七(2,3-二-O-乙酰基-6-O-叔丁基二甲基硅烷基)-β-环糊精毛细管色谱柱的研制及色谱性能

合成了七（2,3-二-O-乙酰基-6-O-叔丁基二甲基硅烷基）-β-环糊精,并采用静态法成功地将其涂渍到弹性石英毛细管柱上。研究了其气相色谱分离性能,发现此固定相涂渍性好,柱效较高,热稳定性好,对卤代芳烃异构体以及难分离的二取代苯的位置异构体具有良好的分离能力。     

聚氯乙烯膜碘离子选择电极在溴碘离子共存体系分析中的应用

介绍了聚氯乙烯膜碘离子选择电极(PVC-I-ISE)的制备方法,电极对碘离子的能斯特响应斜率为59 mV/pI,响应的线性范围为4.0×10-5~1.0×10-2mol.L-1,检出限为1.6×10-5mol.L-1,低于用银ISE的检出限,电极的使用寿命为一个月以上。将制备的碘离子选择电极作为指示电极用于对溴、碘混合离子体系进行连续分别电位滴定,并与以银电极为指示电极的电位滴定方法进行了比较。结果表明用PVC-I--ISE作指示电极,可在I--Br-共存的混合溶液中进行两离子的连续电位滴定,而用银-ISE时则不能。     

Self-organized Criticality in an Earthquake Model on Random Network

A simplified Olami-Feder-Christensen model on a random network has been studied. We propose a new toppling rule — when there is an unstable site toppling, the energy of the site is redistributed to its nearest neighbors randomly not averagely. The simulation results indicate that the model displays self-organized criticality when the system is conservative, and the avalanche size probability distribution of the system obeys finite size scaling. When the system is nonconservative, the model does not display scaling behavior. Simulation results of our model with different nearest neighbors q is also compared, which indicates that the spatial topology does not alter the critical behavior of the system.     

New Matrix Lie Algebra, a Powerful Tool for Constructing Multi-component C-KdV Equation Hierarchy

A set of new multi-component matrix Lie algebra is constructed, which is devoted to obtaining a new loop algebra A-2M. It follows that an isospectral problem is established. By making use of Tu scheme, a Liouville integrable multi-component hierarchy of soliton equations is generated, which possesses the multi-component Hamiltonian structures. As its reduction cases, the multi-component C-KdV hierarchy is given. Finally, the multi-component integrable coupling system of C-KdV hierarchy is presented through enlarging matrix spectral problem.     

Scheme for Quantum Entanglement Swapping on Cavity QED System

We propose a scheme for realizing quantum entanglement swapping between the atoms in cavity QED. With only virtual excitation of the cavity during the interaction between the atoms and cavity, the scheme is insensitive to the cavity mode states and the cavity decay. The ideas can also be utilized for realizing entanglement swapping between the atomic levels in a single atom and the atomic levels in the Bell states and between the atomic levels in the Bell states and the atomic levels in the W states.     

Quantum Inequality Bounds for Free Rarita-Schwinger Field in Flat Spacetime

Although quantum field theory allows the local energy density negative, it also places severe restrictions on the negative energy. One of the restrictions is the quantum energy inequality (QEI), in which the energy density is averaged over time, or space, or over space and time. By now temporal QEIs have been established for various quantum fields, but less work has been done for the spacetime quantum energy inequality. In this paper we deal with the free Rarita-Schwinger field and present a quantum inequality bound on the energy density averaged over space and time.Comparison with the QEI for the Rarita-Schwinger field shows that the lower bound is the same with the QEI. At the same time, we find the quantum inequality for the Rarita-Schwinger field is weaker than those for the scalar and Dirac fields. This fact gives further support to the conjecture that the more freedom the field has, the more easily the field displays negative energy density and the weaker the quantum inequality becomes.     

一种自适应层进式Savitzky‐Golay光谱滤波算法及其应用

可调谐半导体激光吸收光谱技术（TDLAS）利用半导体激光器的可调谐和窄线宽特性,通过选择特定气体的单条吸收线,排除其余气体的干扰,可以实现高精度、高选择性的气体浓度测量,在气体浓度检测系统中具有广泛的应用前景。在不同的应用条件和环境下,需要解决相应的硬件和数据处理方面的技术问题。主要研究TDLAS技术机动车尾气CO组分浓度遥测系统中的光谱数据处理问题,该系统利用路面漫反射回波信号遥测行驶中的机动车尾气CO组分浓度。由于激光扫描光谱回波信号受到漫反射面情况变化、空气环境变化、尾气湍流影响等因素影响,探测器收集到的信号不仅较弱同时也夹杂着多种噪声, 即测量光路信噪比较差, 故提出一种自适应层进式Savitzky-Golay(S-G)平滑滤波算法,实现了对光谱进行滤波处理从而更加准确地反演CO浓度。S-G滤波算法因其原理简单、功能强大、只需设置两个参数（窗口大小、拟合阶数）等优点,已广泛应用于光谱处理。如何正确设置S-G算法参数使滤波效果在去噪不足和过度滤波之间找到平衡点,是该滤波算法应用的一大难题。设计的检测系统中,测量光路光谱信号为非平稳信号,噪声和有效信号幅度时变,最佳窗口大小和多项式阶数随信号动态而变化,且变化区间较大,使用固定参数的S-G滤波器难以达到最佳效果。提出的自适应层进式S-G平滑滤波算法,通过逐层将测量光路光谱信号经过S-G滤波后,与参考光路的光谱信号设置的参考段比对信号相关系数和信号一阶导相关系数的和,以自适应得到逐层最优参数。通过对信噪比从9.81～29.77的10组不同带噪光谱分析验证了该算法的有效性,自适应层进式S-G算法能较好地去除噪声并还原带噪信号所携带的待测气体浓度信息,与带噪光谱对比,吸收光谱峰值最大误差由25.152%降至5.917%,积分吸光度最大误差由18.1%降至3.9%。在实现的系统中,使用自适应层进式S-G算法对测量光路进行滤波处理,并对不同车型、不同排量、燃烧不同油品的机动车在怠速和缓速通过(5 km·h-1)系统时其排放的CO浓度进行实时在线监测。     

显微红外光谱法研究聚乙烯复合材料光氧化的深度分布

采用显微红外光谱法结合表面形貌分析研究了分别填充碳酸钙、绢英粉、云母、高岭土和硅藻土的高密度聚乙烯(HDPE)的自然光氧化随深度的分布。研究结果表明无机填料对HDPE光氧化的深度分布有很大的影响。填充碳酸钙的HDPE从表面到内部都没有明显氧化发生。而填充绢英粉、云母、高岭土和硅藻土的HDPE从表面到内部羰基指数逐渐减小,氧化深度都在150 μm以上。HDPE复合材料沿深度方向的氧化情况与其断面裂纹的产生情况吻合。结合无机填料的紫外吸收特性讨论了它们对HDPE光氧化的影响机理。     

垂直均匀射流下CPU散热器换热性能的数值分析

对垂直射流下CPU散热器的流场及温度场进行了数值模拟,得到了CPU散热器流场及温度场的分布规律,指出近底面肋片间存在回流区,明显影响传热。分析了CPU散热器在射流时不同情况下的散热性能,计算所得数据有助于CPU散热器的设计与改进。     

高压静电场促进植物生长技术的研究

高压静电场促进植物生长技术源于自然又高于自然 ,它包括静电种子处理和静电场生长环境等技术 .文章论述了该技术的实施方法 ,并报道了已经取得的初步成果 .