全文获取类型
收费全文 | 4303篇 |
免费 | 842篇 |
国内免费 | 400篇 |
专业分类
化学 | 2937篇 |
晶体学 | 38篇 |
力学 | 286篇 |
综合类 | 55篇 |
数学 | 495篇 |
物理学 | 1734篇 |
出版年
2024年 | 17篇 |
2023年 | 93篇 |
2022年 | 171篇 |
2021年 | 187篇 |
2020年 | 211篇 |
2019年 | 190篇 |
2018年 | 176篇 |
2017年 | 139篇 |
2016年 | 227篇 |
2015年 | 228篇 |
2014年 | 284篇 |
2013年 | 364篇 |
2012年 | 394篇 |
2011年 | 358篇 |
2010年 | 278篇 |
2009年 | 211篇 |
2008年 | 255篇 |
2007年 | 244篇 |
2006年 | 203篇 |
2005年 | 171篇 |
2004年 | 113篇 |
2003年 | 114篇 |
2002年 | 103篇 |
2001年 | 95篇 |
2000年 | 85篇 |
1999年 | 121篇 |
1998年 | 72篇 |
1997年 | 87篇 |
1996年 | 70篇 |
1995年 | 65篇 |
1994年 | 49篇 |
1993年 | 45篇 |
1992年 | 27篇 |
1991年 | 27篇 |
1990年 | 21篇 |
1989年 | 10篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 13篇 |
1985年 | 5篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1957年 | 3篇 |
排序方式: 共有5545条查询结果,搜索用时 31 毫秒
981.
Influence of local environment on the intensity of the localized surface plasmon polariton of Ag nanoparticles 下载免费PDF全文
A combined Ag nanoparticle with an insulating or conductive
layer structure has been designed for molecular detection using
surface enhanced Raman scattering microscopy. Optical absorption
studies revealed localized surface plasmon resonance, which shows
regular red shift with increasing environmental dielectric
constant. With the combined structure of surface enhanced Raman
scattering substrates and rhodamine 6G as a test molecule, the
results in this paper show that the absorption has a linear
relationship with the local electromagnetic field for insulating
substrates, and the electrical property of the substrate has a
non-negligible effect on the intensity of the local electromagnetic
field and hence the Raman enhancement. 相似文献
982.
Yi-Zhen Wang Guan-Hai Wang Xiao-Min Xiong Biao Wang Li-Ming Zhang Jin-Xiu Zhang 《Rheologica Acta》2010,49(11-12):1117-1126
Traditional torsional resonators, often obtaining the viscoelastic moduli of complex fluids only at one or several given discrete frequencies, lack the continuously varying frequency capability. This is an obvious disadvantage of the traditional torsional resonator technique. This paper presents an improved strategy, based on our previous discrete-frequency-measuring method (Wang et al., J Rheol 52:999–1011, 2008), to overcome such restriction and thus accomplish the continuously varying frequency capability of the traditional torsional resonator for measuring the viscoelastic properties of complex fluids. The feasibility of this strategy is demonstrated with the Newtonian fluids (several water–glycerol solutions) of viscosities varying from 10 to 1,400 cp by using our homemade torsion resonator apparatus in the 10 ~ 2,500 rad/s frequency range (continuous frequencies). Some results for typical viscoelastic polymers (two polyethylene oxide (PEO) aqueous solutions) are also given. Additionally, a comparison of the PEO results is made with the common rheometer technique. It is demonstrated that this improved strategy could enable the traditional torsional resonators, with one oscillating resonance mode, to work as the microrheological technique and the common rheometer technique in the continuous frequency range. 相似文献
983.
The influence of the ultra-short pulse wavelength on the populations in the three electronic states of CsI molecule is investigated using the time-dependent wave packet method. The calculated results show that the populations in the two excited states approach to the maxima at the wavelengths of 369 nm and 297 nm, respectively. The photodissociation reaction channels of the CsI molecule can be chosen by controlling the pump pulse wavelength. 相似文献
984.
飞秒物理、飞秒化学和飞秒生物学 总被引:7,自引:0,他引:7
飞秒激光技术因其极高的时间分辨特性而被广泛应用于研究多种材料的超快过程,文章从几个侧面就飞秒技术在物理学,化学及生物学等方面的应用作了介绍,在飞秒物理方面,介绍了飞秒技术在研究半导体量子阱材料,纳米材料的性质及高次谐波产生等方面的研究进展,飞秒化学则主要介绍了飞秒技术在研究光化学反应,光解离过程、键的断裂及结合以及相关的动力学过程的应用;在生物方面,则介绍利用飞秒技术研究光合作用中的能量传递过程,视觉系统中的光致异构化过程以及DNA中的电荷传递及质子传递等过程的研究现状。 相似文献
985.
Cerebral hemodynamic response in Chinese (first) and English (second) language processing revealed by event-related functional MRI. 总被引:14,自引:0,他引:14
Y Pu H L Liu J A Spinks S Mahankali J Xiong C M Feng L H Tan P T Fox J H Gao 《Magnetic resonance imaging》2001,19(5):643-647
Comparative functional neuroimaging studies using the block design paradigm have previously demonstrated that there are no significant differences in the location of areas of cerebral activation when native Chinese speakers independently process single words or sentences in both the Chinese (first) and English (second) languages. While it has also been documented that significant domains of brain response include the inferior to middle left frontal lobe, the latency, amplitude and duration of the associated hemodynamic changes during isolated neural processing of Chinese and English languages still remain unknown. The aim of this study, therefore, was to examine the characteristics of the hemodynamic alterations in the above-mentioned regions with event-related functional MRI (ER-fMRI) when native Chinese speakers performed verb generation tasks in both the Chinese (first) and English (second) languages. Our results demonstrate the presence of a similar neural activity-induced hemodynamic response in the inferior to middle left frontal lobe during both tasks. Further, there were also no statistically significant differences among the variables that described the hemodynamic response curves. These findings strongly imply that the underlying neural mechanism for Chinese (first) and English (second) language processing may be similar in native Chinese speakers. 相似文献
986.
987.
应用几何光学近似理论模型计算了激光相位多普勒系统中微粒的光散射特性,得到了散射光强与粒径关系、检测器表现的散射光强分布、相位差与粒径特性中的非线性跃变以及检测器形状对特性的影响。 相似文献
988.
考察了几种硅胶负载贵金属催化剂和HRhCO(TPP)3催化剂的1-己烯氢甲酰化反应,对Rh/SiO2、 HRhCO(TPPTS)3/SiO2 和TPPTS-Rh/SiO2上的1-己烯氢甲酰化结果进行了比较.结果表明, TPPTS-Rh/SiO2催化剂的醛的选择性和醛的正异比n/b接近HRhCO(TPPTS)3/SiO2 的相应的催化性能,而远高于Rh/SiO2的相应的催化性能, 7.0 MPa高压下TPPTS-Rh/SiO2催化剂的活性大幅度增加,达到0.0692 S-1.实验排除了其他可能,认为是含有孤对电子的TPPTS 和Rh/SiO2中高度分散的Rh粒子产生了化学键的作用,形成了具有匀相性能的支撑水膜多相催化剂: TPPTS-Rh/SiO2. 相似文献
989.
Three double‐chain amphiphiles with amino acid groups as hydrophilic moiety were synthesized. These amphiphiles can be easily dispersed in buffer solution to form transparent dispersion. Examination of the dispersion by transmission electron microscopy (TEM) showed the formation of stable vesicular aggregates, which was also confirmed by the ability to encapsulate water‐soluble dyes. Since amino acid groups are located on the surface of the vesicles, water‐soluble carbodiimide can induce the condensation of these groups to form peptide. The phase transition temperatures of these vesicles were estimated by differential scanning calorimetry (DSC), and a decrease of phase transition temperature was observed after polycondensation due to the disturbance of the ordered arrangement of the hydrophobic chains. The leakage rate of the vesicles before and after condensation was studied by monitoring the increase of fluorescence intensity of water‐soluble dye. These vesicles belong to the least permeable ones and the leakage rate can be controlled by varying the degree of condensation or the temperature. 相似文献
990.
Wen Yan HU Wen Ping XU Jian Gong SHI* Yong Chun YANG Guang Xiong ZHOU Institute of Materia Medica Chinese Academy of Medical Sciences Peking Union Medical College Bejing Hospital of Jiu Quan District Gansu Province Jiuquan Dis 《中国化学快报》2001,(9)
Alangium, the sole genus in the family Alangiaceae, has a variety of about 20 species distributed in the tropical and subtropical area of the Eastern Hemisphere, and 13 species are known to occur in the south of China1. A. plantanifolium and A. chinense are used in chinese traditional medicine for the treatment of rheumatalgia, paralysis, cardianeuria, and wound2. Pharmacological studies of the extracts of these two species showed muscular relaxing activity, and anabasine was considered as t… 相似文献