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131.
分别通过浸渍法和共沉淀法制备了不同Ni负载量的Ni/Al2O3催化剂。考察了Ni负载量、制备方法以及反应温度对Ni/Al2O3催化甲烷裂解性能的影响。结果表明,在550℃,浸渍法制备的Ni/Al2O3催化剂,当Ni负载量为20%(质量分数)、Ni金属平均粒径为11.25 nm时,具有最佳的甲烷催化裂解效果,其每摩尔Ni的氢气产量和每克Ni碳产量分别为164 mol和15.30 g。催化剂制备方法对Ni/Al2O3甲烷催化裂解反应有显著影响,相同Ni负载量共沉淀法制备的Ni/Al2O3甲烷催化裂解总体效果要好于浸渍法制备的Ni/Al2O3,而且反应过程中生成的碳纤维较长,管径也较均一。550℃时,共沉淀法制备的Ni负载量为41.2%(质量分数)的Ni/Al2O3催化剂在反应至350 min时,仍保持着30%以上的转化率。 相似文献
132.
Gladysheva M. V. Plyusnin P. E. Komarov V. Yu. Tsygankova A. R. Gerasimov E. Yu. Shubin Yu. V. Korenev S. V. 《Journal of Structural Chemistry》2022,63(4):556-568
Journal of Structural Chemistry - New complex salts [Pd(NH3)4][Pd(NH3)3NO2][CrOx3]·H2O I, [Pd(NH3)4][Pd(NH3)3NO2][CoOx3]·H2O II, and a series of solid solutions... 相似文献
133.
燃烧法合成铝酸盐发光粉的研究 总被引:25,自引:0,他引:25
利用金属硝酸盐和尿素发生的氧化还原反应,制备了发绿光的铝酸盐发光粉Ce0.67Tb0.33MgAl12O20.5.反应在600℃下完成.对产物的性质进行了表征和研究.考察了尿素用量,炉温及其它制备条件对发光粉的性质,特别是亮度的影响 相似文献
134.
135.
In this article, we investigate the Cauchy problem for the generalized double dispersion equation in n-dimensional space. We establish the decay estimates of solution to the corresponding linear equation. Under smallness condition on the initial data, we prove the global existence and asymptotic behaviour of the small amplitude solution in the time-weighted Sobolev space by the contraction mapping principle. 相似文献
136.
D. V. Pinakov V. A. Logvinenko Yu. V. Shubin G. N. Chekhova 《Journal of Thermal Analysis and Calorimetry》2010,100(1):163-169
Inclusion compounds (intercalates) of fluorinated graphite matrix with methylene dichloride (C2F
x
Br
z
·yCH2Cl2, x = 0.49, 0.69, 0.87, 0.92, z ≈ 0.01) were synthesized by guest substitution from acetonitrile to methylene dichloride. The kinetics of the thermal decomposition
(the first stage of filling → the second stage of filling) was studied under isothermal conditions at 291–303 K. The relationship
between the structure of host matrices with thermal properties and kinetic parameters of inclusion compounds is discussed. 相似文献
137.
Surface structures and electronic properties of hypophosphite, H2PO2−, molecularly adsorbed on Ni(1 1 1) and Cu(1 1 1) surfaces are investigated in this work by density functional theory at B3LYP/6-31++g(d, p) level. We employ a four-metal-atom cluster as the simplified model for the surface and have fully optimized the geometry and orientation of H2PO2− on the metal cluster. Six stable orientations have been discovered on both Ni (1 1 1) and Cu (1 1 1) surfaces. The most stable orientation of H2PO2− was found to have its two oxygen atoms interact the surface with two PO bonds pointing downward. Results of the Mulliken population analysis showed that the back donation from 3d orbitals of the transition metal substrate to the unfilled 3d orbital of the phosphorus atom in H2PO2− and 4s orbital's acceptance of electron donation from one lone pair of the oxygen atom in H2PO2− play very important roles in the H2PO2− adsorption on the transition metals. The averaged electron configuration of Ni in Ni4 cluster is 4s0.634p0.023d9.35 and that of Cu in Cu4 cluster is 4s1.004p0.033d9.97. Because of this subtle difference of electron configuration, the adsorption energy is larger on the Ni surface than on the Cu surface. The amount of charge transfers due to above two donations is larger from H2PO2− to the Ni surface than to the Cu surface, leading to a more positively charged P atom in NinH2PO2− than in CunH2PO2−. These results indicate that the phosphorus atom in NinH2PO2− complex is easier to be attacked by a nucleophile such as OH− and subsequent oxidation of H2PO2− can take place more favorably on Ni substrate than on Cu substrate. 相似文献
138.
Mathematical Notes - Let $$\alpha > 0$$ be any fixed noninteger. In the paper, we prove an analogue of the Bombieri–Vinogradov theorem for the set of primes $$p$$ satisfying the... 相似文献
139.
Doklady Mathematics - Let 0 < α, σ < 1 be arbitrary fixed constants, let $${{q}_{1}} < {{q}_{2}} < \ldots < {{q}_{n}} < {{q}_{{n + 1}}}$$... 相似文献
140.
A. B. Shubin K. Yu. Shunyaev 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2010,84(12):2011-2016
The fundamental characteristics of the reduction of scandium trifluoride and trichloride with aluminum were studied by thermodynamic
modeling over wide temperature and pressure ranges (1100–1400 K and 1–106 Pa for ScF3 and 800–1200 K and 1–105 Pa for ScCl3). Calculations of the equilibrium compositions of the systems were performed to draw conclusions about the contents of condensed
and gaseous components and determine the temperatures of the complete reduction of trihalides with the formation of a two-phase
alloy containing a saturated solution of scandium in aluminum and the Al3Sc intermetallic compound. The results of modeling were in agreement with the available experimental data. 相似文献