3-(3''''-羟基丁基)异苯并呋喃-1(3H)-酮的合成

由邻苯二甲酸酐为原料 ,经中间体 3 羟基苯酞 (3 ) ,再经溴丙烯及锡存在下 3的烯丙基化、硼氢化氧化、铬酐氧化、二甲基锌甲基化 ,共 6步反应合成了 3 (3’ 羟基丁基 )异苯并呋喃 1(3H) 酮。     

Accurate studies on the full vibrational energy spectra and molecular dissociation energies for some electronic states of N_2 molecule

1 IntroductionAccurate results of high-lying vibrational energies and molecular dissociation energy De of diatomic electronic states are very important for thermodynamics, molecular spec- troscopy, reactive scatterings, and the collision physics of ultracold atoms. For example, the binding energy of the highest bound vibrational state to the ground vibrational state determines the s-wave scattering length. This in turn determines the low- energy (pre- dominantly s-wave) atomic elastic-scatteri…     

Critical Slowing Down in One-Dimensional Maps and Beyond

This is a brief review on critical slowing down near the Feigenbaum period-doubling bifurcation points and its consequences. The slowing down of numerical convergence leads to an “operational” fractal dimension D=2/3 at a finite order bifurcation point. There is a cross-over to D ₀=0.538... when the order goes to infinity, i.e., to the Feigenbaum accumulation point. The problem of whether there exists a “super-scaling” for the dimension spectrum D _q ^W that does not depend on the primitive word W underlying the period-n-tupling sequence seems to remain open     

第九讲光速减慢和光缓存技术

高速光信号的存储是光信息科学的重要分支,全光缓存器是当今高速光信号处理的瓶颈.本文介绍了全光缓存器的研究进展,着重介绍了光速减慢的原理、物理基础, 以及在半导体量子点中利用电磁诱导透明效应发展全光缓存器的思路.     

孪生子佯谬

本文从一个新的角度来阐释孪生子佯谬的症结所在，详细分析了由于双胞胎兄弟所在参考系的不对称性导致的荒谬结论，并在两个惯性系下分别做了计算，最后的结论是相同的，并不存在矛盾，同时印证了所有的惯性系是平权的这一大前提!     

Synthesis of a novel tripodand having 3-hydroxy-2-naphthoeic amide groups and its anion recognition ability

A novel tripodand having 3-hydroxy-2-naphthoeic amide groups was prepared by the reaction of 1,3,5-tris(aminomethyl)-2,4,6-trimethylbenzene with 3-allyloxy-2-naphthoeic acid chloride followed by thermal Claisen rearrangement. This tripodand can exhibit the anion binding ability in chloroform solution. In particular, it can bind with acetate, dihydrogen phosphate, and fluoride ions to form 1:1 complexes.     

过冷沸腾非均相汽泡界面特性分析

本文针对过冷沸腾中汽泡顶部射流现象进行分析与模拟。建立汽泡界面模型,考虑蒸发凝结以及Marangoni效应。利用CFD软件Fluent6.0对模型进行计算分析,成功模拟得到泡顶射流流场。模拟结果无论是流场结构,还是流场强度,都与实验一致吻合,充分证明泡顶射流由Marangoni效应引起。