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991.
G. N. Kozhemyakin D. V. Lutskiy M. A. Rom P. V. Mateychenko 《Crystallography Reports》2008,53(7):1267-1271
The growth conditions and structural quality of Sb-Bi gradient single crystals with Bi content from 2 to 18 at %, grown by
the Czochralski method with solid phase feed, are investigated. Bi distribution in the crystals along their pulling direction
are studied by electron probe microanalysis and the change in the interplanar spacing is analyzed by double-crystal X-ray
diffraction. It is established that the pulling rate and feed mass affect the Bi distribution in Sb-Bi single crystals. 相似文献
992.
Methods for accelerometer unit calibration are usually based on sufficiently strict requirements on the knowledge of the gravity orientation with respect to the unit (of the order of fractions of an arc minute). But it is not always possible to know the orientation with such high accuracy. In the present paper, we consider an approach to accelerometer unit calibration for whose implementation it suffices to have rough angular information (of the order of tens of arc minutes). We use a guaranteeing approach to calculate optimal schemes calibration experiments and propose an iterative scheme of calibration. 相似文献
993.
Three-dimensional laminar forced convection including steady-periodic transition is investigated up to periodic-chaotic transition
in the fully developed region of coolant passages with staggered arrays of pin fins. Comparative examples concern overall
pressure losses and heat transfer characteristics of circular, square and elliptical pins made of nickel and copper. In the
numerical model, transient conjugate heat transfer is assumed and space periodicities in pressure, velocity components and
temperatures are taken into account. In the range of operative conditions investigated, overall friction factors increase
almost linearly with the Reynolds number, while the increase of overall Nusselt numbers with the Reynolds number is characterized
by two slope changes connected with the onset of streamwise vortices, and the shedding of transverse vortices, respectively.
The use of copper, instead of nickel, increases the overall Nusselt number with all shapes, but is particularly beneficial
to the elliptical section. Square pins are characterized by the highest values of friction factors, but are also the best
performers as far as convection enhancing is concerned. The reverse is true for the elliptical pins which are characterized
by the lowest values of friction factors, but are the worst performers as far as convection enhancing is concerned. On the
basis of overall performances, the elliptical pins made of copper are the best choice, at least in the upper range of Reynolds
numbers investigated. 相似文献
994.
Adsorption of the copper ions from aqueous solutions, benzene, and water on the active carbon obtained by chemical activation
from walnut shells was studied. The active carbon was additionally oxidized with hydrogen peroxide and then impregnated with
nitrogen-containing compounds. As a result of impregnation with melamine, a secondary porosity is formed within the oxidized
active carbon, leading to an increase in the specific surface of the sorbent. A modified carbon surface is heterogeneous,
and the carbons themselves exhibit catalytic activity in the oxidation of luminol and decomposition of hydrogen peroxide. 相似文献
995.
996.
K. Migléczi Gy. Somorjai M. Pátfalusi G. Tóth Gy. Horváth I. Hazai 《Chromatographia》2004,60(1):S67-S74
GYKI-16084 – (+)-(R)-2-{3-(benzo[1,4]dioxan-2-yl-methylamino)-1-propyl}-3(2H)-pyridazinone hydrochloride – is a new drug candidate for the treatment of benign prostatic hyperplasia. In our study the major metabolites formed in the rat and dog were isolated from dog and rat urine, then their structures were elucidated by means of MS and NMR. A two stage solid phase extraction (SPE) procedure and a semi-preparative HPLC method were developed utilizing various mechanisms of separation. The major metabolites proved to be isomeric glucuronides of the benzodioxane moiety hydroxylated at positions 6 or 7 and {2-(2-carboxyethyl)-3(2H)-pyridazinone}. 相似文献
997.
998.
A. I. Kolesnikov I. A. Kaplunov I. V. Talyzin S. A. Tret’yakov O. V. Gritsunova E. Yu. Vorontsova 《Crystallography Reports》2008,53(7):1144-1149
A computer simulation and measurements of the light transmittance of germanium and paratellurite crystals of different thickness
were used to show that, at scattering probabilities of photons comparable to their absorption probabilities, the standard
methods for calculating light extinction coefficients on the basis of the Bouguer law lead to rough errors in estimation of
the optical quality of a material. 相似文献
999.
A. P. Dudka 《Crystallography Reports》2008,53(2):351-355
The methods of automation of the procedure for crystal structure model refinement from experimental diffraction data, implemented in the ASTRA program package, are described. Such tools as statistical tests, parameter scanning, and data scanning reduce the time necessary for structural investigation. At strong correlations between parameters, especially when the data set is limited, parameter scanning has an advantage over the full-matrix refinement. 相似文献
1000.
A mathematical model of the formation of primary grown-in microdefects on the basis of dissociation diffusion is presented.
Cases of “vacancy-oxygen” (V + O) and “carbon-interstitial” (C + I) interaction near the crystallization front are considered
for dislocation-free Si single crystals grown by the floating-zone and Czochralski methods. The approximate analytical expressions
obtained by setting 1D and 2D temperature fields in a crystal are in good agreement with the heterogeneous mechanism of formation
of grown-in microdefects. 相似文献