CO_2化学吸收技术的模拟及环境影响评价

本文采用二乙醇胺(DEA)作为化学吸收剂,通过流程模拟工具Aspen plus对电厂烟道气的CO_2捕集过程进行模拟,分析各个关键参数对系统性能的影响。最后利用MATLAB软件构建了三种模型,对CO_2捕集技术的环境影响进行评价。结论表明:升高吸收溶液温度会减少DEA溶剂损失,降低再沸器热负荷,不过提高溶液温度会消耗额外的能量;当吸收溶液质量分数为0.25时,再沸器消耗的等效功最少;在轮船运输场景下,当泄漏因子取0.05时,其有效排放因子大于参考电厂的排放因子,CCS技术在减缓气候变暖中不会起到作用.     

Protecting Distribution Entanglement by Weak Measurement and Reversal under Various Decoherence Sources

Protection of entanglement from disturbance of the environment is an essential task marion processing. We examine the validity and limitation of the weak measurement and reversal in quantum infor- （WMR） operation in the protection of distributed entanglement from various decoherence sources. Since the entanglement variation can be investigated analytically for an arbitrarily entangled bipartite pure state under three kinds of typical noisy quantum channels, we show explicitly that the WMR operation indeed helps for protecting distributed entanglement from ampli- tude damping and phase damping, but not for depolarizing. Bxperimental feasibility for testing our results is discussed using current laboratory techniques.     

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针对HL-2A装置极向场电源晶闸管触发器系统同步信号波形畸变严重、频率不断变化的特点,通过分析和比较各种滤波器的滤波效果,提出了一个多级数字滤波器联合滤波的方案。利用MATLAB软件搭建了该滤波器的仿真模型,并对其进行了仿真分析,理论上证明了该方案的可行性。通过估计算法的延时,证明了该数字滤波器满足实时信号处理的要求。     

Design and Fabrication of Six-Channel Complex-Coupled DFB Quantum Cascade Laser Arrays Based on a Sampled Grating

We designed and fabricated a six-channel complex-coupled distributed feedback （DFB） quantum cascade laser arrays based on a sampled Bragg grating. The six-channel DFB laser arrays exhibit a linear tuning range of 74nm centered at a wavelength of 7.55μm at room temperature. Robust single-mode emission with a side mode suppression ratio about 20 dB was observed, even at full power. The used sampled grating and reflectivity coating on the back facet lead to the peak output power varying from 55 to 82 m W with a small difference in slope efficiency from 100 to 128mW/A.     

Passively Q-Switched Tm,Ho：YVO4 Laser with Cr：ZnS Saturable Absorber at 2 μm

A stable diode-pumped passively Q-switched Tm,Ho：YVO4 laser with Cr：ZnS saturable absorber is reported. The shortest pulse duration of -500 ns with the central wavelength of 2041 nm is obtained at the pump power of 7.4 W, corresponding to the pulse energy of 3.5 μd at repetition rate of 65 kHz.     

A Diode-Pumped 1617 nm Single Longitudinal Mode Er：YAG Laser with Intra-Cavity Etalons

We demonstrate the continuous wave p-polarized single longitudinal mode （SLM） operation of an Er：YAG laser at 1617.6nm pumped by a diode-laser with three inserted Fabry-Perot （FP） etalons at room temperature. The Brewster angle inserted FP is applied to obtain the p-polarized laser. For free running, the maximum output power is 570 m W with a pump power of 12.5 W. An incident pump power of 12.5 W is used to generate the maximum p-polarized single longitudinal mode output power of 78.5 m W, corresponding to a slope efficiency of 1.6% and an optical-to-optical efficiency of 0.61%. The beam quality M2 is measured to be 1.15 at the highest SLM output power. This stable polarized SLM oscillation is encouraging due to its application for an injection-locked system used as a master laser.     

LD抽运腔内和频571.6 nm连续波黄光激光器

报道了全固态连续波571.6 nm黄光激光器.黄激光是分别由两片Nd∶YAG的1 444 nm和946 nm谱线非线性和频产生,两条谱线在各自晶体对应能级跃迁分别为4F3/2-4I15/2和4F3/2-4I9/2.实验中采用复合腔结构,利用RTP晶体II类临界相位进行内腔和频,当注入到两片Nd∶YAG晶体的抽运功率分别为25 W和14.8 W时,获得562 mW的连续波571.6 nm黄激光输出,4 h功率稳定度优于±2.9％.     

紫外光谱法监测阿司匹林合成体系中的阿司匹林和水杨酸

建立一种同时快速定量分析阿司匹林合成体系中阿司匹林和水杨酸的方法。通过均匀设计构造样本并采集其紫外光谱,结合偏最小二乘法（PLS）建立同时测定混合体系中阿司匹林和水杨酸的校正模型,阿司匹林和水杨酸模型的校正均方根误差分别为1.708μg/mL和0.435μg/mL。该模型用于预测氨基磺酸催化合成过程中阿司匹林和水杨酸含量,二组分回收率在93.48%—108.37%之间,相对标准偏差（RSD）分别为3.45%和4.80%。结果表明,紫外光谱法结合PLS模型实现氨基磺酸催化合成阿司匹林过程的实时监测是可行的。     

电化学法制备Ni-W-P纳米线阵列电极及其催化析氢性能

采用二次氧化法制备了多孔阳极氧化铝(AAO)模板, 通过控制电位沉积技术在AAO模板内组装了Ni-W-P合金纳米线阵列. 在扫描电子显微镜(SEM)下观察到Ni-W-P纳米线表面光滑, 长约20 μm, 直径均匀(约为100 nm), 与AAO模板孔径基本一致. 阴极极化曲线和交流阻抗图谱(EIS)的测试结果表明, Ni-W-P合金纳米线阵列电极析氢反应(HER)电阻减小, 具有更高的催化析氢活性, 电流密度为10 mA·cm^-2时, 析氢极化电位较Ni-W-P合金电极正移约250 mV.