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91.
92.
Two quantities ηrel and are applied to study the nonideal acetone–water association mixture. An all-atom acetone model and a TIP5P water model have been adopted for molecular dynamics simulation. We study the transport properties of the system comparing the 's of strong hydrogen bond and weak contact based on transport properties, MD simulations together with NMR experimental data and find good agreement of concentration dependence, which exhibits the cooperation effect. 相似文献
93.
Zhaoqiang Lu Lin Cheng Jun Li Kai Zhang Song Yi Jingui Qin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):925-932
The synthesis and structural characterization of a series of novel, fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties are described. The monomers, 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a – 2d ), were conveniently and efficiently synthesized from phenols and phthalic anhydride in two steps via 2‐(4′‐hydroxybenzoyl)benzoic acids, which were first obtained by the Friedel–Crafts reaction in good yields and with high stereoselectivity and were then converted into 2a – 2d by fusion with hydrazine. All the polymers were prepared by nucleophilic aromatic substitution (SNAr) polycondensation between the compounds perfluorobiphenyl and 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a ‐ 2d ). The resulting fluorinated polymers were readily soluble in common organic solvents (e.g., CHCl3, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, N‐methylpyrrolidone, etc.) at room temperature. Their weight‐average molecular weights and the polydispersities ranged from (7.96–18.25) × 103 to 1.31–2.71, respectively. Their glass‐transition temperatures varied from 213 to 263 °C. They were all stable up to 390 °C both in air and in argon. The 5% weight‐loss temperatures of these polymers in air and argon ranged from 393–487 to 437–509 °C, respectively. Wide‐angle X‐ray diffraction studies indicated they were all amorphous and could be attributed to the presence of kink nonplanar moiety, phenyl phthalazinone along the polymer backbone. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 925–932, 2004 相似文献
94.
Do W. Lee Eun Y. Seo Sung I. Cho Chae S. Yi 《Journal of polymer science. Part A, Polymer chemistry》2004,42(11):2747-2755
Pyridine‐2‐carboximidates [methyl ( 1a ), ethyl ( 1b ), isopropyl ( 1c ), cyclopentyl ( 1d ), cyclohexyl ( 1e ), n‐octyl ( 1f ), and benzyl ( 1g )] were prepared from the reaction of 2‐cyanopyridine with the corresponding alcohols. Cyclopentyl‐substituted 1d was found to be a highly effective ligand for copper‐catalyzed atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA). For example, the observed rate constant for a CuBr/ 1d catalytic system was found to be nearly twice as high as the cyclohexyl‐substituted CuBr/ 1e catalytic system [kobs = (1.19 vs 0.56) × 10?4 s?1). The effects of the solvents, temperature, catalyst/initiator, and solvent/monomer ratio on the ATRP of MMA were studied systematically for the CuBr/ 1d catalytic system. The optimum condition for the ATRP of MMA was found to be a 1:2:1:400 [CuBr]o/[ 1d ]o/[ethyl 2‐bromoisobutyrate]o/[MMA]o ratio at 60 °C in veratrole solution, which yielded well‐defined poly(MMA) with a narrow molecular weight distribution of 1.14. The catalytically active copper complex 2d was isolated from the reaction of CuBr with 1d . Narrow molecular weight distributions as low as 1.06 were achieved for the CuBr/ 1d catalytic system by employing 10% of the deactivator CuBr2. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2747–2755, 2004 相似文献
95.
The reversible nonlinear conduction (RNC) in of high‐density polyethylene/acetylene carbon black composites with different degrees of crosslinking was studied above room temperature and below the melting point of high‐density polyethylene (HDPE). The experimental current density‐electric field strength curves can be overlapped onto a master curve, suggesting that the microscopic mechanisms for the appearance of RNC exist regardless of the ambient temperature and the crosslinking degree of the HDPE matrix. The relationship between the crossover current density and the linear conductivity can be explained in the framework of the dynamic random‐resistor‐network model. According to these results, two electron‐tunneling models are suggested to interpret the microscopic conduction behavior. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1212–1217, 2004 相似文献
96.
97.
由于可见光成像系统的聚焦范围有限,因而在成像过程中,除聚焦良好的物体能生成清晰的图像外,该物体前后一定距离外的所有物体都将呈现不同程度的模糊.为了获得场景内所有物体均清晰的图像,在分析了多聚焦图像成像机理的基础上,提出了一种基于小波包变换的融合方法.它是将成像系统先聚焦在一部分对象上,得到其清晰的图像;然后再将其聚焦在另一部分对象上,得到另一清晰的图像;最后把这两幅实验图像加以融合,从而获得场景内所有物体均清晰的图像.实验结果表明,基于小波包变换的融合方法能够将信号的频带进行多层次划分,对高频成分也能进一步地分解,可有效综合多聚焦图像. 相似文献
98.
以铝酸镧(001)单晶为基片,采用两步法制备Tl2Ba2CaCu2Oy(Tl 2212)高 温超导薄膜.首先,利用脉冲激光沉积(PLD)工艺沉积Ba2CaCu2Ox非晶前驱体薄膜;然后,前驱体薄膜在高温(720—850℃)下密封钢容器里铊化结晶形成Tl 2212薄膜.XRD结果表明Tl2212 薄膜是沿c轴方向生长的,其相组成为Tl 2212,摇摆曲线(0012)的半高宽为0.72° ,SEM图像显示其表面光滑平整,其零电阻温度为106.2K.
关键词:
Tl 2212超导薄膜
脉冲激光沉积 相似文献
99.
以PCl3为脱水剂,将邻氨基硫酚与水杨酸脱水环化合成出2-(2-羟基苯基)苯并噻唑,并进一步将所得产物与乙酸锌反应合成出2-(2-羟基苯基)苯并噻唑螯合锌(Zn(BTZ)2)材料。以该配合物作为发光层制备出结构为ITO/PVK:TPD/Zn(BTZ)2/Al近白色电致发光器件,其色坐标位于白场之内(x=0.242,y=0.359),在驱动电压为16V时,亮度达3200cdm2,对应的量子效率为0.32%。进一步在Zn(BTZ)2中掺入橙红色染料Rubrene,制成ITO/PVK:TPD/Zn(BTZ)2:Rubrene/Al结构器件,实现了纯白色发光(色坐标值:x=0.324,y=0.343),非常接近于白色等能点,且量子效率达0.47%。最后对上述器件的发光和电学性能进行了深入的研究和探讨。 相似文献
100.
将爆磁压缩等效为电流源的方法,对爆磁压缩发生器通过脉冲变压器对脉冲形成线充电进行了理论分析,得出爆磁压缩发生器在负载上产生电流波形(简称负载电流)为直线情况和任意电流波形情况下充电电流和充电电压的表达式。分析表明变压器耦合互感与负载电流随时间变化增长率是脉冲形成线充电的两个重要参数,脉冲形成线第一个充电电压峰值与变压器的耦合互感和负载电流波形斜率成正比,负载电流波形斜率的变化可以改变充电电压峰值的时间,斜率不断增加可以延长第一个充电电压峰值时间,从而可能增加充电电压的幅值,提高爆磁压缩发生器能量的利用效率。 相似文献