 50篇 |
1981年 | 29篇 |
1980年 | 30篇 |
1979年 | 46篇 |
1978年 | 38篇 |
1977年 | 43篇 |
1976年 | 30篇 |
1975年 | 29篇 |
1974年 | 30篇 |
1973年 | 34篇 |
排序方式: 共有4188条查询结果,搜索用时 15 毫秒
91.
We study the electrical transport properties of well-contacted ballistic single-walled carbon nanotubes in a three-terminal configuration at low temperatures. We observe signatures of strong electron-electron interactions: the conductance exhibits bias-voltage-dependent amplitudes of quantum interference oscillation, and both the current noise and Fano factor manifest bias-voltage-dependent power-law scalings. We analyze our data within the Tomonaga-Luttinger liquid model using the nonequilibrium Keldysh formalism and find qualitative and quantitative agreement between experiment and theory. 相似文献
92.
Interest in the heavy fermion metals has motivated us to examine the quantum phases and their Fermi surfaces within the Kondo lattice model. We demonstrate that the model is soluble asymptotically exactly in any dimension d>1, when the Kondo coupling is small compared with the RKKY interaction and in the presence of antiferromagnetic ordering. We show that the Kondo coupling is exactly marginal in the renormalization group sense, establishing the stability of an ordered phase with a small Fermi surface AFS. Our results have implications for the global phase diagram of the heavy fermion metals, suggesting a Lifshitz transition inside the antiferromagnetic region and providing a new perspective for a Kondo-destroying antiferromagnetic quantum critical point. 相似文献
93.
Yuki Yamamoto Jun‐ya Hasegawa Yoshikatsu Ito 《Journal of Physical Organic Chemistry》2012,25(3):239-247
The kinetics of carbamate formation from the reaction of carbon dioxide with α‐amino acids in D2O was first investigated by means of nuclear magnetic resonance spectroscopy. Potassium carbonate was used as the CO2 source. For each amino acid, the maximum carbamate yield, the apparent rate constant for the carbamate formation kapp, and the rate constants for the formation k1 and the breakdown k?1 of the carbamate were estimated. Plots of log k1 or log k?1 versus pKa of amino acids indicated that the formation rate k1 increased with the basicity (pKa) of amino acid, while the decomposition rate k?1 decreased. A Br?nsted β value of 0.39 was obtained from the former plot, being in good agreement with the previously reported ones (0.26–0.43). The observed negative pKa dependence of log k?1 (Br?nsted α = 0.34) is reasonable, because the carbamate decomposition is acid‐catalyzed and the steady‐state concentration of H+ should be higher for weaker basic amines. The charge (σ) and the lone‐pair energy (EN) at the nitrogen atom of the amino group were calculated. Although log k1 correlated with σ and EN, log k?1 was unrelated with both of these parameters. Considering that the carbamate formation (k1) is not only base‐catalyzed but should also be promoted by the nucleophilicity of the amino nitrogen, its correlation with σ and EN in addition to pKa is rational. The irrelevance of log k?1 to σ and EN is not surprising, because σ and EN are not a direct measure of [H+] of the solution. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
94.
Akter Sharmin Tanabe Tomoki Maejima Satoshi Kawauchi Satoko Sato Shunichi Hinoki Akinari Aosasa Suefumi Yamamoto Junji Nishidate Izumi 《Optical Review》2016,23(2):354-359
Optical Review - To quantify the changes in optical properties of in vivo rat liver tissue, we applied diffuse reflectance spectroscopy (DRS) system using single-reflectance fiber probe during... 相似文献
95.
Shimizu Y Shiokawa N Yamamoto N Kozuma M Kuga T Deng L Hagley EW 《Physical review letters》2002,89(23):233001
Propagation of a light pulse through a high-Q optical microcavity containing a few cold atoms (N<10) in its cavity mode is investigated experimentally. With less than ten cold rubidium atoms launched into an optical microcavity, up to 170 ns propagation lead time ("superluminal"), and 440 ns propagation delay time (subluminal) are observed. Comparison of the experimental data with numerical simulations as well as future experiments are discussed. 相似文献
96.
Electronic states of P donors in Si nanocrystals (nc-Si) embedded in insulating glass matrices have been studied by electron spin resonance. Doping of P donors into nc-Si was demonstrated by the observation of optical absorption in the infrared region due to intraconduction band transitions. P hyperfine structure (hfs) was successfully observed at low temperatures. The observed splitting of the hfs was found to be much larger than that of the bulk Si:P and depended strongly on the size of nc-Si. The observed strong size dependence indicates that the enhancement of the hyperfine splitting is caused by the quantum confinement of P donors in nc-Si. 相似文献
97.
Koike Y Metoki N Haga Y McEwen KA Kohgi M Yamamoto R Aso N Tateiwa N Komatsubara T Kimura N Aoki H 《Physical review letters》2002,89(7):077202
The magnetic structure of the localized-5f uranium intermetallic compound U3Pd20Si6 has been determined by means of a neutron diffraction experiment. Our data demonstrate that this compound has a collinear coupling of the sublattice ordering of the uranium spins on the 4a and 8c sites. We conclude that higher-order exchange and/or quadrupole interactions are necessary to stabilize this unique collinear structure. We discovered a new type of spin-flop transition against the uniaxial anisotropy induced by this collinear coupling. 相似文献
98.
T.M. Nakatani Y.K. Takahashi M. Yamamoto 《Journal of magnetism and magnetic materials》2010,322(3):357-361
We have investigated the structure of Co2MnSi/MgO/Co2MnSi magnetic tunneling junctions with different tunnel magnetoresistance values depending on the in situ annealing temperatures just after the deposition of the upper Co2MnSi electrodes. The nano-beam diffraction patterns indicated that the degree of order of the upper Co2MnSi electrode annealed at 550 °C was higher than that of an electrode annealed at 400 °C. Moreover, the degree of the L21 order of the upper Co2MnSi electrode annealed at 550 °C was even lower than that of the lower Co2MnSi electrode annealed at an almost equal temperature of 600 °C. Atomic-scale observation using a high-angle annular dark-field (HAADF) method distinctly showed the existence of the L21-ordered regions in the B2-ordered matrix in the upper Co2MnSi electrode annealed at 400 °C. 相似文献
99.
100.
The effect of the ratio of fluctuation field (Hf) to coercivity (Hc) on the temperature coefficient of coercivity [α(Hc)] was investigated for Co55Cr15.5Pt28B1.5/Co63Cr37/Cr, Co69Cr19Pt9Ta3/Cr, and Co86Cr10Ta4/Cr thin films (longitudinal recording media) with very small average grain volume (Vphy). α(Hc) increases markedly with increase in temperature between near 250 and 350 K for Co55Cr15.5Pt28B1.5/Co63Cr37/Cr thin films. α(Hc) is approximately proportional to the ratio Hf/Hc for all thin films, as in the case of advanced data backup tapes prepared from ultrafine particles. α(Hc) and the ratio Hf/Hc increase as Vphy decreases. Smaller Hf/Hc values are necessary for small α(Hc) values, which is very important for the thermal stability of high-density recording media with very small Vphy. 相似文献