三元相图及坐标变换的单纯形优化法测定铜(Ⅱ)-邻菲啰啉-铬天菁S三元络合物组成

本文用三元相图及坐标变换的单纯形优化法安排实验,测定铜(Ⅱ)-邻菲啰啉(Phen)-铬天菁S(CAS)三元络合物组成。通过两种方法,不同途径所得结果一致,络合比为3:3:2。     

On multivalued complementarity problems in Banach spaces

In this paper, we prove a new existence result for multivalued complementarity problems in Banach spaces. Our result represents a refinement and improvement of the previously known results.     

The Mixed LB film of Crowned Phthalocyanine and Picrate

Phthalocyaninesareexcellentpigmentswithgo0dthermalandchemicalstability.TheypossessanumberofcharacteristicsthatmakethemsuitableforaPplicahonsinthefieldofmolecularelectronicsl.LBfilmsofphtalocyanineshavebeenwidelystudiedinthepastdecades2'3.PreviouslywereportedthefabricationofmixedLBfilmsofanamphiphilicphthalocyanineandhydrophobicporphyrin4.Herewereportthedepositionandcharacterizationofthemixedfilm0fphthalcyaninehavingapendantcr0wnethergroupandnacceptor(picrate)basedonhost-guestcomPlexation.Mo…     

[Sc(NO_3)_3(H_2O)_2]·(B15C5)的合成、性质和结构

在乙腈介质中培养出硝酸钪和苯并-15-冠-5形成的配合物单晶[Sc(NO_3),(H_2O)_2)。(B15C5),对其进行了熔点、元素分析、红外光谱、摩尔电导等方面的鉴定。X射线结构分析表明,该晶体属单斜晶系,空间群为P2_(1/n),晶胞参数为:α=9.405(6),b=15.569(8),c=15.896(2),β=95.92(1)°,V=2315.5~3,,Z=4,D_c=1.53g/cm~3,D_0=1.54g/cm~3。Sc(Ⅲ)离子同三个双齿硝酸根和两个水分子配位,构成八配位的配合物,并通过氢键与冠醚形成分子缔合物。     

A Fatou theorem for α-harmonic functions

We study functions which are harmonic in the upper half space with respect to (−Δ)^α/2, 0<α<2. We prove a Fatou theorem when the boundary function is L^p-Hölder continuous of order β and βp>1. We give examples to show this condition is sharp.     

Photoluminescence study of ZnCdSe/ZnSe quantum dot systems

The optical properties of the populated ZnCdSe/ZnSe quantum dots have been studied by photoluminescence spectra measured with different laser excitation apertures at temperatures from 22 to 300 K. The differences of spectral features between small and large excitation spot suggest the existence of quantum dot size fluctuation in the system. The temperature evolution of photoluminescence spectral features revealed that two types of quantum dots with different densities and sizes coexist in ZnCdSe/ZnSe system. The energy spacings of the two kinds of quantum dot emissions are about 50 meV at various temperatures. The thermally activated lateral transfer processes of carriers populated in the two sorts of quantum dots are investigated by temperature dependences of spectral intensities.     

相位型宽频带激光测振仪的研究

在理论上详细描述了一种新型的激光偏振移相干涉测振系统.通过计算机对两路正交干涉光电信号的接收和正弦逼近法数字处理,在1Hz～10KHz宽频带内测量振动台的振幅和初相位,从而实现加速度传感器复合灵敏度的绝对校准.运用琼斯矩阵证明干涉系统中通过偏振片调整可保证两信号的正交性.     

Performance comparison and parametric study on spiral groove gas film face seals

Several spiral groove gas film face seals (SGFS) with different layouts are compared quantitatively to analyze their merits and faults and application behaviors. In addition, a parametric study on downstream mode SGFS is conducted to determine its optimal parameters under certain working conditions. In the computation of gas film pressure on the face, finite element method (FEM) is applied to adapt to complicated geometrical boundary.