茂金属化合物对苯乙烯丁二烯嵌段共聚物SBS催化加氢的研究

合成了一系列茂金属催化剂（C5H4R)2TiCl2[R=H(1),Me(2),C6H11(3)]和（C5H4R)2TiAr2[R=H,Ar=C6H5(4),p-MeC6H4(5),m-MeC6H4(6);R=Me,Ar=C6H5(7),p-MeC6H4(8);R=C6H11,Ar=C6H5(9),p-MeC6H4(10)],研究了这些催化剂对苯乙烯丁二烯嵌段共聚物SBS的催化加氢,考察了催化剂种类、用量及催化剂各组分之间的比例对加氢效果的影响,得到了较佳的条件,可使聚合物加氢度达到98%以上,钛催化剂用量为0.001-0.003mmol/g聚合物。     

ααTwo new eudesmane sesquiterpenes from Lactuca sativa var. anagustata L

Two new eudesmane sesquiterpene lactones were isolated from the stalk of Lactuca sativa var.anagustata L and their structureswere elucidated by means of spectroscopic methods,including 2D NMR(~1H-~1H COSY,HMBC and NOESY) as 1β-O-β-D-glucopyranosyl-4α-hydroxyl-5α,6β,11βH-eudesma-12,6α-olide(1) and 1β-hydroxyl-15-O-(p-methoxyphenylacetyl)-5α,6β,11βH-eudesma-3-en-12,6α-olide(2).     

溶胶-凝胶法合成超细Li_(2 x)RE_xSi_(1-x)O_3及其离子导电性

用溶胶 凝胶法合成了Li2 xRExSi1 -xO3(RE =Pr ,Nd ,Sm ,Gd ;x =0～ 0 15 ) ,用DTA TG ,XRD ,TEM及交流阻抗等技术对样品的结构、形貌、粒径及离子导电性等进行了观察和测试。其固溶体形成范围是 0 相似文献   

α-可分解4-圈系统

An m-cycle system of order ν and index λ, denoted by rn-CS(ν, λ), is a collection of cycles of length m whose edges partition the edges of λκ_v. An m-CS(ν, λ) is α-resolvable if its cycles can be partitioned into classes such that each point of the design occurs in precisely α cycles in each class. The necessary conditions for the existence of such a design are m|λν(ν-1)/2,2|λ(ν-1), m|αν,α|λ(ν-1)/2 It is shown in this paper that these conditions are also sufficient when m = 4.     

互补问题算法的新进展

互补问题是一类重要的优化问题,在最近３０多年的时间里,人们为求解它而提出了许多算法,该文主要介绍１９９０－１９９７年之间出现的某些新算法,它们大致可归类为：（１）光滑方程法;（２）非光滑方程法;（３）可微无约束优化法;（４）ＧＬＰ投影法;（５）内点法;（６）磨光与非内点连续法,文中对每类算法及相应的收敛性结果做了描述与评论,并列出有关文献。     

两束啁啾脉冲控制下的H+D+光缔合反应研究

从理论上研究了两束啁啾脉冲控制H+D⁺的光缔合反应. 第一束脉冲用来加速碰撞伴的碰撞速度,第二束脉冲用来增加产物HD⁺的产率. 结果表明:第一束脉冲的参数决定了第二束脉冲的优化参数以及产物HD⁺的布居. 产物的布居可以通过调节两束脉冲的延迟时间得到控制. 关键词： 光缔合 +分子')" href="#">HD⁺分子 啁啾脉冲 波包     

水稻压致变异和高压对水稻生长发育的影响

 将高收获指数型优质籼稻（Oryza sativa L.）品种“粤香占”种子在不同条件下进行了3个生长周期的高压种子处理和实验室种植试验。稻种经高压处理后,与对照样品相比,当代种子发芽和秧苗成长较慢且植株个体差异较大;后期生长较快,分蘖数及产量与对照样持平或有所增加。受压样品产生了4种新的植株变异,其中2种为不育植株,另外两种变异植株种植至F2及F3代,变异性状都能稳定遗传。表明高压不仅可以对水稻当代植株生理产生明显的影响,而且可以诱导水稻产生明显和稳定的可遗传变异。     

High-Frequency Einstein-Podolsky-Rosen Entanglement via Atomic Memory Effects in Four-Wave Mixing

Atomic memory effects occur when the atomic relaxation times are comparable to or much longer than the cavlty relaxation times. We show that by using the memory effects, it is possible to obtain high-frequency Einstein- Podolsky-tlosen entanglement between a pair of Stokes and anti-Stokes fields in a four-wave mixing system. The physical origin is traced to the dynamical Stark splittings of dressed states due to the parametrically amplified fields. This mechanism provides an alternative and efficient way for sideband entanglement.     

液体表面张力系数测定实验的几点分析

用拉脱法测定水的表面张力系数实验中，用焦利氏秤测定（Ｆ—Ｗ）时，确定焦利氏秤标尺读数Ｌ１、Ｌ２的位置有两种方法。本文旨在详细分析这两种方法隐含的实验条件和对实验结果的影响．并进行比较，得出结论。     

A singlet state prepared with resonant interaction via trapped ions

A simple scheme for the generation of the three-qutrit Λ-type singlet state with resonant interaction via trapped ions is proposed. In the present proposal, the required interaction time is very short due to resonant interaction. The present proposal may be realized based on the current technologies. We also note that the three-ion three-level maximally entangled state can be generated via resonant interaction in one step.