全文获取类型
收费全文 | 7418篇 |
免费 | 1385篇 |
国内免费 | 1193篇 |
专业分类
化学 | 6066篇 |
晶体学 | 81篇 |
力学 | 392篇 |
综合类 | 83篇 |
数学 | 787篇 |
物理学 | 2587篇 |
出版年
2024年 | 30篇 |
2023年 | 149篇 |
2022年 | 324篇 |
2021年 | 311篇 |
2020年 | 359篇 |
2019年 | 411篇 |
2018年 | 306篇 |
2017年 | 288篇 |
2016年 | 405篇 |
2015年 | 419篇 |
2014年 | 459篇 |
2013年 | 590篇 |
2012年 | 709篇 |
2011年 | 666篇 |
2010年 | 418篇 |
2009年 | 427篇 |
2008年 | 459篇 |
2007年 | 368篇 |
2006年 | 358篇 |
2005年 | 320篇 |
2004年 | 277篇 |
2003年 | 243篇 |
2002年 | 325篇 |
2001年 | 267篇 |
2000年 | 167篇 |
1999年 | 150篇 |
1998年 | 128篇 |
1997年 | 74篇 |
1996年 | 83篇 |
1995年 | 64篇 |
1994年 | 64篇 |
1993年 | 52篇 |
1992年 | 77篇 |
1991年 | 49篇 |
1990年 | 51篇 |
1989年 | 31篇 |
1988年 | 22篇 |
1987年 | 24篇 |
1986年 | 24篇 |
1985年 | 13篇 |
1984年 | 8篇 |
1983年 | 11篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1971年 | 1篇 |
1959年 | 2篇 |
1957年 | 2篇 |
1936年 | 3篇 |
排序方式: 共有9996条查询结果,搜索用时 15 毫秒
991.
The three-component mobile phase, methanol-acetonitrile-water, has been frequently used for the separation of natural products in complicated herbal extracts by reversed-phase liquid chromatography, especially when two-component solvent systems do not work. However, the rational for optimization of this three-solvent system is not clear, so far. In this study, the retention behavior of different types of natural products in RP-LC with a methanol-acetonitrile-water elution system was studied. A total of 27 compounds from four classes, including steroids, flavonoids, phenolic acids, and triterpene saponins were analyzed by high-performance liquid chromatography coupled with mass spectrometry or ultraviolet detectors. It was interesting to find that prolonged retention times and improved separation capabilities were obtained when the acetonitrile-to-methanol ratio was 3-16%. This rule applied to all four classes of natural products under different instrumental conditions, and could be valuable for the separation of natural products in complicated samples. 相似文献
992.
Chien CC Zhang G Hwu Y Liu P Yue W Sun J Li Y Xu H Xue H Xu LX Wang CH Chen N Lu CH Lee TK Yang YC Lu YT Ching YT Shih TF Yang PC Je JH Margaritondo G 《Analytical and bioanalytical chemistry》2011,401(3):827-835
Refractive-index (phase-contrast) radiology was able to detect lung tumors less than 1 mm in live mice. Significant micromorphology differences were observed in the microradiographs between normal, inflamed, and lung cancer tissues. This was made possible by the high phase contrast and by the fast image taking that reduces the motion blur. The detection of cancer and inflammation areas by phase contrast microradiology and microtomography was validated by bioluminescence and histopathological analysis. The smallest tumor detected is less than 1 mm(3) with accuracy better than 1 × 10(-3) mm(3). This level of performance is currently suitable for animal studies, while further developments are required for clinical application. 相似文献
993.
We study in dimension d?2 low-energy spectral and scattering asymptotics for two-body d-dimensional Schrödinger operators with a radially symmetric potential falling off like −γr−2, γ>0. We consider angular momentum sectors, labelled by l=0,1,…, for which γ>2(l+d/2−1). In each such sector the reduced Schrödinger operator has infinitely many negative eigenvalues accumulating at zero. We show that the resolvent has a non-trivial oscillatory behaviour as the spectral parameter approaches zero in cones bounded away from the negative half-axis, and we derive an asymptotic formula for the phase shift. 相似文献
994.
Semiparametric models with both nonparametric and parametric components have become increasingly useful in many scientific fields, due to their appropriate representation of the trade-off between flexibility and efficiency of statistical models. In this paper we focus on semi-varying coefficient models (a.k.a. varying coefficient partially linear models) in a “large n, diverging p” situation, when both the number of parametric and nonparametric components diverges at appropriate rates, and we only consider the case p=o(n). Consistency of the estimator based on B-splines and asymptotic normality of the linear components are established under suitable assumptions. Interestingly (although not surprisingly) our analysis shows that the number of parametric components can diverge at a faster rate than the number of nonparametric components and the divergence rates of the number of the nonparametric components constrain the allowable divergence rates of the parametric components, which is a new phenomenon not established in the existing literature as far as we know. Finally, the finite sample behavior of the estimator is evaluated by some Monte Carlo studies. 相似文献
995.
EXISTENCE OF PERIODIC SOLUTIONS FOR A DIFFERENTIAL INCLUSION SYSTEMS INVOLVING THE p(t)-LAPLACIAN 总被引:1,自引:0,他引:1
We study a nonlinear periodic problem driven by the p(t)-Laplacian and having a nonsmooth potential (hemivariational inequalities). Using a variational method based on nonsmooth critical point theory for locally Lipschitz functions, we first prove the existence of at least two nontrivial solutions under the generalized subquadratic and then establish the existence of at least one nontrivial solution under the generalized superquadratic. 相似文献
996.
In this paper we consider parallel identical machines scheduling problems with deteriorating jobs. In this model, job processing times are defined by functions of their starting times. We concentrate on two goals separately, namely, minimizing the total absolute differences in completion times (TADC) and the total absolute differences in waiting times (TADW). We show that the problems remains polynomially solvable under the proposed model. 相似文献
997.
Sun Z Kim JH Zhao Y Bijarbooneh F Malgras V Lee Y Kang YM Dou SX 《Journal of the American Chemical Society》2011,133(48):19314-19317
Controlling the morphology and size of titanium dioxide (TiO(2)) nanostructures is crucial to obtain superior photocatalytic, photovoltaic, and electrochemical properties. However, the synthetic techniques for preparing such structures, especially those with complex configurations, still remain a challenge because of the rapid hydrolysis of Ti-containing polymer precursors in aqueous solution. Herein, we report a completely novel approach-three-dimensional (3D) TiO(2) nanostructures with favorable dendritic architectures-through a simple hydrothermal synthesis. The size of the 3D TiO(2) dendrites and the morphology of the constituent nano-units, in the form of nanorods, nanoribbons, and nanowires, are controlled by adjusting the precursor hydrolysis rate and the surfactant aggregation. These novel configurations of TiO(2) nanostructures possess higher surface area and superior electrochemical properties compared to nanoparticles with smooth surfaces. Our findings provide an effective solution for the synthesis of complex TiO(2) nano-architectures, which can pave the way to further improve the energy storage and energy conversion efficiency of TiO(2)-based devices. 相似文献
998.
Chang‐Xin Zhou Xue‐Yao Wang Jian‐Xia Mo Jian Zhang Li‐She Gan 《Helvetica chimica acta》2011,94(2):347-354
Two new indolizidine alkaloids, (±)‐3‐oxoisoelaeocarpine ( 1 ) and (±)‐elaeocarpine N‐oxide ( 2 ), along with three known alkaloids, (±)‐isoelaeocarpine ( 3 ), (±)‐elaeocarpine ( 4 ), and (?)‐isoelaeocarpiline ( 5 ), were isolated from an EtOH extract of the branches and leaves of Elaeocarpus sphaericus. The structures of these compounds were determined by spectroscopic and chemical methods. Furthermore, enantiomers of compounds 1 and 3 were separated on a chiral CD‐Ph column, and their absolute configurations were determined by TD‐DFT (=time‐dependent density‐functional theory) quantum‐chemical calculations of their electronic circular dichroism (ECD) spectra. 相似文献
999.
Yong Shen Ai‐Xue Zuo Zhi‐Yong Jiang Xue‐Mei Zhang Hong‐Ling Wang Ji‐Jun Chen 《Helvetica chimica acta》2011,94(1):122-126
Two new C20‐diterpenoid alkaloids, named aconicarchamines A and B ( 1 and 2 , resp.), were isolated from Aconitum carmichaelii. By UV, IR, MS, and 1D‐ and 2D‐NMR analyses, their structures were elucidated as 14,17‐dihydro‐14,17‐dihydroxyajabicine and 15‐O‐acetyllassiocarpine. Compound 1 is the third C20‐diterpenoid alkaloid with the lycoctine skeleton bearing an exocyclic C‐atom at C(14). 相似文献
1000.
Three polyoxometalates encapsulating high-nuclearity magnetic clusters MFe(5), [As(2)MFe(5)Mo(22)O(85)(H(2)O)](n-) (M = Fe(3+), n = 14; M = Ni(2+) and Mn(2+), n = 15), were synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, thermogravimetric analysis, and magnetism measurements. The polyanion [As(2)MFe(5)Mo(22)O(85)(H(2)O)](n-) consists of a central MMo(7)O(28) (M = Fe(3+), Ni(2+), and Mn(2+)) fragment and two AsMo(7)O(27) fragments linked together by two trimeric clusters, Fe(2)MoO(μ(2)-O)(2) and Fe(3)(H(2)O), to form a banana-shaped structure with C(1) symmetry. The MMo(7)O(28) and AsMo(7)O(27) units have a similar structure and can be considered as a monocapped hexavacant α-B-Keggin subunit with a central MO(4) group or a central As(III)O(3) group. The polyoxometalates have a low absorption of υ(Mo-O(d)) (925-913 cm(-1)) because most of the Mo atoms in the polyanions have at least two longer Mo-O(d) bonds. The framework of the arsenomolybdates is stable before As(2)O(3) escaping (ca. 300 °C). The analysis of magnetostructural correlations and magnetism measurements indicate the coexistence of ferro- and antiferromagnetic interactions, which give an overall ferromagnetic spin ground state in the compounds. 相似文献