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61.
In this paper the problems of unique solvability of boundary value problems for infinite functional differential systems and positivity of their solutions are reduced to analysis of scalar functional equations in the space of measurable essentially bounded functions y:[0,+∞)→(−∞,+∞). Efficient tests of the solvability and the positivity are obtained. 相似文献
62.
63.
We study in this paper the remnants of the contact partial order on the orbits of the adjoint action of contactomorphism groups on their Lie algebras. Our main interest is a class of noncompact contact manifolds, called convex at infinity. 相似文献
64.
Vladimir M. Feygelman Yakov R. Tymyanskii Nadezhda I. Makarova Michail I. Knyazhanskii Sergei I. Druzhinin Boris M. Uzhinov 《Journal of Physical Organic Chemistry》1990,3(3):200-204
The photophysics and photochemistry of N-amino-substituted pyridinium salts were investigated. Electron transfer from the amino group to the pyridinium ring takes place in the singlet excited state. The fluorescence quenching and photoreactivity of these compounds is conditioned by this process. Irradiation of N-aminopyridinium salts in solution leads to novel fused heterocycles or to triphenylpyridine, depending on the concentration of the initial compound. Free radical intermediates are involved in the photoreaction. 相似文献
65.
The problem of derivation of the equations of motion from the field equations is considered. Einstein's field equations have a specific analytical form: They are linear in the second order derivatives and quadratic in the first order derivatives of the field variables. We utilize this particular form and propose a novel algorithm for the derivation of the equations of motion from the field equations. It is based on the condition of the balance between the singular terms of the field equation. We apply the algorithm to a non‐linear Lorentz invariant scalar field model. We show that it results in the Newton law of attraction between the singularities of the field moved on approximately geodesic curves. The algorithm is applicable to the N‐body problem of the Lorentz invariant field equations. 相似文献
66.
This paper reviews the application of a modification of the polarographic Brdi?ka method for cancer testing. The modification comprises the catalytic electroreduction of metal ions (here called Brdi?ka method based on catalytic metal ion reduction for cancer testing—BMMCT) and/or the electrooxidation of proteins, instead of the classical approach based on the catalytic electroreduction of protons, i.e., hydrogen waves (here called Brdi?ka method based on catalytic hydrogen evolution for cancer testing—BMHCT). Further, in the modified method, the mercury electrode has been replaced by a nontoxic solid electrode and the entire measuring system has been automated. The modified method excels in improved testing rates and sensitivity of cancer testing. The cancer testing of vaginal secretions is characterized by high specificity as well. 相似文献
67.
This study describes a novel approach to separate three soil carbon (C) sources by one tracer method (here 13C natural abundance). The approach is based on the combination of C3 and C4 sources in different treatments, identical decomposition of C3 and C4 substances in soil, and subsequent calculation of their contribution to the total CO2 efflux. We used the temporal dynamics of the CO2 efflux from a C3 grassland soil amended with added C3 or C4 slurry and/or C3 or C4 sugar to estimate contributions of three separate C sources: native soil organic matter (SOM), slurry and sugar, to CO2 efflux. Soil with slurry and/or sugar was incubated under controlled conditions, and concentration and delta13C values of evolved CO2 were measured over a 2-week period. The main assumption needed for separation of three C sources in CO2 efflux, i.e. identical decomposition of applied C3 and C4 sugars in soil, was investigated and proven. The relative contribution to the CO2 efflux increased, but its duration decreased with an increased microbial availability of the C source, i.e. sugar > slurry > SOM. The microorganisms used the C sources according to their availability. The contribution of sugar to the CO2 efflux was finished after 2-4 days. Separation of three CO2 sources and comparison of CO2 from different treatments tracing the changes of SOM and slurry decomposition induced by addition of sugar were investigated. During the sugar decomposition (the first 2-4 days), the SOM decomposition strongly decreased. At the same time the contribution of slurry-C to CO2 increased. The shortcomings and limitations as well as possible future applications of the suggested method including FACE (Free Air Carbon dioxide Enrichments) and continuous labelling experiments are discussed. 相似文献
68.
Anton A. Ulantikov Konstantin A. Brylev Taisiya S. Sukhikh Yuri V. Mironov Viktoria K. Muravieva Yakov M. Gayfulin 《Molecules (Basel, Switzerland)》2022,27(22)
A series of eight new octahedral rhenium cluster complexes with the general formula trans-[{Re6Q8}L4X2] (Q = S or Se; L = 1,2-Bis(4-pyridyl)ethylene (bpe) or 1,3-Bis(4-pyridyl)propane (bpp); X = Cl or Br) was synthesized and investigated. While bpe is a ligand with a conjugated aromatic system, bpp represents a molecule of opposite type and has independent aromatic systems of the two pyridine rings. It was shown that this difference in the electronic structure of the ligands has a fundamental effect on the electronic structure, electrochemical and luminescent properties of the corresponding cluster complexes. Specifically, the [{Re6Q8}(bpe)4X2] complexes in solutions show multiple quasi-reversible electrochemical transitions associated with reduction of the organic ligands. At the same time, the trans-[{Re6Q8}(bpp)4X2] complexes show multielectron quasi-irreversible reduction processes, which correlate with the mixed character of the lowest unoccupied molecular orbitals of these complexes. All the obtained new compounds exhibit red photoluminescence. The photophysical parameters (emission lifetimes and quantum yields) measured for the bpp complexes exceed those revealed for bpe complexes by more than an order of magnitude. 相似文献
69.
Simon Yakov Serovajsky 《Journal of Applied Analysis & Computation》2013,3(2):183-195
An optimization control problem for a hyperbolic equation is considered. The system is nonlinear with respect to the state derivative. The regularization technique for the state equation is applied. The necessary conditions of optimality for the regularized control problem are proved. It uses the extended differentiability of the control-state mapping for the regularized equation. The convergence of the regularization method is proved. Thus the optimal control for the regularized problem with a small enough regularization parameter can be chosen as an approximate solution of the initial optimization problem. 相似文献
70.