交联壳聚糖树脂吸附Co2+的机理研究

研究了甲醛、环氧氯丙烷交联壳聚糖 (AECTS) 对Co2 的吸附热力学行为,用FTIR、WXRD对吸附产物进行了结构表征,并研究了溶液中介质种类的不同对Co2 吸附量的影响.结果表明:AECTS主要以配位吸附和物理吸附形式吸附Co2 ;树脂与Co2 配位后,结晶度下降;AECTS对Co2 的吸附行为同时符合Freundlich模型和Langmuir模型;吸附为自发的、放热的熵减小过程;不同介质对树脂吸附Co2 的影响大小顺序为HCl>CdCl2>MgCl2>NaCl,前两者使吸附量减小,后两者使吸附量增加,作用机理相差较大.     

RTCM算法在一维光子晶体缺陷模中的应用

利用RTCM算法研究一维光子晶体的缺陷模.研究了TE波和TM波入射时的情况,通过改变杂质层的光学厚度以及杂质层的折射率从而得出一些有重要指导意义的缺陷模特性.同时对有缺陷的一维光子晶体在窄带滤波器中的应用做了一定程度的探讨.结果表明:正入射时,TE波和TM波的透射率几乎相同,随着杂质层光学厚度的增加,透射峰数目增加,这有助于制作多道窄带滤波器.因此,有缺陷的一维光子晶体可以制作波分复用中的多道滤波器.     

代数数的有理和代数逼近及应用

用Thue-Siegel方法给出了一大类代数数的有效有理和代数逼近.作为应用,证明了:若D>0非平方数,x²-Dy²=-1的基本解ε=x0+y0√D(2/1),则x²+1=Dy⁴可解的充要条件是y0=A²,A为整数,且当ε>64时,x²+1=Dy⁴最多只有一组正整数解(x,y).     

Dumb-bell Structures of Nonstoichiometric La（Ni, Sn）5＋x Alloys and Their Relationships with the Preparation Methods

Crystal structures of nonstoichiometric La(Ni, Sn)5 x (x = 0.1～0.4) alloysprepared by different methods were investigated by using powder X-ray diffraction and Rietveldrefinement analysis. Space group of this type of alloys belongs to P6/mmm, in which Sn onlyoccupies the 3g sites. It has been demonstrated that some of the la sites of the nonstoichiometricalloy are replaced by the Ni-Ni dumb-bells which have a strong correlation with the anisotropicthermal parameter B33. The preparation methods have an effect on the number of dumb-bells thatcan substitute the l a sites. It was found that the annealed alloys have more Ni-Ni dumb-bells inthe structure than the rapid solidified and as-cast alloys have while still keep good crystallinity.     

透明质酸纳米材料在荧光/光声成像和光疗中的应用

荧光/光声成像和光疗技术的生物医学应用引起了人们越来越多的关注, 然而很多荧光/光声造影剂存在生物相容性较差, 缺乏肿瘤靶向性, 信噪比较低, 功能单一等共性问题, 严重限制其诊疗应用. 透明质酸具有优异的生物相容性和主动肿瘤靶向性, 可被透明质酸酶降解, 并且易于化学修饰和实现多种超分子弱相互作用力协同工作. 因此, 人们将透明质酸与荧光/光声造影剂结合制备纳米材料, 使其在细胞乃至活体的标记性能和治疗效果获得了很大的改善. 本文综述了将两类物质结合制备纳米材料的方法, 着重阐述了纳米材料的结构与性能关系, 为其未来设计和开发提供了指导, 最后对存在的主要问题以及未来的重要研究方向进行了分析和展望.     

溶胶凝胶法合成莫来石纳米带

Single-crystal mullite nanobelts were prepared by a simple sol-gel method using WO₃ as additive, and nanobelts were straight and uniform with width of 200 nm and length of 3~4 μm. The as-prepared products were characterized with XRD, SEM and TEM and the nanobelt formation mechanism was also discussed. The interphase of aluminium tungstate acted as seed crystals or epitaxial templates during the formation of nanobelts. The further experiments showed that there was a strong correlation between the formation of nanobelts and the presence of WO₃.     

Application of Bipartite and Tripartite Entangled State Representations in Quantum Teleportation of Continuous Variables

We mostly investigate two schemes. One is to teleport a multi-mode W-type entangled coherent state using a peculiar bipartite entangled state as the quantum channel different from other proposals. Based on our formalism,teleporting multi-mode coherent state or squeezed state is also possible. Another is that the tripartite entangled state is used as the quantum channel of controlled teleportation of an arbitrary and unknown continuous variable in the case of three participators.     

基于漂移布朗运动的光纤陀螺加速贮存寿命评估

众多"长期贮存,一次使用"的军事应用需求决定了光纤陀螺的贮存寿命指标的重要性,为此针对在贮存期内具有长寿命、高可靠性特点的光纤陀螺,实施加速贮存退化试验,并采用基于漂移布朗运动的方法,对光纤陀螺的贮存寿命与可靠性进行评估.依据光纤陀螺的贮存故障模式影响及危害性分析结果,确定了加速模型,并结合线性漂移布朗运动的特点,建立了光纤陀螺可靠性评估模型.利用加速贮存退化试验的试验数据对光纤陀螺贮存寿命进行评估,得到了评估结果,从而验证了方法的适用性.     

一种新型高功率微波相移器

 研究了一种新型高功率微波相移器同轴插板式相移器,其设计思想为：在同轴波导内插入金属导体板,将同轴波导分为几个扇形截面波导,由于扇形截面波导中传输的TE₁₁模相速度与同轴TEM模的相速度不同,通过改变插入金属板的长度就可以实现相移的调节。设计了中心频率为4 GHz的同轴插板式相移器,并进行了数值模拟验证。结果表明：当相移器同轴波导内半径为2.0 cm,外半径为4.5 cm,相移器总长度为50 cm时,可实现的最大相移量为360°,在3.9~4.1 GHz频率范围内相移器的插入损耗低于0.1 dB。     

激光辐照下静止及旋转充压柱壳结构变形的对比分析

 采用3维实体单元模拟激光辐照下静止及旋转充压柱壳的应力和应变分布,分析了柱壳可能发生破坏的位置和条件。通过对计算结果的分析表明,对于激光辐照下静止及旋转充压柱壳,裂纹都有可能在光斑边缘附近产生。但由于在旋转充压柱壳上,在过光斑中心圆周上有高应力带状区域,因此旋转柱壳有可能在这一环带区域也发生破坏。在相同的激光加载条件下,静止充压柱壳更容易在局部区域开始发生破坏。