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991.
A. Jarid M. Aaid Y. Legoux J. Merini M. Loudet D. Gonbeau G. Pfister-Guillouzo 《Chemical physics》1991,150(3):353-360
The electronic and structural characteristics of CrF5, CrF4, RuF5 and RuF4 were studied. Ab initio (SCF-CI) calculations were performed with different structures and spin states for each complex. The favored conformation always corresponds to the highest multiplicity: doublet for CrF5 in D3h, triplet for CrF4 in Td, quadruplet for RuF5 in C4v and quintuplet for RuF4 in D4h symmetry. 相似文献
992.
Raskulova T. V. Volkova L. I. Danilevich Yu. S. Shainyan B. A. Khaliullin A. K. 《Russian Journal of Organic Chemistry》2002,38(5):754-755
Russian Journal of Organic Chemistry - 相似文献
993.
994.
995.
996.
J. C. S. Moraes E. M. Telles F. C. Cruz A. Scalabrin D. Pereira C. Garelli N. Ioli A. Moretti F. Strumia 《International Journal of Infrared and Millimeter Waves》1991,12(12):1475-1486
We report the discovery of 57 new fir laser lines from13CD3OH molecule optically pumped by a waveguide CO2 laser of 300 MHz tunability. For all lines, precise frequency offset measurements between the CO2 line center and the center of the absorbing13CD3OH line were performed using the transferred Lamb-Dip technique. We have also measured directly the frequency of seven FIR laser lines by heterodyning with already known laser lines. We present a complete list of all known laser lines (134) and frequency measurements (24) for this molecule.Work supported by CNPq, FAPESP, FAEP-Brasil, and CNR-Italia 相似文献
997.
X. Luo F. Y. Shi J. X. Lin 《International Journal of Infrared and Millimeter Waves》1991,12(2):141-147
Detection of COCl2, a highly toxic gas in chemical industry, using laser photoacoustic spectroscopy is presented. The spectrophone system used has a broad band LN2 cooled CW CO laser as a source of radiation, which operates from 4.8–8.4 um in the mid-infrared. Using an extracavity open longitudinal resonant cell, absorption signals to about 30 CO laser lines in the 5.45 um region could be observed. detection sensitivity has been estimated to be ppb order.This work has been supported by the NSFC 相似文献
998.
V. Formisano G. Bellucci A. Grigoriev A. Coradini J. P. Bibring 《Il Nuovo Cimento C》1992,15(6):1113-1119
Summary Multispectral imaging of planets opens a new class of studies of atmospheric and surface signatures. With ISM experiment on
board Phobos, the first IR multispectral imaging of Mars from space was achieved. In viem of the Future Omega experiment on
board Mars 94, we present here a sample of data and results (and problems) which can be achieved by studying spectral reflectance.
Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990. 相似文献
999.
The structure of the nematic-isotropic interfacial layer is studied theoretically for systems formed by rod-like and persistent macromolecules. It is shown that the width of interfacial layer is normally of the order of the straight part of a molecule. This allows us to use the approach which describes intermolecular interactions phenomenologically (i.e. it allows us to consider all interactions), at the same time this approach describes molecular flexibility microscopically (i.e. it allows us to study the effects of flexibility correctly). It was found, that non-monotonic gradient profiles in the surface layer of the order parameter or of the concentration of molecules as a function of the coordinate perpendicular to the interface are possible. For example, a thin layer with abnormal ordering of molecules along the surface may exist near the interface for some systems. 相似文献
1000.
E. V. Zakharov S. N. Levchenko Yu. Ya. Kharlanov 《Computational Mathematics and Modeling》1997,8(3):282-287
The article considers the mathematical model of a lens antenna in the shape of a homogeneous dielectric torus excited by an
axial magnetic dipole. The boundary-value problem for an elliptical differential equation is posed and reduced by the fundamental
solution method to an integral equation of 2nd kind over the torus section. A numerical algorithm is proposed, and the numerical
results are compared with experimental findings.
Translated from Obratnye Zadachi Estestvoznaniya, Published by Moscow University, Moscow, 1997, pp. 109–115. 相似文献