CS2中对苯醌n-π*单-三态跃迁的可见吸收光谱及其共振拉曼光谱

测量了对苯醌(p-benzoquinone,PBQ)在CS2中的可见吸收光谱,论证了该实验中发现的507 nm带来源于PBQ的n-π*单-三态跃迁.基于液芯光纤内共振拉曼散射可以提高拉曼光谱强度109倍这一技术,在10-3～10-6 mol·L-1的浓度范围首次探测到514.5 nm激光激发该跃迁而产生的共振拉曼光谱(1 439cm-1).分析认为该谱线来源于PBQ的n-π*单-三态跃迁的羰基伸缩振动(v c-o).实验发现,随着PBQ溶液浓度的降低,该谱线的拉曼频移发生蓝移.文章的研究结果将有助于理解PBQ电子结构与其光物理特性的相互关系,便于获得更丰富的分子结构信息.     

柔性衬底白色有机电致发光器件的制备及其性能

采用以ITO为导电层的柔性透明PET基片作为衬底,以2-(2-羟基苯基)苯并噻唑螯合锌(Zn(BTZ),)作为发光层制备出结构为PET／ITO／PVK：TPD／Zn(BTZ)2／Al明亮的近白色柔性有机小分子电致发光器件。发光的色坐标值为x=0．242,y=0．359,在25V的直流电压驱动下,亮度为1000cd／m^2,量子效率达到了0．30％。并进一步在Zn(BTZ)2中掺入橙红色染料Rubrene,制成PET／ITO／PVK：TPD／Zn(BTZ)2：Rubrene／Al结构器件。实现了纯白色发光(色坐标值：x=0．339,y=0．339),非常接近于白色等能点,驱动电压为25V时器件的亮度达1200cd／m^2,且量子效率达0．35％。最后对器件的发光性能及机理进行了深入的研究和探讨。     

Critical Behaviors in a Stochastic One-Dimensional Sand-Pile Model

A one-dimensional sand-pile model (Manna model), which has a stochastic redistribution process, is studied both in discrete and continuous manners. The system evolves into a critical state after a transient period. A detailed analysis of the probability distribution of the avalanche size and duration is numerically investigated. Interestingly,contrary to the deterministic one-dimensional sand-pile model, where multifractal analysis works well, the analysis based on simple finite-size scaling is suited to fitting the data on the distribution of the avalanche size and duration. The exponents characterizing these probability distributions are measured. Scaling relations of these scaling exponents and their universality class are discussed.     

Equal-power 4m-th power sum squeezing of generalized magnetic-field component in vacuum state immiting four-state superposition multimode entangled state light field

By utilizing multimode squeezed states theory, we study the generalized nonlinear equal-power higherpower sum squeezing properties of the generalized magnetic-field component in four-state superposition multimode entangled state light field ｜ψ1^（4）〉q. The state is composed of multimode vacuum state, multimode coherent state and its contrary state, multimode imaginary coherent state. It is found that the state ｜ψ1^（4）〉q is a type of four-state superposition multimode nonclassical light field, and under certain fixed conditions, the generalized magnetic-field component in the state ｜ψ1^（4）〉q can display generalized nonlinear equal-power 4m-th power sum squeezing effects which change periodically.     

平行双射流场纳米颗粒的形成与凝聚的研究

对平行双射流中H2SO4蒸气扩散进行了大涡模拟,给出了硫酸/水系统成核生成纳米颗粒及颗粒的凝聚过程中颗粒的分布特性,分析了燃料中硫的浓度、环境相对湿度以及射流Reynolds数对于颗粒浓度和粒径分布的影响．结果表明,硫酸/水系统会成核生成大量的纳米颗粒,在双管射流的中间和射流场周围,颗粒具有较高的浓度;颗粒的凝聚过程使颗粒的数量减少、直径变大;随着硫的浓度的增加,流场中的颗粒浓度有明显增加,而成核后形成的颗粒直径减小;环境湿度和Reynolds数的增大,有利于成核过程,因而导致形成更多的颗粒．     

自适应设计广义线性模型极大拟似然估计的渐近性

在对Fisher信息矩阵的最小特征根最一般的假定,响应变量的矩条件尽可能弱和其它正则条件下,证明了自适应设计广义线性模型中极大拟似然估计的强相合性与渐近正态性,同时给出了强收敛速度.     

Highly Efficient Simplified Organic Light-Emitting Diodes Utilizing F4-TCNQ as an Anode Buffer Layer

We demonstrate that the electroluminescent performances of organic light-emitting diodes （OLEDs） are significantly improved by evaporating a thin F4-TCNQ film as an anode buffer layer on the ITO anode. The optimum Alq3-based OLEDs with F4-TCNQ buffer layer exhibit a lower turn-on voltage of 2.6 V, a higher brightness of 39820cd/m^2 at 13 V, and a higher current efficiency of 5.96cd/A at 6 V, which are obviously superior to those of the conventional device （turn-on voltage of 4.1 V, brightness of 18230cd/m^2 at 13 V, and maximum current efficiency of 2.74calla at 10 V）. Furthermore, the buffered devices with F4-TCNQ as the buffer layer could not only increase the efficiency but also simplify the fabrication process compared with the p-doped devices in which F4-TCNQ is doped into β-NPB as p-HTL （3.11 cd/A at 7 V）. The reason why the current efficiency of the p-doped devices is lower than that of the buffered devices is analyzed based on the concept of doping, the measurement of absorption and photoluminescence spectra of the organic materials, and the current density-voltage characteristics of the corresponding hole-only devices.     

给定最大度的单圈偶图的谱半径

单圈偶图是边数等于顶点数的简单连通偶图.Δ（G）表示图G的最大度.文中给出了最大度为Δ(≥ⁿ⁺¹/2)的n阶单圈偶图的谱半径的上界,并刻画了达到该上界的图.文中还证明了当Δ（G）≥[（2n+1）/3]+1时,n（≥8）阶单圈偶图G的谱半径随着最大度的递增而严格递增,并在此基础上给出了谱半径排在前17位的n（≥16）阶单圈偶图.     

The Discrete Subgroups and Jфrgensen’s Inequality for SL(m,Cp)

In this paper, we give discreteness criteria of subgroups of the special linear group on Qp or Cp in two and higher dimensions. J rgensen's inequality gives a necessary condition for a nonelementary group of Mbius transformations to be discrete. We give a version of Jфrgensen's inequality for SL(m, Cp).