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61.
Treatment of several cyclic olefins, β-pinene, allylbenzene, and estragole with palladium(II) salt in acetic acid in the presence of t-butyl hydroperoxide and tellurium(IV) oxide afforded mainly the corresponding allylic acetates. The reaction proceeded catalytically with palladium(II) salt, t-BuOOH working as a reoxidizing agent. 相似文献
62.
The stereoselective total synthesis of (+)-obtusenyne is described. The oxonene skeleton possessing trans-orientated alkyl substituents at the α,α′-positions was stereoselectively constructed via cyclization of the corresponding hydroxy epoxide promoted by Eu(fod)3. 相似文献
63.
64.
We demonstrate 12-fs-pulse generation from a diode-pumped Kerr-lens mode-locked Cr:LiSAF laser. This is to our knowledge the shortest pulse ever produced from a mode-locked Cr:LiSAF laser. Based on an improved estimation of the intracavity dispersions, we utilized BK7 glass for the Brewster-prism-pair material. 相似文献
65.
66.
H. Ohyama E. Simoen C. Claeys K. Takakura H. Matsuoka T. Jono J. Uemura T. Kishikawa 《Physica E: Low-dimensional Systems and Nanostructures》2003,16(3-4):533
Results are presented of a detailed study of the effects of high-temperature 4-MeV neutron irradiation on the performance degradation of Si pin photodiodes together with the radiation-induced defects, observed by deep level transient spectroscopy. The degradation of the device performance and the introduction rate of the lattice defects decrease with increasing sample temperature during irradiation. For a 250°C irradiation, the reduction of the reverse current is only 20% of the starting value. This result suggests that the creation and recovery of the radiation damage proceeds simultaneously at high temperatures. Carbon-related complex as hole capture levels is also mainly responsible for the device degradation for high-temperature neutron irradiation. 相似文献
67.
I. Mirebeau M. Hennion M.J.P. Gingras A. Keren K. Kojima M. Larkin G.M. Luke B. Nachumi W.D. Wu Y.J. Uemura I.A. Campbell G.D. Morris 《Hyperfine Interactions》1997,104(1-4):343-348
In the amorphous ( Fe1-x Mn_x)75 P16 B_6 Al_3 alloys, muon and neutron depolarization data, combined with the results of small angle neutron scattering, magnetization and Mössbauer spectroscopy, probe the existence of three distinct magnetic transitions at TC, TK and TF (TF < K < C). 相似文献
68.
R. F. Kiefl J. H. Brewer I. Affleck J. F. Carolan P. Dosanjh W. N. Hardy T. Hsu R. Kadono J. R. Kempton S. R. Kreitzman Q. Li A. H. O'Reilly T. M. Riseman P. Schleger P. C. E. Stamp H. Zhou L. P. Le G. M. Luke B. Sternlieb Y. J. Uemura H. R. Hart K. W. Lay 《Hyperfine Interactions》1991,63(1-4):139-144
We have searched for anomalous internal magnetic fields in highT
c materials which are predicted to occur in anyon and flux phase models of superconductivity. The magnitude, anisotropy and
temperature dependence of the observed fields inc-axis oriented samples of sintered YBa2CuO3O7 and of thick-film Bi2Sr2CaCu2O8 are consistent with a conventional nuclear dipolar origin. An upper limit of ≲0.08 mT is set for any anomalous magnetic fields
along thec-axis atμ
+ sites in bulk CuO2 superconductors. 相似文献
69.
H. Uemura 《Journal of Theoretical Probability》2004,17(2):347-366
We study the Tanaka formula for multidimensional Brownian motions in the framework of generalized Wiener functionals. More precisely, we show that the submartingale U(B
t
–x) is decomposed in the sence of generalized Wiener functionals into the sum of a martingale and the Brownian local time, U being twice of the kernel of Newtonian potential and B
t
the multidimensional Brownian motion. We also discuss on an aspect of the Tanaka formula for multidimensional Brownian motions as the Doob–Meyer decomposition. 相似文献
70.
Axisymmetrical snap buckling of a clamped shallow spherical shell with initial deformation and subject to uniform pressure is analysed based on the finite-deformation theory. As a refinement to analyses given in the author's previous papers, a variable term in the deformation pattern is introduced and Galerkin's method is applied to the non-linear simultaneous differential equations, so that upper buckling pressures are obtained as a function of the geometrical parameter α. Non-uniqueness of solution is shown in the region of larger values of α, where the higher order of deformation mode takes place. Stability of a number of possible equilibrium states is checked by use of the second variation of total potential energy to clarify the actual buckling process. The remark- able decrease of buckling pressure is reasonably explained by introducing a small initial deflection, which explains the discrepancy between the classical buckling pressure and experimental results. 相似文献