Internal quantum efficiency enhancement of silicon nanocrystals using double layer Au-rich cermet films

To improve the internal quantum efficiency of silicon nanocrystals, a double layer structure with Au-rich cermet is proposed. In the region far below surface plasmon resonance energy, effective enhancement can be still obtained, which indicates means to make surface plasmon mediated enhancement efficient in a wide wavelength region especially for long wavelength.     

A liquid chromatography–tandem mass spectrometry method for the simultaneous quantification of escin Ia and escin Ib in human plasma: application to a pharmacokinetic study after intravenous administration

A rapid and sensitive liquid chromatography–tandem mass spectrometry (LC‐MS/MS) method was developed and validated for simultaneous quantification of escin Ia and escin Ib in human plasma. After a solid‐phase extraction (SPE), the analytes were separated on a Zorbax Extend C₁₈ column by isocratic elution with a mobile phase of methanol–acetonitrile–10 mm ammonium acetate (27:27:46, v/v/v) at a flow rate of 1.0 mL/min and analyzed by mass spectrometry in the positive ion multiple reaction monitoring mode. The precursor to product ion transitions of m/z 1131.8 → 807.6 was used to quantify escin Ia and escin Ib. Good linearity was achieved over a wide range of 2.00–900 ng/mL for escin Ia and 1.50–662 ng/mL for escin Ib. The intra‐ and inter‐day precisions (as relative standard deviation) were less than 11% for each QC level of escin Ia and escin Ib. The accuracies (as relative error) were within ±5.27% for escin Ia and within ±4.07% for escin Ib. The method was successfully employed in a pharmacokinetic study after a single intravenous infusion administration of sodium aescinate injection containing 10 mg escin to each of the 10 healthy volunteers. Copyright © 2010 John Wiley & Sons, Ltd.     

回归法与作图法求解实验方程之比较

以测约利弹簧秤劲度系数为例对回归法与作图法求解实验方程作了比较，并建议在高校实验教学中推广用回归法处理数据。     

师范生化学教学设计能力构成、水平层级及发展进阶研究

教学设计能力是师范生教学能力培养的重要组成部分。利用定性与定量相结合的研究方法从“教学设计知识”“教学设计技能”“教学设计态度与意识”等3个维度构建了师范生化学教学设计能力的构成模型及水平层级模型。开发了教学案例分析和问卷等2种测评工具对师范生化学教学设计能力进行实证研究,探查了师范生在“中学化学教学设计与实践”课程中化学教学设计能力的发展进阶。结果表明:师范生教学设计知识由单一发展为多样化,教学设计的技能从没有角度进阶到了多角度,教学设计态度与意识从不积极、不自信发展为积极且自信。     

In基二氧化碳氧化丙烷脱氢催化剂的研究

二氧化碳氧化丙烷脱氢增产丙烯是提高丙烷脱氢单程转化率与二氧化碳资源化利用的重要途经,探究高效的非贵金属环保型催化剂对工业界和科学界均有重要意义。采用不同合成方法制备了系列In基催化剂,通过X射线衍射、拉曼、H2-程序升温还原、扫描电镜观测了In活性位结构。关联活性数据得出,具有InO6结构的InOx团簇或In2O3颗粒在CO2氧化丙烷脱氢气氛中能够发生氧化还原循环,从而驱动CO2及丙烷分子的活化,而水热法合成样品中不含该InO6结构,因此不具备CO2活化能力。此外,十元环MFI型Silicalite-1沸石相比十二元环的Si-Beta沸石载体能够促进CO2的吸附,也提高了CO2对丙烷分子活化的促进作用。     

4,4'-二（羟甲基）联苯的合成

以4,4'-二（氯甲基）联苯为原料,经水解生成苄醇类化合物4,4'-二（羟甲基）联苯。采用¹HNMR, IR, HPLC对产物进行了表征。研究讨论了反应条件、催化剂等因素对产物含量和收率的影响,并且优化了4,4'-二（羟甲基）联苯的合成工艺,提出了可能的催化反应机理。结果表明：聚乙二醇作为催化剂,可与溶液中的阳离子发生络合,增强了亲核试剂的反应活性,提高了反应速率。在优化工艺下反应12 h,粗产品HPLC含量可达97.2%,收率93.9%。     

彩色多普勒超声在浅表软组织肿块诊断中的应用分析

本研究探讨彩色多普勒超声在浅表软组织肿块诊断中的应用价值。选取浅表组织肿块患者210例,其中良性病变患者172例,恶性病变患者38例,给予彩色多普勒超声检查。结果显示,恶性病变形态不规则、内部不均匀低回声、边界模糊、内部血流丰富比例明显高于良性病变(P<0.05);恶性病变病灶收缩期峰值流速(Vmax)和阻力指数(RI)明显高于良性病变(P<0.05),病灶最大长径/最大短径(L/S)明显低于良性病变(P<0.05);年龄、形态、内部回声、边界、内部血流、Vmax和RI建立Logistic回归方程,其诊断恶性病变的ROC曲线下面积为0.910(P<0.05),灵敏性和特异性达到84.00%和96.00%。可见彩色多普勒超声在浅表软组织肿块良恶性诊断中有较好的应用价值。     

具有结构阻尼的Kirchhoff型波方程的时间依赖全局吸引子

本文讨论了具有结构阻尼的Kirchhoff型波方程:■解的适定性和长时间行为.当非线性项f的增长指数满足2≤p≤3+2γ时,借助Faedo-Galerkin逼近方法和渐近正则估计,得到了解的适定性和正则性.继而利用收缩函数方法验证解过程的渐近紧性.最终证明了时间依赖全局吸引子在自然能量空间H₀¹(Ω)×L²(Ω)中的的存在性.     

Full Bandwidth Measurement of Supercontinuum Spectral Phase Coherence in Long Pulse Regime

Abstract

This article reports that spectral phase coherence in the supercontinuum in long pulse regime can be measured simply and effectively by using an interference technique with the help of a Mach–Zehnder interferometer. It is also demonstrated that chromatic dispersion on the fringe visibility of interference spectral patterns is overcome in the setup. The technique is applied to characterize supercontinuum spectral phase coherence in a highly non-linear optical fiber with different input conditions: unseeded, coherent seeded, and incoherent seeded picosecond pumps. The results confirm the phase coherence characteristic predicted theoretically in previous studies.