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61.
We report herein the supramolecular assembly and spectroscopic and luminescent properties of gold(I) complexes of diphosphines (dppm [bis(diphenylphosphino)methane], dppp [1,3-bis(diphenylphosphino)propane], and dpppn [1,5-bis(diphenylphosphino)pentane]) and N,N'-bis-4-methylpyridyl oxalamide (L). The dppm and dppp cases form the rectangular structures, [dppm(Au(2))L](2)(ClO(4))(4) and [dppp(Au(2))L](2)(ClO(4))(4), with four gold(I) ions at the corners, as well as two L and two dppm or dppp ligands as edges, featuring 38- and 42-membered rings for the former and the latter, respectively. Remarkably, the packing of the dppp complexes shows interesting one-dimensional rectangular channels in the solid state, most likely due to intermolecular pi...pi interactions. The dpppn complex has been structurally characterized as a one-dimensional coordination polymer, {[(dpppn)(3.5)(Au(7))L(3.5)](PF(6))(7)}. The absorptions and emissions of the compounds are in general due to intraligand transitions, but aurophilic or pi...pi interactions could also make partial contributions. The dipyridyl amide system with the amides incorporated into the bridging ligands as well as the one-dimensional rectangular channels in the solid state for the dppp-based rectangle make this a promising family of metal-containing cyclic peptides in crystal engineering and molecular-recognition studies. 相似文献
62.
Jhieh-Yu Shyng How-Ming Shieh Gwo-Hshiung Tzeng Shu-Huei Hsieh 《European Journal of Operational Research》2010
This study proposes a novel Forward Search and Backward Trace (FSBT) technique based on Rough Set Theory to improve data analysis and extend the scope of observations made from sample data to solve personal investment portfolio problems. Rough Set Theory mathematically classifies data into class sets. The class set with the most objects may generate one decision rule. The rules generated from RST are rough and fragmented, that are very difficult to interpret the information. An empirical case is used to generate more than 85 rules by the RST method in comparison with FSBT method which only generated 14 rules. This result can show our proposed method is better than traditional RST method based on class sets that contain the most objects. Much of human knowledge is described in natural language. It is a very important thing to convert information from computer databases into normal human language. Sample data taken from features with the same backgrounds are used to compile different portfolios that investment companies and investment advisors can employ to satisfy the investor’ needs. The method not only can provide decision-making rules, but also can offer alternative strategies for better data analysis. We believe that the FSBT technique can be fully applied in research on investment marketing. 相似文献
63.
64.
A New Approach for Visual Cryptography 总被引:1,自引:0,他引:1
Visual cryptography is to encrypt a secret image into some shares (transparencies) such that any qualified subset of the shares can recover the secret visually. The conventional definition requires that the revealed secret images are always darker than the backgrounds. We observed that this is not necessary, in particular, for the textual images.In this paper, we proposed an improved definition for visual cryptography based on our observation, in which the revealed images may be darker or lighter than the backgrounds. We studied properties and obtained bounds for visual cryptography schemes based on the new definition. We proposed methods to construct visual cryptography schemes based on the new definition. The experiments showed that visual cryptography schemes based on our definition indeed have better pixel expansion in average. 相似文献
65.
Cherngy-Chyi Tzeng Yue-Ling Zhao Yeh-Long Chen Shorong-Shii Liou Tai-Chi Wang Ya-Ling Chang Che-Ming Teng 《Helvetica chimica acta》1997,80(8):2337-2344
In a search for inhibitors of platelet aggregation, a number of α-methylidene-γ-butyrolactones 5 and 6 bearing flavone or xanthone moieties, respectively, were synthesized and evaluated for their antiplatelet activity against thrombin(Thr)-, arachidonic-acid(AA)-, collagen(Col)?, and platelet-activating-factor(PAF)-induced aggregation in washed rabbit platelets. These compounds were synthesized from 7-hydroxyflavone ( 1 ) or 3-hydroxyxanthone ( 2 ) via O-alkylation (→ 3 and 4 , resp.) and Reformatsky-type condensation (Scheme). Most of the flavone-containing α-methylidene-γ-butyrolactones 5a – d showed potent antiplatelet effects on AA- and Col-induced aggregation, while xanthone derivatives 6c – e were found to have the same pharmacological profile than aspirin in which only AA-induced aggregation was inhibited (Table 1). However, 6c – e were approximately three to ten times more potent than aspirin (Table 2). For the vasorelaxing effects, 5a was the only compound which exhibited significant inhibitory activity on the high-K+ medium, Ca2+-induced vasoconstriction (Table3). Both 5a and 6a , with an aliphatic Me substituent at C(γ) of the lactone, were active against norepinephrine-induced phasic and tonic constrictions while their γ-aryl-substituted counterparts 5b – f and 6b – f were inactive. 相似文献
66.
Cherng-Chyi Tzeng Yeh-Long Chen Chyi-Jia Wang Tai-Chi Wang Ya-Ling Chang Che-Ming Teng 《Helvetica chimica acta》1997,80(4):1161-1168
O-Alkylation of 8-hydroxy-1H-quinolin-2-one ( 1 ) afforded 8-(2-oxopropoxy)-1H-quinolin-2-one ( 2 ) which was immediately cyclized to form the tricyclic 2,3-dihydro-3-hydroxy-3-methyl-5H-pyrido[1,2,3-de][1,4]benzoxazine,-5-one ( 3). The Reformatsky-type condensation of 3 furnished antiplatelet 8-[(2,3,4,5-tetrahydro-2-methyl-4-methylidene-5-oxofuran-2-yl)melhoxy]-1H-quinolin-2-one ( 4 ). Its counterparts 7a – f , Ph-substituted at C(2) of the furan ring, were obtained from 1 via alkylation and the Reformatsky-type condensation. Although compound 4 was less active against platelet aggregation than 7a – f , it was the only compound which exhibited significant inhibitory activity on high-K+ medium, Ca2+-induced vasoconstriction and was more active than most of its Ph-substituted counterparts against norepinephrine-induced vasoconstrictions. 相似文献
67.
Chromatographic investigation of an acetone extract of the octocoral Xenia puerto‐galerae afforded three new cadinene sesquiterpenes; 8‐epi‐xenitorin A ( 1 ), 10‐epi‐xenitorin C ( 2 ), and 7‐isopropenyl‐4,10‐dimethyl‐2,3,4,5‐tetrahydronaphthalene ( 3 ), in addition to four known cadinene analogs ( 4 , 11–13 ) and six xenicanes ( 5–10 ). The structures were elucidated through spectroscopic analysis, especially 2D NMR. A biogenetic pathway of 1–3 and analogs was proposed. 相似文献
68.
K.-W. Lin Y.-M. Tzeng Z.-Y. Guo C.-Y. Liu J. van Lierop 《Journal of magnetism and magnetic materials》2006
We have measured positive exchange bias in a Ni80Fe20/NixFe1−xO thin-film nanocrystallite system. A series of solid solution NixFe1−xO 40 nm thick films capped with 25 nm thick Ni80Fe20 were deposited using a range of %O2/Ar bombardment energies (i.e. End-Hall voltages). Proper tuning of the deposition conditions results in a Ni80Fe20/NixFe1−xO (30%O2/Ar) based bilayer that exhibits a positive exchange bias loop shift of Hex∼60 Oe at 150 K. 相似文献
69.
Long-Li Lai Ling-Yung Wang Hui-Fang Tzeng Jian-Wen Lin Sheng-Ming Huang Kuang-Lieh Lu Yi-Hung Liu Yu Wang 《Liquid crystals》2005,32(3):389-394
To help understand the influence of polarity and length of the terminal alkyl chain of a molecule on the molecular stacking of a liquid crystal and on its mesogenic behaviour, four new aminophenylazo-(4)-p-alkylbenzenes were prepared and one of them was further studied by single crystal structure determination. The molecular stacking based on this crystallographic data was established, and compared with that of two previously reported homologues. The mesogenic behaviour of this series of compounds was also investigated. 相似文献
70.
A good traffic assignment model can be a powerful tool to describe the characteristics of traffic behavior in a road network. The traffic assignment results often play an important role in transportation planning, e.g., an optimal and economical network design. Many traditional traffic assignment models rely heavily on the travel cost function established by Wardrop’s principles; however, the Wardrop’s travel cost function has been proven to be weak for explaining the uncertainty and interactivity of traffic among links. This study tries to construct a traffic assignment model that is different from Wardrop’s in many aspects. First, it considers the cross-effect among the links. Second, a fuzzy travel cost function is established based on the possibility concept instead of precise calculation of traffic volumes. Third, the techniques of fuzzy measure and fuzzy integral are applied to calculate the subjectively perceived travel costs during traffic assignment. Furthermore, in order to validate our model, a detailed network with 22 nodes and 36 links is used to illustrate it. Study results show that our model explains more interactivity and uncertainty of traffic among links when compared with the traditional model of Wardrop’s. 相似文献