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91.
We describe the dynamics of phase separation and transition processes, in binary mesomorphic mixtures with the help of a system of two coupled partial derivative equations. We emphasize, both analytically and numerically, that, depending on the regions of the phase diagram, the dynamical behaviour may result either from a two step process (first the phase transition, then the phase separation) or from a process showing salient features of the Cahn-Hilliard spinodal decomposition (bicontinuous periodic networks in the transient stages). The dynamics of evolution of the domain patterns are illustrated with the help of numerical simulations in which homeotropic and planar anchorages are visualized. 相似文献
92.
Y. Wardi 《Journal of Optimization Theory and Applications》1990,64(2):399-417
Stochastic algorithms for optimization problems, where function evaluations are done by Monte Carlo simulations, are presented. At each iteratex
i, they draw a predetermined numbern(i) of sample points from an underlying probability space; based on these sample points, they compute a feasible-descent direction, an Armijo stepsize, and the next iteratex
i+1. For an appropriate optimality function , corresponding to an optimality condition, it is shown that, ifn(i) , then (x
i) 0, whereJ is a set of integers whose upper density is zero. First, convergence is shown for a general algorithm prototype: then, a steepest-descent algorithm for unconstrained problems and a feasible-direction algorithm for problems with inequality constraints are developed. A numerical example is supplied. 相似文献
93.
In this paper, we treat a domain optimization problem in which the boundary-value problem is a Neumann problem. In the case where the domain is in a three-dimensional Euclidean space, the first-order and the second-order necessary conditions which the optimal domain must satisfy are derived under a constraint which is the generalization of the requisite of constant volume.Portions of this paper were presented at the 13th IFIP Conference on System Modelling and Optimization, Tokyo, Japan, 1987. 相似文献
94.
Th. Brückel Y. Chernenkov B. Dorner V. P. Plakhty O. P. Smirnov 《Zeitschrift für Physik B Condensed Matter》1990,79(3):389-395
We have measured the spin wave spectrum for the garnet Ca3Cr2Ge3O12 by means of inelastic neutron scattering. The data can be well described in the framework of linear spin wave theory if we assume a Heisenberg model with two exchange parameters up to the next nearest neighbours (J
1 andJ
2) and a staggered anisotropy field (A). A least squares fit to the observed dispersion relations yield the following values for these parameters: J
1=–0.582(8)K,J
2=0.416(4)K,A=0.25(8)K. Although symmetry requires that two nearest neighbour exchange constantsJ
1 andJ
1
'
must be distinguished, only the average J
1=(J
1+3J
1
'
)/4 and the condition –0.35 K <J
1=J
1-J
1
'
<0.50 K could be deduced from the experiment. The most striking result is the positive value ofJ
2. We discuss the implications for an understanding of superexchange mediated by more than one oxygen atom. In an extension of the conventional analysis we have calculated the integrated intensities in order to check the eigenvectors directly. Good agreement between observed and calculated intensities was obtained. 相似文献
95.
Y. Bassiakos A. Athanassiou S. Roussiakis G. Theodorou 《Journal of Radioanalytical and Nuclear Chemistry》1992,158(2):239-250
Five Upper Miocene fossil Hipparion molars were studied for U-distribution by Fission Track. U uptake has reached the whole mass of the teeth and no saturation fronts seem to occur in the interior layers. Mean U-concentration in dentine, cement and enamel was 157, 139 and 78 ppm, respectively. Uenamel/Udentine 0.5 is considerably higher than 0.1 reported in the past for Upper-Quaternary mammoth teeth. These features are disadvantageous for ESR-dating in Hipparion enamel, although a long-lived signal (g=2.0018) is apparent. Leaching phenomena occur in the outer regions of these teeth. Inner enamel folding seems to have hindered a more uniform U-distribution in the teeth. 相似文献
96.
Egyptian Portland Cement in the form of one inch cube was hydrated at different times of hydration. Nine cubes of each period of hydration were heated for five minutes 200, 300, 400 up to 1000°C then were quenched in air. The compressive strength was measured for these samples and related to unheated ones. These cubes were ground and measured by Mössbauer spectrometry to correlate the effect of dehydration of cement pastes on the states of iron, with the decrease of compressive strength. It was observed that starting from 400°C the central doublet characteristic of the hydration process decreased as the dehydration temperature was increased. At 1000°C the dehydration process was complete, the central doublet disappeared and the compressive strength vanished. The hydration process was found to be reversible. The application of Mössbauer spectrometry to estimate the degree of fire in concrete building was demonstrated. 相似文献
97.
98.
When the cations bound to purple membrane are removed it turns blue, and when this blue membrane is irradiated its color changes to pink. Irradiation of pink membrane leads to the reformation of blue membrane. We have determined that the quantum efficiency for the formation of pink membrane from deionized blue membrane is 1.6 ± 0.6 ± 10 4 at 0o C, pH 5.0. We also found that the quantum efficiency for the back photoconversion, i.e. the formation of blue membrane from pink membrane, is 8.8 ± 1.6 ± 10-3 at 0o C, 55 times greater than that of the forward photoconversion reaction. The extinction coefficients of the pink membrane and blue membrane were determined to be 44 500 ± 670 cm-1 M-1 at 491 nm and 54 760 ± 830 cm-1 M -1 at 603 nm, respectively, assuming light-adapted purple membrane is 63 000 cm-1 M -1 at 568 nm. The quantum efficiency for forming pink membrane from blue membrane is much lower than that for forming the photointermediate of the blue membrane's photocycle. Their relationship is similar to that of light-adaptation and photocycle of the dark-adapted purple membrane. 相似文献
99.
100.